Optical PropertiesofCondensed Matters.ppt

单击此处编辑母版标题样式,单击此处编辑母版文本样式,第二级,第三级,第四级,第五级,*,Optical Properties of Condensed Matters,祝 世 宁,引言,:,光学过程的分类，光学系数，复折射率与复介电常数，光学材料,(,绝缘晶体，半导体，玻璃，金属，高分子材料等,),，凝聚态物质光学性质的特征,(,对称性，电子能带，晶格振动，态密度，局域态和集体激发等,),，微观模型,光在凝聚态物质中传播的经典理论,:,光在稠密光学介质中的传播，偶极振子模型，色散理 论，光学各向异性,:,双折射,带间吸收,:,带间跃迁,直接跃迁的跃迁几率，直接带隙半导体的带边吸收，间接带隙半导体的带边吸收，带边以上的带间吸收，吸收谱的测量，光探测材料与器件,激子,:,激子的概念，自由激子，外场中的自由激子，高密度的自由激子，弗仑克尔激子,发光,:,固体中光的发射，带间发光，光致发光，电致发光,量子阱与量子点,:,量子限制结构，半导体量子阱的结构与制备，电子能级，光的吸收与激发，量子限制斯塔克效应，光发射，量子阱子的带间跃迁，,Bloch,振子，量子点,自由电子,:,Plasma,反射率,自由载流子电导，金属，掺杂半导体，,Plasmon,高分子材料,:,高分子材料简介，共轭分子的电子态，高分子光谱，芳烃共轭聚合物，有机光电子学,发光中心,:,电子,声子相互作用，色心，离子晶体中的顺磁杂质，固体激光器与放大器，发光材料,声子,:,红外活性声子，极性晶体红外反射与吸收，极化激元，极化子，非弹性光散射，声子寿命,非线性光学,:,非线性极化率张量，光学非线性的物理起源，二阶非线性效应，三阶非线性效应,光子晶体和光学微腔,:,光子能带，光子晶体的构成，光学微腔，腔量子电动力学简介,Chapter 1,Introduction,1.1 Classification of optical processes,Reflection,Propagation,Transmission,Optical medium,Optical medium,refractive index,n,(,),=,c,/v(,),Snells,law,absorption,resonance,luminescence,spontaneous,emission,elastic and,Inelastic scattering,nonlinear-optics,Propagation,1.2 Optical coefficients,Coefficient of reflection or reflectivity(R):,R,=reflected power/incident power,Transmission or,transmissivity,(T):,T,=transmitted power/incident power,R,+,T,=1,Refractive index(,n,):,Absorption coefficient(,),=-,d I*d z/I,(,z,);,Beers law,:,i,s strong function of frequency,Luminescence,The atom jumps to an excited state by absorption of a,Photon,then relaxes to an intermediate state,before re-,emitting a photon by spontaneous emission as it falls,To the ground state.The photon emitted has a smaller,energy than the absorbed photon.The reduction in the,Photon energy is called the,Stokes shift,.,Scattering,Variation of,n,of the medium on a length scale,smaller than the,of the light,N:the number of scattering,centres,/V;,S:,scattering cross-section;,=N,S,Rayleigh,scattering:,1.3 The complex refractive index and dielectric constant,Complex refractive index,:,extinction coefficient,Where,Complex dielectric constant,The relationship between the real and imaginary,parts of two coefficients:,For,weakly absorbing medium,is very small,The reflectivity(normal incidence):,In the transparent region of material:,is very small,and,2,are negligible,one may consider only the real parts of,n,and,;,In the absorption region,one need to know,both the real and imaginary parts of,n,and,.,1.4 Optical materials,1.41 Crystalline insulators and semiconductors,Transparency range,the index,may be taken to be real with no,imaginary component,(approximately constant n=1.77),R,=0.077,hence,T=,(1,-R,),2,=0.85,Phonon absorption or lattice,absorption,Due to absorption by bound,electrons,Fundamental absorption edge,is determined by the band gap.,The optical properties of semiconductors are similar to,those of insulators,expect that the electronic and phonic,transitions occur at longer wavelengths.Its transparency,range lies outside the visible spectrum,so it has a dark,Metallic appearance.,1.4 Optical materials,1.41 Crystalline insulators and semiconductors,Materials can take on new properties by controlled doping with optically active substance.,Transmission spectrum of ruby(ruby Al,2,O,3,With 0.05%Cr,3+,)compared to,sapphire(pure,Al,2,O,3,).The thicknesses of the two crystals,were 6.1 mm and 3.0 mm,respectively,The principle of doping optically active atoms,into,colourless,hosts is employed extensively,in the crystals used for solid state lasers.A,typical example is the ruby crystal.Rubies,consist of Cr+3 ions doped into Al2O3.In,the natural crystals,the Cr+3 ions are present,as impurities,but in synthetic crystals,the,dopants,are deliberately introduced in controlled,quantities during the crystal growth process.,1.4 Optical materials,1.4.2 Glass,Most types of glasses are made of silica(SiO,2,)with other chemicals.Insulator,all the characteristic features crystalline insulators,the trans range from around 200 nm to,beyond 2000 nm;,Small absorption and scattering losses;,n,changes by,less than 1%over the whole visible spectral region;,Chemicals are commonly added to silica during the fusion,process to alter the refractive index and transmission range;,Stained glass and,colour,glass filter are made by adding,semiconductors with gaps in visible spectral region.,1.4 Optical materials,1.4.3 Metals,Reflect infrared and visible,but transmit,ultraviolet (ultraviolet transmission of metals);,High reflectivity is caused by the interaction of the light with the free electrons in metal;,There is a characteristic cut-off frequency called the plasma frequency.,Reflectivity of silver from the infrared to the,ultraviolet,The molecular materials are held together by the weak van de,Waals,bonds,whereas