路博润金属加工液培训资料.ppt

Click to edit Master title style,Click to edit Master text styles,Second level,Third level,Fourth level,Fifth level,The Lubrizol Corporation 2007,all rights reserved,*,The Lubrizol Corporation 2006,all rights reserved,Click to edit Master title style,Click to edit Master text styles,Second level,Third level,Fourth level,Fifth level,Metalworking Additives,金属加工添加剂,October 2012,Agenda,议程,Introduction,概况介绍,Metalworking Capabilities and Support,金属加工系列产品线和技术支持,Product Offering and Formulation Advices,产品介绍和配方举例,Questions,问题,2,Lubrizol,Lockhart,-,Locksol,-Lockguard,Becher Chemie,-Becrosan,-Contram,-Skosanor,Alox,-,Aqualox,-Alox,Gateway,-Addco,-Synester,-Addconate,Lubrizol Metalworking,Brand Names,Sulfurized EP Additives,Traditional Soluble Oil Emulsifier,硫系极压剂及乳化剂产品,Waterbased Additives,Emulsifier Expertise,Speciality Polymeric Esters,水基添加剂、乳化剂和聚合酯,Water based Additives,Corrosion Inhibitor Expertise,水基防锈及防腐蚀剂,Biocides,杀菌剂,Rust Preventives,Water based Corrosion Inhibitors,防锈剂,Rust Preventives,Natural Sulfonate supply,Thixotropic Gelled Sulfonate,防锈剂、磺酸盐,3,Global Support,全球技术支持,Technical laboratories,技术实验室,Wickliffe,OH USA,Brecksville,OH USA,Hazelwood,England,Spartanburg,SC USA,Metalworking Research&Technical Service,金属加工产品研发和技术支持,Hamburg,Germany,德国汉堡,Metalworking Technical Support,金属加工产品技术支持,Shanghai,China,上海,Metalworking Technical Support,金属加工产品技术支持,4,Shanghai Metalworking Resources,上海实验室配置和评价方法,ProcedureProperty Evaluated,IP287 Filter Paper Chip Breakpoint,防锈,/,滤纸铁屑法,IP263Emulsion Stability,乳化安定性,IP 311Concentrate Storage Stability,储存稳定性,IP312Foam Test Shaking Method,泡沫试验,ASTM D 455Kinetic Viscosity,黏度测定,Lubrizol Pump Test Foam Test,路博润泡沫试验,MicroTap II Lubricity,润滑性评定,/,攻丝扭矩,Mod.Timken Fish Tank Bacteria Resistance,抗菌性试验,If need technical service for our customers,pls fill in TSRs first.,MicroTap,Foam Rig,5,Additives Applications Capabilities,路博润添加剂的应用领域,Cleaners,清洗剂,Metal Removal,切削,Metal Forming,成型,Process Additives,工艺助剂,Rust Preventives,防锈,Industrial Additives,工业用油,Corrosion Inhibitors,腐蚀抑制,Internal Lubrication,润滑,Lubrizol Metalworking,Additives,6,Metalworking AdditivesProduct Offering for Water based Products,水基金属加工液产品介绍,Metalworking Additives,金属加工添加剂,Water Based Water Miscible,水基或水溶性产品,Aqueous Fluid System,应用于水基体系,Generally Supplied as Concentrate for Dilution in Water,通常以浓缩液的形态供应，使用时以水稀释,Sub Categories,这类产品包括,Soluble Oil,乳化油,Synthetic,全合成液,Semi Synthetic,半合成液,8,Product Categories,产品,Emulsifier Components,Emulsifier Packages Hong Jing,乳化复合剂,洪泾介绍,Extreme