BioTector B7000在线TOC TN TP分析仪用户手册-2017（英文版）.pdf

Catalog Number:10-MAT-252 BioTector B7000 Online TOC TN TP Analyzer USER MANUAL March 2017,Edition 1 BS4ANP2 2.12e Original Instructions in English Copyright BioTector 2017.All rights reserved.Printed by BioTector.Printed in the Republic of Ireland.Page 2 Table of Contents SECTION 1 SAFETY PRECAUTIONS.5 1.1 INFORMATION AND SAFETY SIGNS USED IN THE MANUAL.5 1.2 PRECAUTIONARY LABELS ATTACHED TO THE INSTRUMENT.6 1.3 POTENTIAL SYSTEM SAFETY HAZARDS.8 1.3.1 Ozone and Toxicity.9 1.3.2 First Aid Treatment.9 1.4 GENERAL SAFETY PRECAUTIONS.10 1.4 PRCAUTIONS GNRALES DE SCURIT.10 1.4.1 Electrical and Burn Precautions.11 1.4.1 Prcautions relatives llectricit et aux brlures.11 1.4.2 Carrier Gas and Exhaust Gas Precautions.12 1.4.2 Prcautions relatives au gaz porteur et dchappement.12 1.4.3 Chemical Precautions.13 1.4.3 Prcautions chimiques.13 1.4.4 Sample Stream Precautions.14 1.4.4 Prcautions relatives aux chantillons.15 SECTION 2 OPERATORS MANUAL.16 2.1 SOFTWARE SCREENS AND SOFTWARE MENU DIAGRAM.16 2.1.1 Startup State.18 2.1.2 System Status Messages.18 2.1.3 Analysis Data Screen.19 2.1.4 Analysis Graph Screen.20 2.1.5 Reagent Status Screen.21 2.1.6 Select Level Menu.21 2.1.7 Enter Password Menu.22 2.2 OPERATION MENU.23 2.2.1 Start Stop.23 2.2.2 Reagents Setup.25 2.2.2.1 Install New Reagents.25 2.2.2.2 Purge Reagents&Zero.26 2.2.3 System Range Data Screen.26 2.2.4 Manual Program Menu.27 2.2.5 Reaction Archive Screen.28 2.2.6 Fault Archive Menu.28 2.2.7 Time&Date Menu.29 2.2.8 Contact Information.29 2.3 CALIBRATION MENU.30 2.3.1 Zero Calibration.30 2.3.2 Span Calibration.32 SECTION 3 TECHNICAL SPECIFICATIONS.34 SECTION 4 INTRODUCTION.37 4.1 BIOTECTOR MAJOR COMPONENTS.37 4.1.1 Analysis Enclosure.37 4.1.2 Electronics Enclosure.39 4.2 BIOTECTOR OPERATION.41 4.2.1 BioTector Oxidation Method.41 4.2.2 BioTector Sample Injection.42 4.2.3 BioTector Analysis Types.42 4.2.3.1 TIC&TOC Analysis.44 4.2.3.2 TC Analysis.44 4.2.3.3 VOC(POC)Analysis.45 4.2.3.4 TC-TIC Analysis.46 4.2.3.5 TN Analysis.47 4.2.3.6 TP Analysis.47 4.2.3.7 TPr Analysis.48 Page 3 SECTION 5 INSTALLATION.51 5.1 BASIC SYSTEM REQUIREMENTS.51 5.2 UNPACKING AND INSTALLATION.52 5.2.1 Analyzer Dimensions and Mounting.53 5.2.2 Wiring Power and Signal Terminals.55 5.2.3 Wiring External Power Disconnection Switch.57 5.2.4 System Fuse Specifications.58 5.3 CARRIER GAS AND REAGENT CONNECTIONS.59 5.3.1 Carrier Gas Connection.60 5.3.2 Reagent Connections.62 5.4 SAMPLE,DRAIN AND EXHAUST CONNECTIONS.64 5.4.1 Sample Inlet Tube Position.64 5.4.2 Drain,Bypass and Exhaust Connections.66 SECTION 6 REAGENTS AND CALIBRATION STANDARDS.67 6.1 REAGENTS.67 6.2 CALIBRATION STANDARDS.68 SECTION 7 ANALYZER COMMISSIONING AND STARTUP.71 SECTION 8 MAINTENANCE MENU.77 8.1 DIAGNOSTICS MENU.78 8.1.1 Process Test.79 8.1.1.1 Oxidation Phase Process Test.79 8.1.1.1.1 Pressure Test.79 8.1.1.1.2 Flow Test.80 8.1.1.1.3 Ozone Test.81 8.1.1.1.4 Sample Pump Test.83 8.1.1.1.5 pH Test.84 8.1.1.2 Liquid Phase Process Test.88 8.1.1.2.1 Purge Cells Test.88 8.1.1.2.2 Clean Cells Test.88 8.1.1.2.3 Read DI Water Reference Test.89 8.1.1.2.4 Read TN&TPr Sample Test.90 8.1.1.2.5 Read TP Sample Test.91 8.1.2 Simulate.92 8.1.2.1 Oxidation Phase Simulate.92 8.1.2.2 Liquid Phase Simulate.96 8.1.3 Signal Simulate.99 8.1.4 Data Output.101 8.1.4.1 Send Reaction Archive.102 8.1.4.2 Send Fault Archive.105 8.1.4.3 Send Configuration.105 8.1.4.4 Send All Data.105 8.1.5 Input/Output Status.106 8.1.6 Service.107 8.2 COMMISSIONING MENU.108 8.2.1 Reaction Time.108 8.2.2 Sample Pump.109 8.2.3 Stream Program.109 8.2.4 COD/BOD Program.110 8.2.5 New Reagents Program.111 8.2.6 Reagents Monitor.111 8.2.7 Autocal Program.112 8.2.8 4-20mA Program.113 8.2.9 Relay Program.115 8.2.10 