固相微萃取SPME应用指南 英文版.pdf

T199925B2001 Sigma-Aldrich Co.Table of ContentsApplication AreaPageBooks1Foods1Polymers and Coatings12Natural Products12Pharmaceuticals16Biological Matrices16Toxicology16Forensics29EnvironmentalWater30Pesticides44Soil48Air51Theory and Technique53Supelco SPME Publications63SPME Products64SPMEApplications Guide3rd EditionSPME Applications GuideThe SPME Applications Guide is a bibliographic resource of more than 750 published technical articles about solid phasemicroextraction.With the continued growth of SPME,and its expansion into environmental,food,forensic,and other fields,werecognize the need for an organized bibliography.This guide should serve a useful purpose in your SPME research and analyses.This guide is for general information only.We have made every attempt to make the information as complete and accurate as possible.Where entries are missing,information was not available at the time of printing.The new additions to the reference list are highlighted in bold.NOTE:Because of copyright restrictions,Supelco cannot provide copies of the articles listed.If you desire copies,please refer to thepublications cited.Using This GuideThis guide is organized in an easy-to-use format.The references are grouped into application areas(see the Table of Contents).TheAnalyte/Matrix column identifies the class of analytes and the sample matrix.The Literature Reference column provides the title of thearticle,journal reference,and authors.The next column describes the SPME fiber and conditions used in the sample extraction.Thelast column indicates the instrument used in the analysis.Key to AbbreviationsAbbrev.DescriptionAEDatomic emission detectionDVBdivinylbenzeneECDelectron capture detectionFIDflame ionization detectionFPDflame photometric detectionFTDflame thermonic detectionGCgas chromatographyHPLChigh pressure liquid chromatographyICPinductive coupled plasmaMSmass spectrometryMSDmass selective detectionNPDnitrogen/phosphorus detectionPADphotodiode-array detectionPDMSpolydimethylsiloxanePICIpositive ion chemical ionizationSIMselective ion monitoringTCDthermionic-selective detectionTEDthermal energy detectionVISvisible spectrophotometryBulletin 925BT199925B2001 Sigma-Aldrich Co.SPME Application Guide 3rd EditionSPME Fiber/Analyte/Extraction MatrixLiterature ReferenceConditionsInstrumentBooksTechniques for Analyzing Food Aroma,Marcel Decker ISBN:0-8247-9788-4,Marsili,R.Solid Phase Microextraction:A Practical GuideEdited by SueAnn Scheppers WercinskiMarcel Decker 15BN:0-8247-7058-7Applied SPME,1999,364-371 Royal Society of Chemistry,Cambridge,UK Coden:67TUA8Talon,R,Montel,M.Solid Phase Microextraction:Theory and PracticeEdited by Janusz PawliszynVCH,New York,275pp(1997)Applications of Solid Phase MicroextractionEdited by Janusz PawliszynRSC Chromatography Monographs ISBN 0-85404-525-2Royal Society of Chemistry 1999Foods601Aroma compoundsDevelopments in extraction techniques and their Review articleGCin foodapplication to analysis of volatiles