Pressure Additives,Lubricity Additives,润滑剂,Rust Preventives,Corrosion Inhibitors,防锈剂,Industrial Metalworking,Biocides,杀菌剂,9,Lubricity Additives for water miscible fluids,水基润滑剂,10,Lubricity/EP agents,润滑,/,极压剂,ADDOSAN ESTEP 206,TMP-Ester of Castoroil and Oleicacid,是以蓖麻油和油酸为原料的,TMP,的酯,Addosan ESTEP 206 is used as an EP-additive in water miscible metal working fluids,especially for Al-processing.Typical treat levels in the concentrate should be 5-10%.,该产品可用于水基配方中做极压剂，特别适合铝加工。加量,510%,For the machining of steel the addition should be between 5 and 20%to the concentrate,depending on the requirements and the severity of the process,用于钢材加工时需要在浓缩液里加入,520%,，视加工的剧烈程度而定。,In non water based metal working fluids,Addosan ESTEP 206 is qualified for fine steel wire drawing in combination with P-EP and S-additives.,在非水基的体系中它与含磷或含硫极压剂共用可用于细钢线的拉拔。,Addosan ESTEP 206 can also be used as a fatty agent in non-water miscible metal working fluids.,在非水溶性配方里可用作油性剂,It is also suitable for grinding processes where a good stability of the fatty component is required,.,在磨削加工中如果需要使用稳定性好的油性剂，可考虑使用该产品,11,Addosan Estep 206,Properties,Colour,颜色,:ligth brown,浅棕色,Acid value,酸值,(mg KOH/g):max 10Viscosity,黏度,(40 C):appr 85 mm/s,Typical use level,典型用量,Waterbased,水基,:5 10%Neat oils,油基,:1 2%,(neat oils:2%Estep 206+0.5%EPC 127 -used for flute grinding,在油基配方中使用,2%Estep 206+0.5%EPC 127,可用于成管加工,),12,BECROSAN E 2135,amine and boron free formulation with biocide,配方举例：不含胺、不含硼的半合成液配方,BECROSAN E 2135 45%,Addosan ESTEP 206,10%,Naphthenic Base Oil 42%,CONTRAM OF-G 2.5%,CONTRAM J 30 D 0.5%,An approx.8%emulsion of a preparation of BECROSAN E 2135,performance ester(in particular Addosan ESTEP 206)in base oil(as above)works extraordinary well for general aluminium machining.,上述配方以,8%,的稀释液用于铝加工具有非常突出的效果,Appearance,外观,visual,目测,translucent,半透明,Emulsion stability,乳化安定性,visual after 24 hrs 0 ml oil/0 ml cream,pH value,5%in water,5%,水溶液的,PH,值,DIN 51 3699.1,Corrosion protection DIN 51 360 part 2 Note 0 at 4%vol,防锈,13,Semi Synthetic Aluminum,铝加工半合成液,润滑效果,45%B,ECROSANE2135+,环烷基油,VS 10%ADDOSANESTEP206+45%BECROSANE2135+,环烷基油,14,High oil-Semi-Synthetic Packages,与高含油半合成复合剂的复配配方,Base oil,基础油,41.70,45.70,50.70,BECROSAN E 2137 H/LUBRIZOL 5683,42.00,-,-,BECROSAN E 2135,-,40.00,-,BECROSAN E 2152,-,-,35.00,ADDOSAN ESTEP 206,10.0,10.0,10.0,CONTRAM MBO or ST-1,2.00,2.00,2.00,CONTRAM J 30 D,0.30,0.30,0.30,Quicklin 13,1.00,-,-,Water,水,3.00,-,-,TD 25/30,-,2.00,2.00,LUBRIZOL 5674,消泡剂,0.10,-,0.10,15,Performance,性能,E 2137 H/LUBRIZOL 5683,E 