橡塑合金产品说明书中英文.doc

橡塑合金 产品说明书RUBBER-PLASTIC ALLOYS (NBR/PVC Blends) Production manual 本公司的“橡塑合金”是丁腈橡胶（NBR）与聚氯乙烯（PVC）的熔融共混胶。由于丁腈橡胶与聚氯乙烯有很好的相容性，两种材料可以用任何比例进行共混。 The companys Rubber-Plastic Alloy is a NBR and PVC melting blends. Because the good compatibility of NBR and PVC, two materials can be blended with any proportion. “橡塑合金”为非污染型浅黄色胶片.牌号、技术参数、重要特性和特殊用途见下表“Rubber-Plastic Alloys”, non polluting light yellow films. Thier trademark, technical parameters, main characteristics and special usage are in the table below: 牌号NBR的丙烯 腈含 量 % 共混比(NBR/PVC)典 型门尼粘度ML(1+4)100 特 性特殊用途耐臭氧耐候性耐油耐溶剂性抗燃油透过性耐磨抗撕强度阻燃性耐寒性挤出压延工艺NV7218 18 70/30 60BCBCDBCAAAB耐寒优，适宜生产胶辊、安全靴、胶管NV5070 28 70/30 55BABBCBAABA耐寒优良，挤出压延性能优NV5075 33 70/30 55AABABABABA与金属及织物粘合性佳，挤出压延性优NV5495 33 70/30 65AABABABABA工艺性能优。可与国外相称品牌匹比NV7050 33 70/30 45 AABABABABA制品表面光洁度高，工艺性能佳NV6420 33 60/40 65AABABAABCA耐磨、屈挠性优异，宜生产胶辊、输送带NV5093 40 70/30 75AAAAADA耐臭氧及屈挠性能优，适宜生产纺织器材Trade-markAcrylonitrile content of NBR ,%(NBR/PVC),%Typical Mooney viscosityML(1+4)100NV7218 18 70/30 60NV5070 28 70/30 55NV5075 33 70/30 55NV5495 33 70/30 65NV7050 33 70/30 45 NV6420 33 60/40 65NV5093 40 70/30 75Trade-mark Feature特殊用途Ozone andweatherresistanceOil andsolvent resitanceAnti-fuel permeabilityWear and tear strengthFuel re-tardanceCold re-sistanceExtrudingand calen-deringSpecial UsageNV7218BCBCDBCAAABExcellent cold resistanse, suitable for production of rubber rollers, safety boots, rubber hoseNV5070BABBCBAABAExcellent cold re resistance, excellent extruding and calendering performanceNV5075AABABABABA good adhesion with metalsand fablics, excellent extrudingand calendaringperformaceNV5495AABABABABAExcellent processing property. Can be compared with foreign brands ratherNV7050AABABABABAGlossy surface onProducts,good processing propertyNV6420AABABAABCAExcellent wear and flexresistance, f should produce rubber roller, conveyor beltNV5093AAAAADAExcellent flexAnd ozone resistance, suitable for production of textile equipment 橡塑合金的特点 Characteristics of NBR/PVC Blend： 与丁腈橡胶相比，橡塑合金有如下优点：Compared with the nitrile rubber, NBR/PVC Blend has the following advantages： 耐臭氧性和耐候性（耐臭氧龟裂性和耐阳光龟裂性）显著提高。 Ozone resistance and weather ability（Resistance to ozone cracking and Sunshine cracking resistance）Significantly increased 在标准臭氧老化实验条件下（臭氧浓度50pphm、拉伸20%、温度40）实验72小时，橡塑合金不龟裂(化学工业合成材料老化质量监督检查中心和上海市橡胶制品研究所检查报告)，而丁腈橡胶则严重龟裂（见照片）。在更苛刻的条件下（臭氧浓度370520pphm、拉伸40%、温度40）实验96小时，橡塑合金也不龟裂(沈阳橡胶四厂研究所检测报告)l 50pphm20%4070h臭氧老化实验后试样表面状况 丁腈橡胶（丙烯腈含量33%） Nitrile Rubber (Acrylonitrile content 33%) 橡塑合金（共混比70/30、 丙烯腈含量33%） NBR/PVC Blend (blend ratio 70 /30, Acrylonitrile content 33%)After 72 hours testing under a standard ozone aging conditions (Ozone concentration50pphm, extend 20%,tempreture 40), NBR/PVC Blend does not cracks , but the NBR is severely cracking(seeing the photo). Under more severe conditions, (Ozone 370-520pphm X 40%, X 40) After 96 hours testing, NBR/PVC Blend is still not cracking. 