in foodsTrends-Anal-Chem,May 2000,19(5),322-329Sides,S.,Robards,K.,Helliwell,S.602ContaminantsApplication of SPME in Food AnalysisReview articleGC,LC,MSin FoodJ.Chromatogr.A(2000),880(1+2),35-62Kataok,H.,Lord,H.,Pawliszyn,J.8Caffeine and flavorsSolventless Determination of Caffeine inuncoated fiberGC-MSin coffee/tea/colaBeverages Using SPME with Fused Silica Fibers5 minJ.Chromatogr.603:185-191(1992)Hawthorne,S.,Miller,D.,Arthur,C.,Pawliszyn,J.32Flavors inSolid Phase Microextraction for Flavor Analysis100m PDMSGC/GC-MScoffee/fruit juice/J.Agric.Food Chem,42:1925-1930(1994)10 minvegetable oilPeppard,T.,Yang,X.603VolatilesAnalysis of volatile contaminants in vegetable oils byCarboxen/PDMSGC-MSin vegetable oilheadspace SPME with Carboxen-based fibers.30-45 min 100CJ.Chromatogr.873(2000):79-94headspacePage,B.,Lacroix,G.39Halogenated volatilesApplication of SPME to the Headspace GC Analysis ofGCin foodHalogenated Volatiles in Selected FoodsJ.Chromatogr.648(1):199-211(1993)Page,B.,Lacroix,G.41Fatty acids C2-C10 Determination of Fatty Acids Using SPME85m polyacrylateGC/GC-MSin water Anal.Chem:67:4396-4403(1995)Low pH,saltPan,L.,Adams,M.,Pawliszyn,J.derivative:1-pyrene-diazomethane42Flavors in Measuring Flavors Using SPME100m PDMSGC-MScorn oilFood Quality January/February 1995,pp40-4140C,45 minMindrup,R.181Flavors in SPME Associated with Microwave Assisted 100m PDMSSIM GC-MScoffee,potato chipsExtraction of Food ProductspH 2,saltJ.High Res.Chromatogr.20(4):213-216(1997)headspaceWang,Y.,Bonella,M.,Khaled,M.,McNair,H.10 min Ambient temperature,unless otherwise indicated.1SPME Fiber/Analyte/Extraction MatrixLiterature ReferenceConditionsInstrument60Sulfur volatiles in Headspace SPME Analysis of Volatile Organic Sulfurtruffle aromaCompounds in Black and White Truffle AromaJ.Agric.Food Chem,43(8):2138(1995)Pelusio,F.,Nilsson,T.,Tino,R.,Larsen,B.,Montnarell,L.604Aroma compoundsDetermination of major aroma impact compounds in GC-MSin fermented fermented cucumbers by SPME-GC-MS-cucumbersOlfactometry detectionJ.Chromatogr.Sci.(2000),38(7),307-314Marsili,R.,Miller,N.61Flavors in SPME of Flavor Compounds-A Comparison of Two Fiber100m PDMS,GC-FIDcinnamon barkCoatings and Discussion of the Rules of Thumb for Adsorption85m polyacrylateLC-GC 13(11):882-886(1995)120CYang,X.,Peppard,T.headspace62Flavors inSPME and Chiral Gas Chromatography Separations100m PDMSGC-FIDapple essence,LC-GC 13(9):734-740(1995)30C or 40Cseeds,candyMani,V.,Woolley,C.headspace63Essential oils inDetermination of Essential Oils in Hops by Headspace SPME100m PDMSGC-FIDhopsJ.Agric.Food.Chem,44:1768-1772(1996)50C,4 hrField,J.,Nickerson,G.,James,D.Heider,C.605Essential oilsProduction of Yarrow(Achillea millefolium L.)in Norway:in yarrowEssential Oil Content and QualityJ.Agric.Food Chem,(2000)48 No,12,6205-6209Rohloff,J.,Skagen,E.,Steen,A.,Iversen,T.221Essential oils in A Comparison of Selected Analytical Approaches to the100m PDMSGC-MSVirginia cedar oilAnalysis of an Essential Oil10-120 secFlavour and Fragrance Journal 12(1):1-8,(1997)headspaceColeman,W.,Lawrence,B.396Essential oils in Automatic Injection SPME-Chiral-GC-MSD Analysis of 7m PDMSGC-MSVirginia cedar oilEssential Oils6 secJ.Chromatographic Sci.,Vol.36,Dec.1998,575-578headspaceColeman,W.,Perfetti,T.,Lawrence,B.stirring444Volatiles inIdentification of Volatile Compounds in Sunflower Oil100m PDMSGC-MSsunflower oilby Headspace SPME and Ion-Trap GC/MSJ.High Resolut.Chromatgr.