2135,E 2152,Appearance,外观,yelow-light brown,clear,黄色,淡棕色，透明,Yelow light brown,clear,黄色,淡棕色，透明,Yellow light brown,clear,黄色,淡棕色，透明,Appearance emulsion,(5%in 20dH),乳液外观,Fresh,新鲜乳液,Translucent,半透明,Translucent,半透明,Translucent,半透明,after 24 h,24,小时后,translucent-no cream,半透明,无浮皂,translucent-no cream,半透明,无浮皂,translucent-no cream,半透明,无浮皂,corrosion -DIN 51360-part 2,防锈,2%-class 0-1,2%-class 1-2,2%-class 2,corrosion -IP 287,防锈,breakpoint 2%,breakpoint 3%,breakpoint 3%,pH-value-(5%in 20dH)pH,值,9.20,9.40,9.40,foam characteristic,泡 沫,5%in 10dH,no foam,无泡沫,no foam,无泡沫,no foam,无泡沫,5%in 5dH,70 ml-10 ml-0 ml,50 ml-0 ml-0 ml,70 ml-10 ml-0 ml,Reichert without lubricity,磨斑,/,未加润滑剂,30.0 mm,31.3 mm,33.2 mm,Reichert with,磨斑,/,加入,ADDOSAN ESTEP 206,23.0 mm,23.8 mm,24.3 mm,16,Metalworking-Corrosion Inhibitors,防锈剂,Stop Rust,17,Becrosan 2131 Technology,Trivial name:Triazinetrisaminohexanoic acid,三嗪三氨基己酸,IUPAC:6,6,6-(1,3,5-triazine-2,4,6-triyltriimino)-,trihexanoic acid,CAS-No.80584-91-4 MW:468.6 g/mol,18,Becrosan 2131 Technology,Applications,应用,Neutralized with alkali/alkanolamine performs as very effective corrosion inhibitor,用碱,/,醇胺中和后是非常有效的腐蚀抑制剂,Applied in all types of water based systems,Metalworking fluids,(Semi-synthetic and synthetic fluids),可以用于所有类型的水基体系金属加工液,(,半合成和合成液,),High water based hydraulic fluids(HFC),可用于高水基液压液,(HFC),Engine and other cooling systems,用于发动机和其他冷却体系,19,Becrosan 2131 Technology,Benefits,优点,Very effective corrosion inhibition,高效防锈,Does not form resinous films or gums on metals,不会在金属表面形成树脂或胶状膜,Low foaming,低泡沫,No aluminum staining(depending on amine used),不会造成铝腐蚀,Compatible with hard water up to 2000 ppm,耐硬水能力高达,2000 ppm,Can be used for corrosion inhibition of multi-metal systems,might be improved by addition of Skosanor KSP 24/531 and heptanoic/ison.Acid,可以用于含多种金属的体系，添加,Skosanor KSP 24/531,可提高防腐蚀效果,PROVEN:No tendency to form nitrosamines(5f rule in US),不会生成亚硝胺,Excellent air release,良好的空气释放性能,20,Becrosan 2128 Technology,Trivial name:Tolylsulfonamidohexanoic acid,对甲苯磺酰氨基己酸,IUPAC:4-Methylphenylsulfonylaminohexanoic acid,CAS-No.78521-39-8 MW:285.0 g/mol,21,Becrosan 2128 Technology,Applications,应用,:,Neutralized with alkali/alkanolamine performs as very effective corrosion inhibitor,用碱,/,醇胺中和后是非常有效的腐蚀抑制剂,Applied in all types of water based systems Metalworking fluids(Semi-synthetic and synthetic),可以用于所有类型的水基体系金属加工液,(,半合成和合成液,),Water treatment processes,水处理过程,Press waters,水压系统,Industrial cleaners,工业清洗剂,Off-shore lubricants,海上石油,/,天然气钻探用润滑剂,Water based hydraulic