玻璃纤维布-MSDS安全技术说明书-.docx

Material Safety Data Sheet
1. Production name:
Glass fiber cloth
2. Production use:
It is the heat preservation material with the performance of anti-heating and anti-chemical heat conduction.
3. Main components:
Pure chemicals, material components include:
Name
Glass fiber
impregnating compound
binder
Assembled roving
%
98.0~99.5
0.05~1.80
0~0.2

CAS No.
Glass fiber: 65997-17-3
Impregnating compound: NA.
Impregnating compound is a mixture of various chemical substances and used on the surface of glass fiber. Most of the material contained in the infiltration agent is a high molecular weight polymer with reactive composition, ingredients are usually inactive(for example the starch),it is outside of range of EINECS and ELINCS list.
In some cases, the Impregnating compound may contain a mailing of silane or other substances. Because these substances concentration are very low (below the total amount of 0.1%), and they may make polymerization in the process of glass fiber production, Even if these substances are likely to be hazardous substances, manufacturers generally ignore the hazards of these substances.
4. Risk summary
This substance is not classified as dangerous according to Directive European Union 67/548/EEC,99/45/EC and ST/SG/AC.10/30/Rev.2 and revised edition.
Risks classify:
In-taking Pathways: ingestion, inhalation, skin or eyes contact.
Health hazards:
Ingestion: usually, the possibility of eating into the glass fiber is not large, but the food into the glass fiber may cause gastrointestinal discomfort.
Inhalation: Inhalation of glass fiber stive and particulates can cause nose, throat and respiratory allergies.
Skin contact: Contact with glass fiber dust and particulates may cause temporary skin irritation.
Eyes contact: Contact with glass fiber dust and particulates may cause temporary eyes irritation.
Environmental impact: long-term exposure to the glass fiber environment may cause temporary effects.
Explosion hazard: no data available.
5. First aid measures：
Skin contact: Wash off with soap and plenty of water。Do not wash with hot water, because hot water will make the skin pores open, so that the glass fiber thorn deeper。If the glass fiber thorn into the skin, with a towel to help set out, in order to avoid further deterioration, do not rub, scratch the skin has been infected，
Eyes contact: rinse the eyes for 15 minutes with clear water, if the eyes are still very afflictive, please seek medical attention
Inhalation: If breathed in, move person into fresh air. If you feel that it is difficult to breath, please offer oxygen. If not breathing, give artificial respiration. Consult a physician.
Ingestion: usually, the possibility of eating into this material is not large, but if there is such a situation, it should be observed for a few days, convinced that the stomach is not comfortable, do not vomit, unless the medical staff to do so, if it is not comfortable to go to the hospital for treatment.
6. Firefighting measures
Combustion grade：The product itself does not flame，but the impregnating compound and packing material on the glass fiber can be flamed.
Harmful combustion products: The main releases are carbon monoxide, hydrogen, carbon dioxide and water.
Extinguishing measures: Fire extinguishing agents use dry chemical agents, foam, carbon dioxide, water.
Fire precautions and measures：in fire-fighting, wear self-contained breathing apparatus.
7. Accidental release measure:
If release on the ground, sweep up and shovel and keep them in suitable, closed containers of disposal; if release in the water, the glass fiber will make deposition and dispersion, so it is difficult to clear completely. But these materials are not hazardous in water.
8. Handling and storage:
Precautions for safe handling: To avoid packing damage, as far as possible to produce the minimum amount of dust, working environment must be cleans, and avoid debris.
Precautions for storage: Keep products in packaging until they are used to prevent dust pollution.
9. Exposure controls and personal protection:
The max concentration (average weight within 8 hours)
Item
Occupational safety and sanitation (permission limited value)
US government health consultation (permission limited value)
Total dust
15mg/ m3
10mg/ m3
Particulate inhalation
5mg/ m3
3mg/ m3
Fiber inhalation
1 fiber/ml
1 fiber/ml
Chinese Occupational safety and sanitation:
Item
Occupational safety and sanitation (permission limited value)
Total dust
3mg/ m3
Particulate inhalation
-
Excursion limits
6mg/ m3
Note: 1). PC-TWA: the average permission limited concentration based on the time of 8h per day, 40h per week.
2). Excursion limits should be twice the PC-TWA pursuant to PC-TWA
Project control: close the produce area tightly, and keep the relative humidity of the environment.
Respiratory system protection: the appropriate mouth-muffle should be worn when conducting work in the area with high density of dust.
Eye protection: goggles should be worn with face protection.
Body protection: it is advised to wear the work uniform, loose and suitable, with long sleeves and pants; the allergic parts mainly lie in the contact ones like around the neck and waist.
Hands: gloves should be worn and allergic skins are wrist and fingers.
10. Physical and chemical property
Appearance and character: flashing point; white or yellowish white solid, odourless. Nonsense
PH value: nonsense.
Igniting point: nonsense
Melting Point: Upper explosive limit: ＞800 ⁰C. Insignificance.
Boiling Point: Lower explosive limit: Insignificance.
Relative density: Solubility
It is six times of the water, Insoluble
Relative vapor density: Insignificance.
The main purpose: Fiber glass is inorganic non-metallic materials which is used on plastic reinforcement, sound absorption and insulation.
11. Stability and reactivity
Stability: this substance is stable.
Prohibited content: None.
Avoid contact with conditions: None.
Polymerization risk: Can’t Happen
12. Toxicology data
Acute toxicity: None
Thrill: The dust of fiberglass may cause skin and eye irritation. Ingestion of fiberglass may cause temporary discomfort in the throat, stomach and intestines. Inhalation May cause coughing, sneezing, nose and throat irritation. According to current experience, inhalation of fiberglass may cause dyspnea, congestion and chest sclerosis.
Carcinogenicity: IRC is a part of the World Health Organization. He concluded that fiberglass is not a human carcinogen. Because there is insufficient evidence that fiberglass can cause human and experimental animals to cause cancer.
13. Ecological information
By now, no information is available can search on this products, and fiberglass products are not included in the ranks of harmful to animals, plants and fish.

14. Disposal of waste
RCRA harm classification: no harmful solid waste.
DISPOSAL CONSIDERATIONS: Disposal of waste should be in accordance with the local environmental protection rules.
15. Shipment information
Risk classification and number: None.
UN Code: None.
Packing mark: none.
Packing classification: None.
Packing type: None.
Transportation Precautions: Transportation should avoid rolling and damp.
16. Laws information
SARA III:
Risk classification:
Acute health risk: Yes
Chronic health risk : None
Fire Risk: None
Pressure risk: None
Reaction risk: None
Report content：
Part 302/304： None
Part 313： None
《Clean air Act》: None content is included.
WHIMIS rule (Canada):
Not controlled
WHIMIS classification:
None
Contents of national chemical products.
Peremptory rule on chemical products sales and use at the country of products process. Every type contents of chemical products which coated the dispose auxiliaries on the fiberglass products should list on the catalogue of national chemical products from products process country. However, continuous fiberglass products is one article at below country chemical products catalogue, so there is no information on this catalogue.
EU : EINECS/ELINCS
USA EPA: TSCA
CANADA: NDSL/ DSL
JAPAN: CSCL
AUSTRALIA: AICS
PHILIPPINES: PICCS
Korea: (K) ECL
CHINA NEW CHEMICAL PRODUCTS LIST
17. Other data
None by now