(1998),46(7),2744-2747Keszler,A.,Heberger,K.,Gude M.56912 AldehydesInfluence of extraction parameters and medium on 100m PDMSGC-MSin sunflower oil/waterefficiency of SPME sampling in analysis of aliphatic aldehydes30 min 40CJ-Chromatogram-A.11 Jun 1999;845(1-2):337-347 headspaceKeszler,-A;Heberger,-K 447XyleneDetermination of trace xylene in contaminated palm 100m PDMSGC-FIDin palm oiloil by SPME and capillary GC1 min.60CFenxi Huaxue(1999),27(6),676-678headspaceChen,W.,Guo,C.,Hu,C.577Dimetyl disulfide&Volatile reduced sulfur compounds in butter by SPME85m polyacrylateGC-EID methanethiolJ-Dairy-Res.Feb 1999;66(1):115-123 10 min.30-35Cin butterShooter,-D;Jayatissa,-N;Renner,-N 338Benzene,tolueneDetermination of benzene&toluene in vegetableHPLCin vegetable oiloil by SPME/HPLCheadspaceJ.Commod.Sci.(1999),38(1),3-14Giuffrida,R.,Clasadonte,M.,Zerbo,A.Ambient temperature,unless otherwise indicated.2SPME Fiber/Analyte/Extraction MatrixLiterature ReferenceConditionsInstrument606VolatilesHeadspace SPME use for the Characterization of volatile Carboxen/DVB/PDMSGC-FIDin vegetable oilcompounds in vegetable oils of different sensory quality20-60CJ.Agric Food Chem,(2000),48(6),2360-2367headspaceJelen,H.,Obuchowska,M.,Zawirska-Wojtasiak,R.106Flavors in Characterization of Beer Samples Using SPME-GC Analysis100m PDMSGC-FIDbeerSupelco Reporter Vol.16,#4,pg.710 minVas,G.607Sulfur compoundsDetermination of sulfur compounds in beer using headspaceCarboxen/PDMSGC-FPDin beerSPME and GC analysis with pulsed FPD detectorheadspaceJ.Chromatogr.A.(2000),872(1+2),203-213Hill,P.,Smith,R.100Flavors Characterization of Commercial Vodkas by SPME-GC/MS100m PDMSGC-MSin vodkaJ.Sci.Food Agric.70:380-388(1996)1 hrNg,L.,Hupe,M.,Harnois,J.,Moccia,D.202MethylcyclopendienylDetermination of Methylcyclopendienyl Manganese Tricarbonylmanganese in Beverages by SPMEtricarbonylFood Addit.Contam.14(3):301-307(1997)in beveragesForsyth,D.,Dusseault,L.395Aroma volatiles Determination of Fresh Onion(Allium Cepa L)Volatiles 100m PDMSGC-MSin onionby SPME Combined with GC/MS1 minZ Lebedsm Unters Forsch A(1998)207:39-43headspaceJarvedpaa,E.,Zhung,Z.,Huopalahti,R.,King,J.101Flavors SPME for Cheese Volatile Compound Analysis100m PDMS,GC,GC-MSin cheeseJ.Food Sci.61:1118-1129(1996)polyacrylateChin,H.,Bernhard,R.,Rosenberg,M.60C,20 min380Aroma volatilesPattern Recognition of Swiss Cheese Aroma Compounds by 85m polyacrylateGC-FIDin cheeseSPME/GC and an Electronic Nose40C,30 minMilchwissenscaft(1998)53(5)259-263headspaceJou,K.,Harper,W.449Aroma volatilesCryo-trapping/SPME/GC analysis