fluids,水基液压液,Water/glycol cooling systems(+KSP 24/531),水,/,乙二醇冷却体系（可加入,KSP 24/531,提高抗腐蚀效果）,22,Becrosan 2128 Technology,BENEFITS,Very effective corrosion inhibition for ferrous metals,cast iron,ferrous alloys at a pH value of 8.,pH,值,8,时，对铁、铸铁和铁合金的防锈非常有效,Easy handling,easy soluble,non dusting,odorless,容易使用，容易溶解,不会产生粉尘，无味,No sticky residues after water phase evaporation,水相挥发后无粘性残留物,Low foaming,低泡,Compatible with hard water up to 2000 ppm,耐硬水能力,2000 ppm,No staining on aluminum(depending on amine used),不会造成铝变色,No tendency to form nitrosamines,不会生成亚硝胺,Higher thermal stability than metal soaps,比金属皂具有更好的热稳定性,23,Fully synthetic based on BECROSAN 2131,全合成液的建议配方,20%Triethanolamine,三乙醇胺,5%Monoethanolamine,单乙醇胺,16%BECROSAN 2131,2,5%Isononanoic acid,异壬酸,0,5%Skosanor KSP 531,0,5%CONTRAM NFK,55,5%Water,水,DIN 51360 T2(Chip filter test),防锈（滤纸铁屑法）,=2,5%class 0,pH-value(3%in DI-water)pH,值（在,3%,去离子水中）,=9,2,Foam,behaviour,(5%in 10dH-water),泡沫,=70 ml 30 ml 0 ml,Reichert(5%in DI-water,100 m,1,5 kg),磨斑,=30,6 mm/GM 100,24,Starting Formulation Grinding/Machining,more severe machining,用于更高负荷的磨削,/,切削配方,Component,成分,%By Weight,重量,%,Triethanolamine,三乙醇胺,20,Monoethanolamine,单乙醇胺,5,BECROSAN 2131,10,Water,水,balance,ADDCO 410 P,5,ADDCO MLB 10X,10,SKOSANOR KSP 531,0,5,Bactericide/fungicide,杀菌剂,2-3,25,Semi synthetic based on BECROSAN 2131,半合成配方,32,0%Base oil,基础油,8,0%ADDCONATE M,15,5%Triethanolamine,三乙醇胺,2,0%Monoethanolamine,单乙醇胺,7,5%BECROSAN 2128,2,0%BECROSAN 2131,2,5%TD 25/30,7,5%Coupling agents(fatty alcohol),偶合剂,15,0%Water,水,5,0%BECROSAN C656(fatty acid amide,脂肪酸酰胺,),2,5%CONTRAM ST-1,0,5%CONTRAM J 30 D,Appearance,外观,Clear,yellow,黄色透明,Emulsion,乳液,Translucent,半透明,DIN 51360 T2(Chip filter test),防锈,=2,5%class 0,pH-value(3%in DI-water)pH=9,3,26,Use Of,Alkanolamides,In Metalworking,金属加工液中链烷醇酰胺的应用,Emulsifier,做乳化剂,Functions as a primary or secondary emulsifier in o/w metalworking formulations,在水包油型乳化油配方中可做主乳化剂或助乳化剂使用,Lubricity Additive,润滑剂,Amides based on longer chained fatty acids enhance lubrication properties to a fluid,基于长链脂肪酸的酰胺有助于提高体系的润滑效果,Corrosion Inhibitor,防锈剂,Fatty acid alkanolamides provide extra corrosion protection for ferrous metals,脂肪酸的链烷醇酰胺对黑色金属有良好的防锈效果,.,27,Fatty amides/esters,脂肪酸酰胺,/,酯,STRENGTH,优点,Cheap corrosion inhibitors,是一种较便宜的防锈剂,Post treatment application possible,可现场添加,Low classification level,。,Low toxicity profile,低毒性,Some are liquid,easy to handle,有一些产品是液体的，易操作,Used for semi-synthetic and soluble oil type fluids,可用于乳化油和半合成液,28,Fatty amides/esters,脂肪酰胺,/,酯,Product,产品,Alk.amine,胺的种类,Appea-rance,外观,Viscosity 40C,黏 度,TAN,酸值,TBN,碱值,Solubility,溶解性,CP-51360/2,SOE+2%am.5%in w.