Data Program.116 8.2.11 Information.116 8.3 SYSTEM CONFIGURATION MENU.117 8.3.1 Analysis Mode.118 8.3.2 System Program.119 8.3.3 Calibration Data.128 8.3.4 Sequence Program.128 Page 4 8.3.4.1 Average Program.128 8.3.4.2 Cleaning Program.129 8.3.4.3 Zero Program.130 8.3.4.4 Span Program.131 8.3.4.5 Reagents Purge.132 8.3.4.6 Pressure/Flow Test Program.133 8.3.5 Output Devices.135 8.3.6 Reaction Check.136 8.3.7 Result Integration.137 8.3.8 Fault Setup.138 8.3.9 Fault Status.140 8.3.10 CO2 Analyzer.141 8.3.11 Cooler Program.141 8.3.12 Boiler Program.142 8.3.13 Software Update.143 8.3.14 Password.144 8.3.15 Language.144 8.3.16 Hardware Configuration.144 SECTION 9 TROUBLESHOOTING OF SYSTEM FAULT,WARNING AND NOTIFICATION EVENTS.145 9.1 BIOTECTOR FAULT EVENT EXPLANATION AND REMEDIAL ACTION.145 9.2 BIOTECTOR WARNING EVENT EXPLANATION AND REMEDIAL ACTION.148 9.3 BIOTECTOR NOTIFICATION EVENT EXPLANATION AND REMEDIAL ACTION.155 SECTION 10 SERVICE AND MAINTENANCE.156 10.1 WEEKLY MAINTENANCE.156 10.2 SIX AND TWELVE MONTH SERVICE.158 SECTION 11 SYSTEM REPLACEMENT AND SPARE PARTS.164 SECTION 12 WARRANTY AND EXCLUSIONS.165 SECTION 13 APPENDICES.166 APPENDIX 1 INSTRUCTIONS FOR CONNECTING PRINTER TO BIOTECTOR.166 APPENDIX 2 SETTING UP WINDOWS TO RECEIVE DATA FROM BIOTECTOR.167 APPENDIX 3 BIOTECTOR 4-20MA OUTPUT MODES.168 Appendix 3.1 Direct Mode.168 Appendix 3.2 Stream Multiplex Mode.169 Appendix 3.3 Full Multiplex Mode.173 Appendix 3.4 Result Update in Stream and Full Multiplex Modes.178 APPENDIX 4 GLOSSARY OF TERMS AND ABBREVIATIONS.179 APPENDIX 5 CONTACT INFORMATION.182 Page 5 Section 1 Safety Precautions Please read this manual before unpacking,setting up,or operating the BioTector.BioTector should only be used by qualified trained staff and for the purpose it is intended for.Do not use or install this equipment in any way other than the methods specified in this manual.The procedures and methods described in this manual are based on assuming the user have basic,fundamental background on electronics,chemistry and analyzer equipment.If the instructions in this manual are not followed,the operation and protection provided by the equipment may be impaired.1.1 Information and Safety Signs used in the Manual When any supplementary information is required and if any hazards exist,the necessary information and safety signs(Information,Caution,Warning and Danger)will be displayed for the corresponding section or procedure in this manual.Used to indicate supplementary information,to call attention to recommendations,to simplify the operation and to guarantee the correct use of the equipment.Used when there is a danger of minor damage to the system if the user does not follow precautions.Used when there is a danger of minor injury or serious damage to the system if the user does do not follow the precautions.Used when failure to observe a safety precaution may result in serious injury or death.Caution WARNING DANGER Page 6 1.2 Precautionary Labels Attached to the Instrument The labels and tags attached to the instrument are summarized below.Please read all labels and tags attached to the instrument.If not observed,personal injury or damage to the instrument could occur.This symbol,when displayed on the instrument,indicates that the user must gather the necessary operation and/or safety information given in the instruction manual.This symbol,when attached on an enclosure,indicates an existing risk of electrical shock and/or electrocution.Only qualified personnel should open such enclosures and work with hazardous voltages.This symbol,when displayed on a component,identifies that the component surface can be hot.When it is necessary to work with this component,it should be handled with care.This symbol,when noted on