of cheese aroma100m PDMSGC-FID,EMSin cheeseTalanta(1999)48(4),747-7534 min 20CJaillais,B.,Bertrand,V.,Auger,J.headspace187Volatiles in A Study of Volatile Trapping in Spray-Dried Whey ProteinGC-MSwhey proteinConcentrate by Crushing and/or Vacuuming and Detection by SPME/GC-MSFood Res.Int.29:495-504(1996)Stevenson,R.,Chen,X.379Volatiles inUse of SPME of Volatile Compounds in Whey Protein85m polyacrylateGC-MSwhey proteinConcentrates40C,30 minMilchwissenschaft(1998)53(4)209-212headspace,stirringYang,J.,Li,W.,Harper,W.450Volatiles inHeadspace sampling of whey protein concentrate GC-MSwhey proteinsolutions using SPMEheadspaceFood Res.Int.(1999),31(5),371-379Le Quanch,M.,Chen,X.,Stevenson,R.422Flavors in Isolation of Flavor Compounds from Protein MaterialproteinACS Symp.Ser.(1998),705(Flavor Analysis),107-115Mills,O.,Broome,A.102Flavors in Qualitative and Quantitative Analysis of Flavor Carbowax/DVBGC-MStobaccoAdditives on Tobacco Products Using SPME-GC-MS95C,15 minJ.Agric.Food Chem.45:844-849(1997)headspaceClark,J.,Bunch,J.Ambient temperature,unless otherwise indicated.3SPME Fiber/Analyte/Extraction MatrixLiterature ReferenceConditionsInstrument137Phenols in Quantitative Determination of Phenols in Mainstream Smoke PolyacrylateGC-MStobacco smokewith SPME-GC Selected Ion Monitoring MSBuffer,1 hrJ.Chromatogr.Sci.34:272-275(1996)Clark,J.,Bunch,J.608AcetatesQuantitative analysis of acetates in cigarette tobacco GC-MSin Cigarette tobaccousing SPME and GC-MSJ.Chromatogr.Sci.(2000),38(4),137-144Watxon,C.,Ashley,D.369Carboxylic acid esters Derivatization of SPME GC-MS Determination of 85m polyacrylateGC-MSin tobaccoOrganic Acids in Tobacco15 min,stirringJ.Chromatographic Science,Vol.35,(1997)209-212MeOH-HCl derivativesClark,J.,Bunch,J.431Phenols inApplication of SPME in Determination of Phenol in HoneyhoneyRiv.Sci.Aliment,(1997)26(3/4),97-102Conte,L.,Botolomeazzi,R.,Moret,S.,Sibaini,A.,Marcazzan,G.433Volatile organicsIdentification of Volatile Organic Compounds PresentGC-MSin honeyin Different Honeys Through SPME and GC/MSInd.Alimenti.,(1998),37(368),351-356Guidotti,M.,Vitali,M.109Aroma volatiles in Comparison of Dynamic Headspace Concentration 100m PDMS,GC-MScarbonated cola on Tenax with SPME for Analysis of Aroma Volatiles85m polyacrylatebeveragesJ.Agric.Food Chem.45:2638-2641(1997)60C,30 minElmore,S.,Erbahdir,M.,Mottram,D.headspace349Aroma volatiles in SPME Applications in Gas Chromatography Olfactometry 100m,30m,7m PDMSGC-FIDbrewed coffeeDilution Analysis1-90 minJ.Agric.Food Chem.1999,47,1616-1618headspace,stirringDeibler,K.,Acree,T.,Lavin,E.119Aroma inSolid Phase Microextraction:A Valuable Problem Solvervarious fibers&food productsFood Product Design December 1996,pp 73-77extraction conditionsMarsili,R.128Flavor volatiles inAnalysis of Flavor Volatiles Using Headspace SPME85m polyacrylateGC-FIDfruit juiceJ.Agric.Food Chem.44:2187(1997)60 min,salt addedSteffen,A.,Pawliszyn,J.headspace,stirring609Aroma compoundsScreening of Brazilian fruit aromas using SPME-GC-MSvarious fibersGC-MSin Brazilian fruitJ.Chromatogr.A.,873(1),117-127headspaceAugusto,F.,Valenta,A.,dosSantos,T.,Rivellino,S.425Volatiles Analysis of Volatile Fruit Components by Headspace100m PDMSGC-MSin fruitSolid Phase Microextraction30 min 30CFood Chem.