(orig:cl.3,0,9,2),防锈（浓缩液中加,2%,，,5%,稀释）,B.210 E,MEA,Pasty,膏状,-,8,10,Emuls.,可乳化,cl.2,pH 9.2,B.210 M,MEA,Pasty,膏状,-,15,3,Emuls.,可乳化,cl.2,pH 9.1,B.210 R,DEA,Liquid,液体,385,5,130,Emuls.,可乳化,cl.1,pH 9.1,B.210 D II,DEA,Liquid,液体,170,14,35,Emuls.,可乳化,cl.1-2,pH 9.0,B.541,MIPLA,Liquid/pasty,液态,/,膏状,150,3,9,Emuls.,可乳化,cl.2,pH 9.0,B.C 656,DGA,Liquid,液体,200,50,10,Soluble,可溶,cl.1-2,pH 9.2,B.228,DEA,Liquid,液体,390,15,150,Dispers.,水分散,cl.0-1,pH 9.2,B.583,TEA/MEA,Liquid,液体,210,50,52,Emuls,可乳化,cl.0-1,pH 9.1,B.2021,DETA,Waxy,蜡状,45 60C,3.5,24,Insol.,不溶,cl.2,pH 9.2,29,Performance,性能,18%LUBRIZOL 5475,in 100 N base oil,18%LUBRIZOL 5475,+2%BECROSAN 583,in 100 N base oil,18%LUBRIZOL 5475,+4%BECROSAN 583,in 100 N base oil,Appearance,外观,yelow-light brown,clear,黄色,淡棕色，透明,Yelow light brown,clear,黄色,淡棕色，透明,Yellow light brown,clear,黄色,淡棕色，透明,Appearance emulsion,(5%in 20dH),乳液外观,0 ml oil/0.3 ml cream,0 ml oil/0.1 ml cream,0 ml oil/0.1 ml cream,corrosion -DIN 51360-part 2,防锈,5%-class 2,5%-class 1,5%-class 0,corrosion -IP 287,防锈,breakpoint 5,5%,breakpoint 4,5%,breakpoint 4%,pH-value-(5%in 20dH),9.20,9.40,9.40,foam characteristic,泡沫,5%in 10dH,no foam,无泡沫,no foam,无泡沫,no foam,无泡沫,5%in 5dH,70 ml-10 ml-0 ml,100 ml-40 ml-0 ml,100 ml-50 ml-0 ml,Reichert,磨斑,34.0 mm,31.3 mm,28.2 mm,30,ADDCONATE Starting FormulationSemi Synthetic,建议起始配方,半合成,Base oil,基础油,30.00,ADDCONATE M,10.00,DEG,2.00,TEA,10.00,TD 25/30,1.00,Guerbitol C 16,2.50,BECROSAN(TM)C 656,7.50,Isononanoic,异壬酸,1.00,Emulsogen M,0.50,Water,水,35.50,Appearance,外观,Clear yellow liquid,黄色透明液体,Appearance-emulsion,乳液外观,Translucent,半透明,pH-value,(3%in 20dH),PH,值,9.15,Corrosion,(DIN 51360-2-4%),防锈,Class 0-1,31,ADDCONATE Starting FormulationSemi Synthetic,建议起始配方,半合成,base oil,基础油,32.00,ADDCONATE M,8.00,BECROSAN C 2141,(carboxylic acid salt,羧酸盐,),25.00,TD 25/30,2.50,Emulsogen M,5.00,3370 V,2.50,Water,水,15.00,MEA,2.00,BECROSAN C656,(Fatty acid amide),5.00,CONTRAM ST-1,2.50,CONTRAM J 30 D,0.50,Appearance,外观,Clear yellow liquid,黄色透明液体,Appearance-emulsion,乳液外观,Translucent,半透明,pH-value,(3%in 20dH),PH,值,9.3,Corrosion,(DIN 51360-2-4%),防锈,Class 0,32,Biocides,杀菌剂,33,Biocide review:,34,Biocide review:,Micro-organisms like,微生物喜欢,A wet environment,潮湿环境,Temperature,温度,Dust,尘土,And certain elements as food stuff,以及某些可以作为食物的元素,Which are given in all,METAL WORLKING FLUIDS,这些在金属加工液中均可以得到满足,35,Biocide review:,36,Bactericides,杀细菌剂,37,CONTRAM ST-1,N,N-methylenebismorpholine N,N-,亚甲基双吗啉,CAS#5625-90-1,38,CONTRAM