耐油、耐溶剂和耐化学药品性能提高。 Oil, solvent and chemical resistance increase橡塑合金与丁腈橡胶的耐油性均随丙烯腈含量的增长而提高，在丙烯腈含量同等的情况下，橡塑合金明显优于丁腈橡胶。增长PVC的比例，橡塑合金的耐油性提高。Oil resistance of NBR/PVC Blend and nitrile rubber with acrylonitrile contents were increased with the increase, Acrylonitrile content in the same case, NBR/PVC Blend is superior to NBR. Increase the proportion of PVC, the blend increased oil resistance. 图中英文更改 左in No.3 Oil ，volum e change ，NBR，NBR/PVC右in No.2 OilI ，volume change 英文更改：左in fuel B 右in fuel B左 Tensile strengthn retention 右volume change左 NBR/PVC Blend 右 Blend ratio 燃油透过率明显减少，并且丙烯腈含量越高。 Permeability of fuel decrease obviously, and the higher the acrylonitrile content, the lower the permeability 英文更改左 in fuel C 右 in fuel M 15左，右 volume change左，右 NBR NBR/PVC blend（70/30）【Note A】 【注A】 1.标准实验油（standard test oils） 2号油苯胺点933； No.2 Oil Aniline Point 933； 3号油 苯胺点701； No.3 Oil Aniline Point 701； 2.实验用燃油（以下组成均为体积比）2. Test fuels（the following componentare volume ratio）燃油B 甲 /异辛烷（30/70）, 模拟普通汽油（无添加剂）Fuel oil BToluene / isooctane(30/70), Simulation of reg ular gasoline(no-additive) 燃油C 甲苯/异辛烷（50/50）模拟高芳烃含量汽油； Fuel C- toluene/isooctane(50/50) , Simulation of high aromatic content of gasoline 燃油E-10燃油B/乙醇（90/10）， 模拟中、美使用的乙醇汽油； Fuel E-10Fuel B/ethanol(90/10), Simulation china and the U.S. use ofThe ethanol gasoline. 燃油M-15燃油C/甲醇（85/15）, 模拟欧洲使用的甲醇汽油； Fuel M-15fuelC/ Methanol(85/15),Simulation methanol fuel used in Europe; 燃油M-85燃油C/甲醇（15/85）， 模拟欧洲特种车辆使用的燃油。FuelM-85-fuelC/ Methanol(15/85),Simulation special vehicles fuel used in Europe 以上各图的英文修改： 透过率-Permeability燃油C透过率 Permeability of fuel C燃油透过率Permeability of fuelsFuel B, Fuel C,fuel E-10,fuel M15,Fuel M85 耐磨性和撕裂强度提高。 Abrasion resistance and tear strength increased 以下图的英文修改：左- 耐磨性Abrasion resistance 右- 撕裂强度tear strength左- 阿克隆磨耗Akron abration 右- 同上左-丙烯腈含量- Acrylonitrile content 右-共混比blend ratio 丁腈橡胶- NBR 橡塑合金-NBR/PVC Blend 阻燃性提高。氧指数是衡量高聚物是否易燃的一项重要指标：氧指数越小，则越容易燃烧。氧指数21的材料，一般在空气中很容易燃烧。如下图可见，丁腈橡胶属易燃材料。由于聚氯乙烯树脂的含氯量达56%左右，氧指数40，属自熄性材料。丁腈橡胶与聚氯乙烯共混的“橡塑合金”，氧指数比丁腈橡胶高，使阻燃性提高 improve flame retardance. Oxygen index is a measure of whether the combustible polymer is an important indicator: the smaller the oxygen index, the more easy to burn. Oxygen index 40, is self-extinguishing material. Oxygen index of NBR/PVC Blend higher than the nitrile rubber to improve the flame retardancy 上图英文：阻燃性（生胶）Flame retardance ( raw rubber),氧指数 Oxygen index 加工性能改善。与丁腈橡胶相比，挤出速度加快、挤出口型膨胀减少、表面光洁。对压延和模压制品的加工和外观质量都有改善。 processing property improvement. Compared with the NBR, faster extrusion, die swell reduction, smooth surface.processing and appearance of calendered and molded products has improved. 上图的英文： 挤出速度extrusion speed 挤出膨胀率 die swell 橡塑合金的局限性：压缩永久变形及耐寒性比丙烯腈含量相同的丁腈橡胶要差。但是，通过合理选择牌号、并用以及配方调整，可以填补局限性、改善性能。 上图英文：压缩永久变形 compression set 耐寒性 cold resistance 脆性温度 brittleness temperature 【说明】 以上橡塑合金与丁腈橡胶性能对比图例是供客户选用作参考。使用不同的助剂、配方以及工艺条件，会获得不同的性能数据。