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1、AA大学“国家建设高水平大学公派研究生项目”研修计划Research Plan for CSC Scholarship Program, AA姓名/NameXxxxxxxxx学号/Student IDxxxxxx性别/GenderMale出生年月日/Date of birthXxxxxxxx所在学院/CollegeXxxxxxxxxxx所学专业/MajorXxxxxxxxxx国内导师/Domestic supervisor Xxxxxxxx留学国别/Hosting foreign country Xxxxx留学院校/Hosting foreign institution Xxxxxxxx留学院

2、系/Hosting faculty or department Xxxxxxxxx国外导师/Hosting foreign supervisor Xxxxxx学习期限/Duration of study xxx months (from xxxxx to xxxxx) 研究课题名称 Research Title:Minimization of energy requirement for producing solid fuel from sewage sludge employing hydrothermal treatment科研课题背景介绍Research Background:In C

3、hina, over 1.58107 tons of dewatered sewage sludge, with 80% water content, was generated from wastewater treatment plant in 2008. About 60% of the organic substances, removed during the wastewater treatment process, become concentrated as sludge. Traditional disposal methods used by municipal solid

4、 waste treatment facilities, including landfills, composting, and incineration, are unsuitable for sludge disposal because of its high moisture content. Few proper sludge treatments or disposal methods are currently applied in China. The treatment and disposal of sewage sludge are significant enviro

5、nmental problems and have therefore become a major focus of current environmental protection policies. Sludge incineration has received worldwide attention as an effective approach to reduce the quantity and toxicity of sludge. In Japan, most of burnable wastes are incinerated. However, direct sludg

6、e incineration is not cost-efficient and creates unstable burning which generates large amounts of gaseous pollutants. Currently, bio-energy is an excellent energy recycling technology with bright prospect, given its ability to turn refuse into energy. As such, in recent years refuse-derived fuel (R

7、DF) technology has become a refuse processing technology adopted by advanced nations in Europe, America, and Japan etc. In China, sewage sludge was mixed with auxiliary fuels, sulfur-fixating agents, and preservatives. The blends were granulated generating sludge-derived fuel (traditional SDF, T-SDF

8、). Most researchers focused mainly on the T-SDF technology and have made important contribution to understand the combustion characteristics of T-SDF. However, all these technologies relied mainly on adding a large number of coals (about 50%) to improve the heat value and lower the moisture content

9、of fuels. The heat value of T-SDF depends merely on the quantity and proportion of auxiliary fuels, not the reduction of water content of sludge. In some extent, this process realizes sludge recycling and harmless treatment. However, the volume and weight of T-SDF are also increased, resulting in in

10、crease of operating cost. Moreover, the small proportion (about 40%) of sludge in the T-SDF leads to a lower capacity that cannot meet the needs of sludge treatment. Therefore, it is urgent for us to find a cost-effective and energy-saving way to realize sludge recycling, harmless treatment and redu

11、ction.The core issue to produce solid fuel from sewage sludge is how to efficiently remove the water from sludge. The object of this project is to minimize the energy requirements for producing cost-effective and applicable solid fuel from sewage sludge. Hydrothermal treatment (or thermal hydrolysis

12、) is a process in which the sludge is heated as an aqueous phase to temperatures (normally) varying between 120 and about 400C. The hydrothermal treatment process aims to disintegrate the sludge and result in a formation and accumulation of dissolved products. This makes it possible to recover and r

13、ecycle useful resources from the sludge, such as volatile fatty acids, phosphorous compounds, organic compounds for enhanced anaerobic biogas production, and coagulants. After hydrothermal treatment, the sludge and other waste biomass can be dehydrated by mechanical methods and dried under natural c

14、ircumstances easily, used as substituted fuel which we called it novel sludge-derived fuel (N-SDF) in this research. His research will study the influence of hydrothermal conditions on natural drying characteristics of sewage sludge and other waste biomass, the drying mechanisms of hydrothermal trea

15、tment sludge and waste biomass. This research will not only drive the development of sludge treatment technologies but also lend a hand to other waste biomass treatment.In previous studies, we found that the N-SDF produced from sewage sludge by employing the hydrothermal treatment is easier when dry

16、ing under natural circumstances. After 24h natural drying, about 50% water was removed. Comparing with raw sludge, the drying is faster. Obviously, the heat value of N-SDF can be improved further, which increase the stability of combustion. However, some factors are still unclear and needed to be st

17、udied further, limiting its popularization and applications. Therefore, it is necessary to conduct this research. xxxxxxxx is developing and commercializing total technologies to convert unutilized resources such as solid wastes and biomass into high value added energy resources (solid fuel, gaseous