MBO,Oxazolidine,3,3-methylenebis5-methyloxazolidine,噁唑烷，,3,3-,亚甲基双,5-,甲基,唑烷,CAS#66204-44-2,39,Product Features,产品特性,CONTRAM ST-1,Exceptional stability in MWF concentrates,在浓缩物中特别稳定,Does not disrupt balance of emulsion system,不会干扰乳液体系的平衡,Long-lasting efficacy(half-life is 5-8 months),长效（半衰期,5-8,个月）,Unique balance of oil and water solubilityimportant feature for emulsion systems,突出的水溶性和油溶性,对乳液体系非常重要,Low total formaldehyde content,总甲醛含量低,Evidence for efficacy vs.mycobacteria,对细菌特别有效,No skin irritation(no R43),对皮肤刺激性小（不用“贴标签”,R43,）,Easy compatible with common used fungicides(NaPyrion,IPBCs,BBits),容易与抗真菌剂并用,Works quite well in pH ranges 7-11,在,pH7-11,范围内特别有效,Concentrate treatment:2,5 3,0%,浓缩物加剂量,2.5-3.0%,Tankside treatment:not preferred,不推荐用于现场添加,Stability problems of CONTRAM ST-1 as sold:solidification at cold temperatures,CONTRAM ST-2,CONTRAM ST 1-50,ST-1,气温较低时，会凝固，可以使用,CONTRAM ST-2,，,ST-1/50,40,Product Features,CONTRAM MBO,Balanced performance for tankside or concentrate treatment,可以用于浓缩物或现场维护,Greater oil solubility than competitive materials,油溶性更好,Tankside complement to products protected by ST-1 in concentrate(avoid microbe acclimation and resistance),可以用作含有,ST-1,浓缩物产品使用时的现场维护（避免产生耐药性）,High total formaldehyde content for fast activity on existing microbial growth,高甲醛含量可以快速杀死细菌,Based on primary amine,基于一级胺,Concentrate treatment:2,5 3,0%,浓缩物,2.5-3.0%,Tankside treatment:0,1 0,2%,现场,0.1-0.2%,Harder incorporation in MWF concentrates,additional coupling agents necessary(fatty acids,ethoxylated or fatty alcohols),需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）,41,Product Features,CONTRAM 121,Unique balance of performance properties,优异的杀菌性能,Quick activity for tankside control coupled with good stability in fluid concentrates,在浓缩物中优异的稳定性，同时可以用于现场添加,Complement to CONTRAM ST-1 protected fluids alternate tankside chemistry to avoid microbe acclimation and resistance to one particular,bactericide chemical type,可以用作含有,ST-1,浓缩物产品使用时的现场维护替代品，避免某些特定种类的细菌产生抗药性,Greater oil solubility than competitive triazines for improved compatibility and stability in metalworking fluid emulsions,比三嗪类杀菌剂的油溶性更好，和金属加工乳液有更好的兼容性和稳定性,More stable than HHT,比,HHT,更加稳定,Concentrate treatment:2,5 3,0%,浓缩物：,2.5-3.0%,Tankside treatment:0,1 0,2%,现场：,0.1-0.2%,Harder incorporation in MWF concentrates,additional coupling agents necessary(fatty acids,ethoxylated or fatty alcohols),需要一些偶合剂以帮助提高浓缩物的稳定性（脂肪酸，乙氧基化物或脂肪醇）,42,Product Features,CONTRAM OF-G,Fast-acting performance against bacteria for tanks