a product,illustrates the risk of chemical harm due to its corrosive,acidic,caustic or solvent nature.Only qualified and trained staff should handle such chemicals.This symbol,when noted on an analyzer,illustrates the risk of the presence of toxic ozone gas produced in the analyzer.Only qualified and trained staff should work with this analyzer.This symbol,when displayed on the instrument,indicates the presence of devices sensitive to Electro-Static Discharge(ESD).Prior to any work with such components,the individual should be grounded via an earth strap to prevent any possible damage.This symbol,when displayed on the product,indicates that protective eye wear must be used during the maintenance or service of the equipment.This symbol,when used on the product,identifies the location of the protective earth(ground)connection.Page 7 Electrical equipment marked with this symbol may not be disposed of in European domestic or public disposal systems.Return old or end-of-life equipment to the manufacturer for disposal at no charge to the user.Page 8 1.3 Potential System Safety Hazards The potential safety hazards,which are associated with a running BioTector system,are as follows:Electrical hazards Potentially hazardous chemicals Oxygen gas and components generating Ozone gas Please read the instructions in this manual carefully before installing or starting the BioTector.The manufacturer cannot accept liability for damages due to non-observance of this manual.Use of spare parts not supplied by the manufacturer will invalidate the warranty.The manufacturer shall not be liable for omissions or errors contained herein or for incidental or consequential damages in connection with the furnishing,performance,or use of this material.The information contained in this manual is subject to change without notice.The information contained herein is protected by copyright.Reproduction,adaptation,or translation of any part of this manual without prior written permission is prohibited,except as allowed under the copyright laws.Product names mentioned herein are for identification purposes only and may be trademarks or registered trademarks of their respective companies.Where manuals are translated into several languages,the source language text is considered as the original.Maintenance and operation should not be carried out unless personnel have been fully trained in the operation of the BioTector.Prior to working on the inside of the analyzer,the technician should be grounded via an earth strap.Caution Page 9 1.3.1 Ozone and Toxicity Ozone is found in gaseous form as a natural ingredient of the earths atmosphere.Some of the chemical and physical properties of ozone are as follows:Terms Properties of Ozone(O3)Molecule Weight 47.9982 g/g-mol Boiling Point-119 0.3 C Melting Point-192.7 0.2 C Exposure to even low concentrations of ozone can be damaging to delicate nasal,bronchial and pulmonary membrane.Symptoms of acute ozone toxification appear at a concentration of about 1 ppm by volume.The type and severity of symptoms depend on the concentration and duration of exposure.In mild cases and in the early phases of severe cases,symptoms will include one or more of the following:Irritation or burning of the eyes,nose or throat Lassitude Frontal headache Sensation of sub-sternal pressure Constriction or oppression Acid taste in mouth Anorexia In more severe cases,the symptoms may include dyspnoea,cough,choking sensation,tachycardia,vertigo,lowering of blood pressure,severe cramping,chest pain,and generalized body pain.Pulmonary oedema may develop with delayed onset,usually one or more hours after exposure.Following severe acute ozone toxification,recovery is slow.In the few severe human cases reported,10-14 days of