18、 fuel, liquid fuel and electric power) by combining various technologies which have been jointly developed with many companies. We have done many work and made some progress in the field of Waste-to-Energy in xxxxxxx. Because of our outstanding contributions to the development of waste-to-energy tec

19、hnologies, With the co-advising of Prof. xxx and I, this project can be finished on time.References:Wang, W., Luo, Y.X., Qiao, W. 2010. Possible Solutions for sludge dewatering in China. Front. Environ. Sci. Engin. China, 1:102-107. Doi: 10.1007/s11783-010-001-z. Jiang, J.G., Du, X.J., Yang, S.H. 20

20、10. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste Management, 30: 1407-1413.Chen, W.S., Chang, F.C., Shen Y.H., Tsai, M.S. 2010. The characteristics of organic sludge/sawdust derived fuel, Bioresource Technology, doi: 10.1016/j.biortech.2010.1

21、1.007.Jiang, Z.L., Meng, D.W., Mu, H.Y., Yoshikawa. K. 2010. Study on the hydrothermal drying technology of sewage sludge. SCIENCE CHINA Technological Sciences, 1:160-163. doi: 10.1007/s11431-009-0423-7.Neyens, E., Baeyens, J. 2003. A review of thermal sludge pre-treatment process to improve dewater

22、ability. Journal of Hazardous Materials B, 98:51-67.Yoshikawa. K. 2009. Hydrothermal Treatment of Municipal Solid Waste to Produce Solid Fuel. 7th International Energy Conversion Engineering Conference, Aug 2009, Denver, Colorado.Namioka. T., Morohashi. Y., Yamane. R., Yoshikawa. K. 2009. Hydrotherm

23、al Treatment of Dewatered Sewage Sludge for Fuel Production. Journal of Environment and Engineering, 1:68-77.Namioka. T., Yoshikawa. K. 2005. Innovative Pretreatment Technology for Wet Biomass Utilizing Middle Pressure Stream. Nihon Kikai Gakkai Nenji Taikai Koen Ronbunshu.3:259-260.Morohashi. Y., Y

24、amane. R., Namioka. T., Yoshikawa. K. 2008. A Study on Improvement of Dehydration Performance of Sewage Sludge by the Hydrothermal Treatment. Transactions of the Japan Society of Mechanical Engineers Part B. 744:1814-1820.Morohashi. Y., Yamane. R., Yoshikawa. K. High Efficiency Dehydration of Sewage

25、 Sludge by the Hydrothermal Treatment and the Press Filter, 26th Annual International Conference on IT3, May 14-18, 2007, Phoenix, AZ. Zhao, P.T., Ge, S.F., Chen, Z.Q. 2011. A Study on the Improvement of Sludge Dewaterability by Thermal Conditioning. ICEICE. Wuhan. Accepted. 申请人国内科研准备工作概述Theoretical

26、 Review: Inrecent two years,his main work is related to sludge recycling, and thats his interest. He has done some related research in sludge recycling. In the project of sludge drying and incineration, he used a rotary dryer to dry sludge, and then the semi-dry sludge with 40% moisture content was

27、incinerated in coal-fired boiler. To overcome the defects of wedge-shaped paddle dryer in sewage sludge drying, we designed the horizontal disc rotary dryer and did some research on the characteristics of viscous zone of sludge drying. The sewage sludge drying process could be divided into three sta

28、ges: paste, viscous, and granular. In viscous stage, the moisture content of sludge is about 55%. To study the mechanism of sludge dewatering, the main parameters SRF characterizing sludge dewaterability were experimentally investigated and a paper has been accepted by Journal of Southwest Universit

29、y (Natural Science Edition). The sludge flocculation process was studied through fractal dimensions which were determined by image analysis. Two-dimensional fractal dimensions Df and one-dimensional fractal dimensions D1 of flocs formed at different flocculation time and the filtrate speed and speci

30、fic resistance to filtrate (SRF) of conditioned sludge were determined to assess sludge dewaterability. Based on the change of fractal dimensions, the sludge flocculation process was divided into three stages: primary particles form flocculi; flocculi collide with each other, group together to form

31、flocs; equilibrium stage. The critical watershed flocculation times are 45s and 150s respectively. At the very end of flocculi stage and the beginning of flocs, the time is generally set as 45s and when a subsequent dewatering step is applied, lower moisture content sludge cake would be obtained. Th

32、ese researches will provide a theoretical basis for this application.We used the saturated steam to conditioning sewage sludge and applied the steam explosion to crush the cell walls and transform bond water into free water for improving sludge dewaterability. A pilot scale experimental device has b