the molecules are held together by strong covalent bonds.The optical properties of materials are similar to those of the individual molecules;,Saturated compounds:compounds which do not contain any free valence(all the electrons are tightly held in their bonds),and are transparent in the visible,absorb in the infrared and ultraviolet(insulator crystals);,Conjugated molecules(,bezene,C,6,H,6,):The electrons form large delocalized,orbitals,called,orbitals,which spread out across the whole molecule,therefore are less tightly bound than the electrons in saturated molecules.The molecules with visible absorption also tend to emit strongly at visible frequencies(semiconductors);,1.4 Optical materials,1.4.4 Molecular(large organic molecules)Materials,Absorption spectrum of the,polyfluorene,-based,polymers F8.Conjugated polymers such as F8,luminesce,strongly When electrons are promoted,into the excited states of the molecule.The,lumi,-,nescence,is Stokes shifted to lower energy compared,to absorption,and typically occurs in the middle of,the visible spectral region.The emission wavelength,can be tuned by small alternation to the chemical,structure of the molecular unit within the polymers.,The property has been used to develop organic light,emitting devices to cover the full visible spectral region.,What the difference is between condensed matter and atomic or molecular optical physics?,1.5.1 Crystal symmetry,*,long range translational order,Electronic bands,delocalized states,*,point group symmetry,Neumanns principle,The measurable property,point group symmetry,Any macroscopic physical property must have at least the symmetry of the,crystal structure,Optical anisotropy:,birefringence,nonlinear optical coefficient ,1.5 Characteristic optical physics in the condensed matter,Crystal symmetry,Electronic bands,Vibronic,bands,The density of states,Delocalized states and collective excitations,1.5.1 Crystal symmetry,Optical anisotropy:,Lifting of,degeneracies,:,Degeneracy can be lifted by reduction of the symmetry,1.5 Characteristic optical physics in the condensed matter,Splitting of the energy levels of a free atom,by the crystal field effect determined by the symmetry class of the crystal.The splitting,Is caused by the interaction of the,orbitals,of,The atoms with the electric fields of the cry-,stalline,environment.Optical transition between these crystal-field spilt levels,ofen,occur in the visible region,and cause the material to have every interesting properties that are found in the free atoms.,1.5.2 Electronic bands,1.5 Characteristic optical physics in the condensed matter,As the atoms are brought closer together to form the solid,their outer,orbitals,begin to overlap with each other.These overlapping,orbitals,interact strongly,and broad bands are formed.,The electronic states within the bands are,delocalized and possess the translational,invariance of the crystal.Blochs theorem,states that the wave functions:,where,u,k,(,r,)is a function that has the periodicity of the lattice.Each electronic band has a different envelope function,u,k,(,r,),1.5.3,Vibronic,bands,The band arises from the coupling of discrete electronic state to a continuous spectrum of,vibrational,mode.This contrast with the electronic band that arises,from interaction between electronic states of,neighbouring,atoms.,1.5.4 The density of states,This is defined as:,Number of states in the range,E,(,E,+,d E,)=,g(E)d E.,g(E,),is work out in practice:,g(E,),=,g(k),dk,/,dE,This can be evaluated from knowledge of the E-k relationship for electrons or phonons.,1.5.5 Delocalized states and collective excitations,phonon:the collective excitation of lattice vibration;,exciton,:formed from delocalized electrons and holes in semiconductors;,plasmon,:formed from free electrons in metals and doped semiconductors;,many optical effects related to these ,1.5.6 Microscopic models,Classical:Treat both the medium and the light according to classical physics;,Semiclassical,:apply quantum mechanics to atoms,treat light as a classical,electromagnetic wave;,Fully quantum:both atoms and light are treated quantum mechanically.,1.5 Characteristic optical physics in the condensed matter,Exercises:,The complex refractive index of germanium at,400 nm is given by .Calculate for germanium at 400 nm:(a)the phase velocity of light,(b)the absorption coefficient,and(c)the,reflectivity.,Show that the optical density(O.D.)of a sample is related to its transmission T and reflectively R through:,Hence explain how you would determine the optical density by making two transmission measurements,one at wavelength,where the material absorbs,and the other at a wavelength where the material is transparent.,