hospitalization were required.In these cases,minimal residual symptoms were present for as long as 9 months,but all cases eventually recovered completely.The 1983 ACGIH has recommended a Threshold Limit Value(TLV)of 0.1 ppm(0.2 mg/m3)for ozone.The safe level for short human exposure to concentrations of ozone in excess of 0.1 ppm(Threshold Limit Value)is not known with certainty.The atmospheric concentration immediately hazardous to life is likewise not known,but inhalation of 50 ppm for 30 minutes would probably be fatal.The odor threshold of ozone for a normal person is 0.01-0.02 ppm by volume in air.1.3.2 First Aid Treatment Move the victim to an uncontaminated atmosphere.Control restlessness and pain by the administration of sedatives and anodynes orally.Severe cases may require subcutaneous injections of small doses of meperidine hydrochloride(Demerol)for relief of pain.Give oxygen inhalation by facemask when the acute symptoms have subsided.Severe cases require hospitalization since deferred pulmonary oedema may develop.Page 10 1.4 General Safety Precautions Please pay attention to all caution,warning and danger statements at all times.Non-observance of the safety instructions can result in serious personal injury,death or damage to the equipment.Therefore observe the following:Only engineers trained by the manufacturer should carry out maintenance on the BioTector.The power supplies contain capacitors that are charged to hazardous voltages.After disconnecting the main power,allow a minimum of one minute for discharge before opening the control section.Never wash or spray the system with water.Do not allow water to enter the interior.Protect the system from one-sided heat radiation,direct sunlight and vibration.System must be installed in a dry,dust-free room.Special precautions are required in environments with corrosive gases,vapors or explosion risk.Please do not place anything on top of the system.1.4 Prcautions gnrales de scurit Prire dtre toujours attentif toutes les notices de prudence,davertissement ou de danger.Le non respect des instructions de scurit peut engendrer la blessure grave dindividus,leur dcs ou la dgradation du matriel.Pour ces raisons,prire dobserver les rgles suivantes:Seuls les ingnieurs forms par le fabricant doivent raliser des travaux de maintenance sur le BioTector.Lalimentation lectrique contient des condensateurs qui sont chargs des tensions dangereuses.Aprs avoir dbranch lalimentation lectrique,attendre au moins une minute pour permettre la dcharge avant douvrir le botier de commande.Ne jamais laver ou arroser lappareil avec de leau.Ne pas laisser de leau pntrer lintrieur.Protger lappareil des radiations de chaleur sur un seul ct,des rayons directs du soleil et des vibrations.Lappareil doit tre install dans une pice sche et sans poussire.Il est ncessaire de prendre des prcautions particulires dans les environnements contenant des vapeurs ou gaz corrosifs ou ceux risque dexplosion.Prire de ne rien poser sur le dessus de lappareil.Page 11 1.4.1 Electrical and Burn Precautions During system installation,maintenance or servicing:Isolate the system power lines before starting any work in the electronic enclosure.All electrical work should be carried out by qualified electrical personnel only.Comply with all local and national regulations when working with electrical connections.Make sure the system is properly earthed(grounded)before switching on.It is required to connect the mains through an external isolator(2-pole disconnection switch),and if possible connect the mains through an earth leakage circuit breaker.When working with hot surfaces,use protective gloves and handle the components with care.1.4.1 Prcautions relatives llectricit et aux brlures linstallat