(1998),63(2),281-286headspaceIbanez,E.,Lopez-Sebastian,S.,Ramos,E.,Tabera,J.Reglero,G.130Flavor volatiles in Flavor Volatiles in Fruit Beverage with Automated SPME100m PDMS,GC-FIDfruit beverageFood Test.Anal,16:2(1996)85m polyacrylatePenton,Z.20 min,headspace424Oxidative byproductsChanges in Citrus Hystrix Oil During Autoxidationin citrus hystrix oilDev.Food Sci.(1998),40(Food Flavors:Formation,Analysis and Packaging Influences),707-718Pudil,F.,Wijaya,H.,Janda,V.,Volfova,J.,Valentova,H.,Porkorny,J.Ambient temperature,unless otherwise indicated.4SPME Fiber/Analyte/Extraction MatrixLiterature ReferenceConditionsInstrument358Flavor compoundsOptimization of SPME Analysis for Headspace 100m PDMSGC-FIDin orange juiceFlavor Compounds of Orange Juice60C,20 minJ.Agric.Food Chem.1998,46,2744-2747headspace,stirringJia,M.,Zhang,H.,Min,D.451Flavor compoundsPulsed electric field processing effects on flavor in orange juicecompounds and microorganism of orange juiceFood Chem(1999),65(4),445-451Jia,M.,Zhang,Q,Min,D.561Flavor compoundsVolatiles from Unpasteurized and Excessively 75m Carboxen/PDMSGC-MSin orange juiceheated orange juice with SPME and 30 min HeadspaceGC Olfactometry40CJ.Food Science,Vol.64,N0.5,1999,800-803Bazemore,R.,Goodner,K.Rouseff,R.359Flavors inComparison of Gas-Sampled and SPME-Sampled Static 65m PDMS/DVBGC-MSfruit juicesHeadspace for the Determination of Volatile Flavor Compounds40C,30 min Anal.Chem.Vol.71,No.1,January 1,1999,pg 23-27headspaceMiller,M.,Stuart,J.131Flavor volatilesSolid Phase Microextraction for Quantitative 100m PDMSGC-MSin applesHeadspace Sampling of Apple Volatiles30 minAnal.Chem.68:4114(1996)headspaceMatich,A.,Rowan,D.,Banks,N.203Flavor volatilesRapid Analysis of Volatile Flavor Compounds in 100m PDMSGC-FIDIn applesApple Fruit Using SPME&GC-Time-of-Flight Mass Spec2-8 minJ.Agric.Food Chem.45:1801-1807(1997)headspaceSong,J.,Gardner,B.,Holand,J.,Beaudry,R.433Volatiles inVolatile Production and Fruit Quality During Development red delicious applesof Superficial Scald in Red Delicious ApplesFood Res.Int.(1997),30(2),95-103Paliyath,G.,Whiting,M.,Stasiak,M.,Murr,D.,Clegg,G.383Flavor volatiles in Application of SPME and GC/Time-o-Flight Mass65m PDMS/DVBGC-MStomato,strawberrySpectrometry for Rapid Analysis of Flavor Volatiles23C,12 minin Tomato and Strawberry FruitsheadspaceJ.Agric.Food Chem.46:3721-3726(1998)Song,J.,Fan,L.,Beaudry,R.452Flavor volatiles inA new concept for the measurement of total tomato,strawberry,volatile compounds of foodraspberries,applesZ.Lebenam.Unters,Forsch A,1999,208(4),254-258Azodanlou,R.,Darbellay,c.,Luisier,J.,Villettaz,J.,Amode,R.387Flavor volatilesComparison of Three Sample Preparation Techniques for the 100m PDMSGC-MSin tomatoDetermination of Fresh To