【Description】 above rubber alloy compared with the NBR is for customers to use the legend for reference. Using different additives, formulation and process conditions, will be different performance data. 橡塑合金的重要应用 胶管 燃油胶管、液压胶管的内、外层胶，消防胶管； 电线、电缆 耐油电缆护套、矿用电缆护套、阻燃电缆护套、船用电缆护套； 纺织配件 纺织皮圈、纺织皮辊； 胶辊 印刷胶辊（墨辊、酒精润版辊、UV油墨辊）、橡塑并用胶辊； 输送带 阻燃输送带、耐油输送带； 密封件 密封垫圈、高硬度防尘圈、防尘罩、密封条； 胶板 耐油胶板、阻燃地板； 胶布 软体贮油制品（油箱、油囊、油罐）； 鞋底 安全鞋、远动鞋。 其他耐油工业配件 The main application of NBR/PVC Blend: Hose - Outer and inner ruuer of fuel hose and hydraulic hose, fire hose; Wires, cables - Oil resistant cable jacket, mine cable sheath, flame retardant cable jacket, marine cable sheath; Textile Accessories - Textile apron, textile roller; Roller - printing rubber roller (roller, alcohol dampening rollers, UV ink roller), industrial rubber rollers Conveyor Flame retardant and oil resistant conveyor belt; seals - sealing gaskets, high hardness dust ring, automobile dust cover Rubber sheet - oil resistant rubbersheet, flame retardant floor; Rubber coated fabric- oil storage products (fuel tank, oil bag, tank); shoes - safety shoes, sports shoes Other oil resistant industry parts 配方举例 Formulation example 【说明】以下举例系初始配方，仅供参考。客户需根据产品的技术规定、使用的橡胶原材料、生产设备、工艺条件以及成本的具体情况设计合理的生产配方。 1. 胶管 （1）燃油胶管内层胶 橡塑合金（NV5495）100、氧化锌 5、硬脂酸 2、防老剂RD 1、防老剂4010NA 1、 N550炭黑 20、N770炭黑60、增塑剂DOP 20,、增塑剂TCP 20、古马隆树脂 8、 促进剂CZ 1.5、 促进剂TMTD 0.5、硫黄 0.5，合计239.5 （2）钢丝编织胶管外层胶 橡塑合金（NV5075）100、丁苯橡胶（1500）30、氧化锌5、硬脂酸1、防老剂RD1、 防老剂 4010NA 2 、石蜡 1、N550炭黑30、N770炭黑50、增塑剂 DOP 25、 环烷油5、古马隆树脂6、促进剂CZ 1.5、促进剂TMTD 0.2、硫黄2，合计259.7【Description】 The following example line initial formula for reference only. Customer technical requirements based products, the use of rubber raw materials, production equipment, process conditions and specific conditions designed cost of production formula. 1. Hose (1) The inner rubber of fuel hose NV5495 100, 5 zinc oxide, stearic acid 2, antioxidant RD 1, antioxidant 4010NA 1, N550 carbon black 20, N770 Carbon Black 60, plasticizer DOP 20, plasticizer TCP 20, coumarone resin 8 ,Accelerator CZ 1.5, accelerator TMTD 0.5, sulfur 0.5, Total 239.5 (2) Outerrubber of steel wire braided rubber hose NV5075 100, SBR (1500) 30, zinc oxide 5 stearic acid 1, antioxidant RD1, Antioxidant 4010NA 2, paraffin 1, N550 carbon black 30, N770 carbon black 50, plasticizer DOP 25, Naphthenic oil 5, 6, coumarone resin, accelerator CZ 1.5, accelerator TMTD 0.2, sulfur 2, Total 259.7 2 电缆 （1）普通电缆护套 橡塑合金(NV5075) 100、氧化锌5、硬脂酸2、防老剂RD 1、防老剂4010 NA 1、 N550 炭黑 10、白炭黑30、滑石粉40、氢氧化铝50 、三氧化二锑 5、增塑剂 DOP 10、 氯化石蜡（52） 15、 促进剂 DM 0.3、促进剂TMTD 0.5 硫黄0.3，合计270.1 （2）阻燃电缆护套 橡塑合金(NV5075) 100、氧化锌5、硬脂酸2、防老剂RD 1、防老剂MB 1、N550 炭黑5、白炭黑50、超细滑石粉 20、超细氢氧化铝 50、三氧化二锑 10、阻燃剂 氯化石蜡（70）10、增塑剂氯化石蜡（52）10、硅烷偶联剂A-189 0.8、促进剂DM 0.3、促进剂TMTD 0.6、硫黄0.5、交联剂DCP(40%) 1, 合计 267.22 cable (1) General Cable jaketNV5075 100, 5 zinc oxide, stearic acid 2, antioxidant RD 1, Antioxidant 4010 NA 1, N550 10 