33、een built and operated in Yangzhong, Jiangsu province, in September 2010. He has also done some lab scale experimental study on sludge thermal conditioning. He investigated the factors affecting sludge dewaterability by thermal conditioning experimentally, and found that the major factors for improv

34、ing sludge dewaterability by thermal conditioning are conditioning temperature and residence time. He also found that the optimal temperature and residence time for treating municipal sludge are 180C and 60mins, respectively. The moisture content of sludge cake is 50.88% after pressure filtration fo

35、r 50 minutes. Thermal conditioning transforms organic compounds of sludge into soluble substances and greatly increases the COD of the separated water. After thermal conditioning at 180C, the COD of the separated water is about 420 times of the original sludge. Thermal sludge conditioning has the ad

36、vantage of low energy consumption and can help us achieve the goals of sludge reduction, harmlessness and efficient utilization. He used dewatered sludge (20% DS), leaves and straw (unbroken) as raw materials, applied the hydrothermal and hydrothermal treatment/steam explosion to produce sludge deri

37、ved fuel. The biomass (leaves, straw etc.) is not pre-broken. The final product is almost odorless, and the heat value of dry solids didnt change after hydrothermal treatment. The process integrates advanced sludge dewatering and sludge derived fuel together and is easier to implement. Compared with

38、 T-SDF technologies, this process incorporates the advantages of advanced sludge dewatering and sludge derived fuel. The heat value of N-SDF depends mainly on the water removal of sludge not the adding of auxiliary fuel, the proportion of sludge can be highly increased. The production cost of fuel i

39、s reduced because sludge drying and auxiliary fuel are no longer required. With a moisture content of 60%, the low heat value of the fuel is 8500 KJ/kg and can be easily burned in a coal-fired boiler. These researches provide a basis for an experimental study of the application.He is very interested

40、 in what he has done and what he will do. With the co-advising of Prof. Yoshikawa, Prof.Ge and I, I am sure he can finish this project on time and make a progress in his research. 出国学习预期目标The Goals Of The Research: (1) To learn some energy conversion technologies, especially waste-to-energy technolo

41、gies. (2) To study sludge recycling technologies systematically, and do some research on minimization of energy requirement for producing solid fuel according to Prof. Yoshikawas lab facilities, find an efficient method suitable for Chinas national conditions to realize waste-to-energy. (3) To evalu

42、ate and characterize the performances of N-SDF, using life-cycle assessment (LCA) to access the economic feasibility of solid fuel produced from sewage sludge and some other waste biomass. 科研方法The Experimental Methods: (1) Mechanisms of Hydrothermal Treatment Improving N-SDF Drying Properties:The in

43、fluence of hydrothermal conditions (Temperature, Pressure, and Residence Time) on particle Size Distribution: The moisture content of the dewatered sludge would be determined first and then some certain sludge will be placed in the reactor (MMJ-500, OMLAB-TECH CO., LTD., Tochigi, Japan). Three main

44、parameters-(1) Pressure (1.2-2.6Mpa), (2) residence time (10-90 min), (3) Temperature (120-250C) are varied to understand the characteristics of hydrothermal-treatment sludge. After hydrothermal-treatment for a certain time, 5 samples formed under different hydrothermal conditions will be diluted 10

45、0 times with distilled water. Particle size distribution (PSD) was determined by particle measuring systems two-sensor particle counting system, which allows a user to measure particles in most liquids quickly and efficiently within the range of 0.2125.0m. The particle 10 counter provides up to 30 u

46、ser-selectable sizing channels, allowing a very complete analysis of the particle size distribution and simultaneous measurement of various quality assurance standards. The Particle Measuring system incorporates two LiQuilaz volumetric particle counters combined with the LS200 Syringe Sampler. The t

47、wo LiQuilaz particle counters detect particles suspended in liquid between 0.2 and 125.0m. The first particle counter that samples the liquid is a LiQuilaz S02, which measures particles ranging from 0.2 to 2.0m. The second particle counter, the LiQuilaz E20P, detects particulates ranging from 2.0 to

48、 125.0m. By combining these two particle counters, the user has up to 30 user-selectable channels for collecting information on the samples. After then, the N-SDF will be dried in an electric oven at 378k until the mass difference reached less than 0.5%. Ultimate analyses will be conducted with an e

49、lemental analyzer (PerkinElmer, 2400 Series II CHNS/O System), and the heat values will be measured with a calorimeter (Shimadzu, CA-4PJ).Data Analysis: Although the use of arithmetic-mass mean has been identified more properly to provide a wide scale for differentiate mean sizes of different PSD; this study will use the geometric-mass mean particle size. Natural Drying Characteristics of N-SDF: To study on the natural

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