carbon black, silica 30, talc 40, aluminum hydroxide 50,antimony trioxide 5, plasticizer DOP 10, Chlorinated paraffin (52) 15, Accelerator DM 0.3, ,accelerator TMTD 0.5,Sulfer o.3, Total 270.1 (2) flame-retardant cable jacket NV5075 100, 5 zinc oxide, stearic acid 2, antioxidant RD 1, Antioxidant MB 1, N550 carbon black 5, silica 50, super-fine talc20, 50 super-fine aluminum hydroxide, antimony trioxide 10, flame retardant Chlorinated paraffin (70) 10, plasticizer chlorinated paraffin (52) 10, silane coupling agent A-189 0.8, accelerator DM 0.3, Accelerator TMTD 0.6, sulfur 0.5, cross-linking agent DCP (40%) 1, Total 267.2 3 纺织配件 （1）纺织皮圈 橡塑合金（NV5093）100、氧化锌5、硬脂酸1、防老剂2246 1、防老剂MB 0.5、 白炭黑 15、钛白粉 10、增塑剂DOP 12、液体丁腈橡胶10、抗静电剂SN 0.5、 着 色剂适量、促进剂DM 2.8、硫黄2 .3，合计 160.1+ （2）纺织皮辊 橡塑合金（NV5093）100、氧化锌4、硬脂酸0.5、防老剂2246 1.5、白炭黑30、 明胶30、钛白粉 15、增塑剂DOP15、抗静电剂SN1.5、促进剂DM1.5、硫黄10、 着色剂适量，合计210.5+3 Textile Accessories(1) textile apronNV5093100, zinc oxide 5 stearic acid 1, antioxidant 22,461, antioxidant MB 0.5, silica 15, titanium dioxide 10, plasticizer DOP 12, liquid NBR 10, antistatic agents SN 0.5, pigment appropriately, accelerator DM 2.8, sulfur 2.3, Total 160.1 +(2) textile rollerNV5093 100, 4 zinc oxide, stearic acid 0.5, Antioxidant 2246 1.5, silica 30, gelatin 30, pigment titanium dioxide, 15, plasticizer DOP 15, antistatic agents SN 1.5, accelerator DM1.5 , sulfur 10, pigment appropriately,total 210.5 + 4 胶辊 （1）印刷胶辊（硬度30A） 橡塑合金（NV 6420）100、氧化锌10、硬脂酸1、氧化镁3、防老剂2246 1、白 炭 黑 15、钛白粉 5、增塑剂DOP 60、液体丁腈橡胶 30 、专用油膏10、促进剂DM 0.6、 促进剂 TMTD0.3、促进剂TMTM 0.6、硫化剂DTDM 1.2、硫黄0.3、着色剂适 量，合计 237+ （2）耐油胶辊（硬度60A） 橡塑合金（NV 5075）100、氧化锌5、硬脂酸1.5、氧化镁3、防老剂RD 1、防老剂 4010NA 1.5、N550炭黑 30、白炭黑15、增塑剂DOP 30、石油树脂 10、促进剂TMTD 0.2、硫化剂DTDM 1.5、硫黄1.5，合计200.24 Roller(1) printing roller (hardness 30A)NV 6420230, 10 zinc oxide, stearic acid 1, magnesium oxide 3 Antioxidant 2246 1, silica15, titanium dioxide, 5, plasticizer DOP 60, liquidNBR 30 , special factice 10, accelerator DM 0.6, accelerator TMTD0.3, accelerator TMTM 0.6, curing agent DTDM 1.2, sulfur 0.3, pigment appropriately ,total 237 +(2) Oil resistant roller (Hardness 60A)NV 5075 100, 5 zinc oxide, stearic acid 1.5, MgO 3, antioxidant RD 1, antioxidant 4010NA 1.5, N550 carbon black 30, silica 15, plasticizer DOP 30, petroleum resin 10 , Accelerator TMTD 0.2, curing agent DTDM 1.5, sulfur 1.5, Total 200.2 5 输送带 * 阻燃输送带覆盖胶 橡塑合金（NV6240）100、氧化锌3、硬脂酸2、防老剂4010NA 1、防老剂BLE 2、 石蜡1、N220炭黑30、氯化石蜡（70）10、氯化石蜡（52）15、增塑剂DOP 8、古 马隆树脂5、三氧化二锑 5、氢氧化铝 15 、硼酸锌15、促进剂CZ 1、硫黄1.5，、 合计 214.55 conveyor belt* Flame-retardant conveyor belt coverNV6240 100, zinc oxide 3, stearic acid 2, antioxidant 4010NA 1, antioxidant BLE 2, paraffin 1, N220 carbon black 30, chlorinated paraffin (70) 10, chlorinated paraffin (52) 15 plasticizer DOP 8, coumarone resin, 5, antimony trioxide 5, aluminum hydroxide,15, zinc borate 15, accelerator CZ 1, sulfur 1.5, total 214.5 6 密封件 （1）防尘密封圈（高硬度8590A