离子色谱应用（瑞士万通）.ppt

,离子色谱应用,阴离子分析（非抑制电导检测）,阴离子分析（化学抑制电导检测）,阳离子分析,阴离子分析（有机阴离子）,UV/VIS,检测,安培检测,IC-MS,联用技术,Metrosep Dual 1-70,；,邻苯二甲酸,/,乙腈,(TRIS,调,pH4.0),标准品：,1.,Cl,-,5ppm,2.NO,2,-,5,3.Br,-,10,4.NO,3,-,10,5.SO,4,2-,10,阴离子分析（非抑制电导检测）,Metrosep A Supp 4-250,；5mM,邻苯二甲酸,/2,丙酮,(TRIS,调,pH4.4),标准品：,1 Cl,-,25ppm,2.NO,2,-,25,3.Br,-,25,4.NO,3,-,25,5.SO,4,2-,25,Metrosep Dual 1-70,；8mM,邻苯二甲酸,/2,乙腈,(TRIS,调,pH4.0),自来水,1.,Cl,-,2.NO,3,-,3.SO,4,2,Metrosep Dual 1-70；,8mM,邻苯二甲酸,/2,乙腈,(TRIS,调,pH4.0),冶金工艺水样,1.,Cl-525ppm,2.CN-92,3.NO,3,-67,4.SO,4,2-250,5.S,2,O,3,2-n.d.,6.SCN,-,705,Hamilton PRP-X 100；3.2mM,NaOH/0.5mM Na,2,CO,3,自来水,：,1.,未知；,2.SiO,4,2,5.3ppm,Star Ion A 300,柱；,1mM,NaOH/0.1mM Na,2,CO,3,/15mM,果糖。,乙烯乙二醇酯,ppm,1.,SiO,4,2,5.3,2.BO,3,3,5.3,3.n.d.,4.SP,阴离子分析（化学抑制电导检测）,Metrosep A Supp 5-250,；,NaHCO,3,/Na,2,CO,3,;1/3.2mM.,标准阴离子：,ppm,2,F,5,3,乙酸,1,4,甲酸,4,5,ClO,2,3,6,BrO,3,2,7,Cl,10,8,NO,2,5,9,Br,3,10.,NO,3,4,11.苯甲酸盐 1,12.,PO,4,3,5,13.,亚砷酸盐 3,14.,SO,4,2,10,15.,丁二酸盐 4,16.砷酸盐 3,17.,草酸盐 15,EPA,水样中阴离子分析方法,EPA Method Validation,EPA 218.6,Determination of Hexavalent Chromium,EPA 300.0,Method A:standard anions(F,-,Cl,-,NO,2,-,Br,-,NO,3,-,HPO,4,2-,or PO,4,3-,SO,4,2-,),Method B:anion by-products or oxyhalides(ClO,2,-,BrO,3,-,ClO,3,-,),EPA 300.1,Method A:Determination of common anions(F,-,Cl,-,NO,2,-,Br,-,NO,3,-,HPO,4,2-,or PO,4,3-,SO,4,2-,),Method B:Determination of Disinfection By-products(Br,-,ClO,2,-,BrO,3,-,ClO,3,-,),EPA 314,ppb level perchlorate(ClO,4,-,)analysis,C,自来水中卤氧化物及常规阴离子,(EPA 300.0 a+b),A Supp 5 250,+A Supp 1 Guard,2,F,0.09,5,ClO2,0.12,6,BrO3,0.01,7,Cl,32.0,8,ClO3,0.05,9,Br,0.01,10,NO3,4.91,13,SO4,28.2,FS change at 11 and 26 min;ppm,NaHCO,3,/Na,2,CO,3,:1.0/3.2 mmol/L;0.7 mL/min;100 L,A Supp 5-250;,1mM NaHCO,3,/3.2mM Na,2,CO,3,/,2%,乙腈,/0.5%,异丙醇,;0.6 mL/min;20 L,河水,：,ppm,1,F,0.07,3,Cl,6.13,4,NO,2,0.05,6,Br,0.08,7,NO,3,3.68,8,PO,4,3,0.01,9,SO,3,2,0.09,10,SO,4,2,20.54,Metrosep Dual 2;,2mM NaHCO,3,/1.3mM Na,2,CO,3,;0.8 mL/min;20 L,雨水,：,ppm,1,F,0.057,2,Cl,0.353,3,NO,2,0.028,4,NO,3,5.28,5,SO,4,2,2.70,A Supp 4-250；,4mM NaHCO,3,/1mM Na,2,CO,3,;1.0 mL/min;20 L,矿泉水,：,1,F,0.69,2,Cl,17.4,3,NO,2,0.04,4,Br,0.18,5,NO,3,0.27,6,SO,4,2,121,7,I,0.034,ppm,工业废水,1,Cl,-,2,NO,2,1.89,3,SO,3,2,24.64,4,SO,3,2,0.21,5,SO,4,2,1112,6,CrO,4,2,0.31,ppm,A Supp 5 150；,Na,2,CO,3,/NaHCO,3,/,丙酮,;5.0/1.5/10 mM/%;,0.7 mL/min;10 L;Ag,+,cartridge,油田生产水,1,Br,56.9,2,SP,n.q.,3,SO,4,2,26.9,ppm,A Supp 4 250；,1.7mM Na,2,CO,3,/1.8 mM NaHCO,3,A Supp 10-100;4mM,NaHCO,3,/6mM Na,2,CO,3,/5uM,高氯酸盐,啤酒,（10倍稀释）,3,Cl,79.4,7,PO,4,3,290,10,SO,3,2,10.3,11,NO,3,4.3,12,SO,4,2,128,ppm,Metrosep A Supp 4-250;,Na,2,CO,3,/NaOH,2.0/15.0;1.5 L,可乐,：,ppm,1,Cl,-,2,n.d.,-,3,NO,3,/CO,3,2,-,4,SO,4,2,-,5,n.d.,-,6,PO,4,3,362,7,柠檬酸,52,10 g/L,奶粉,;,在线透析,；,A Supp 5-250;,1,mM NaHCO,3,/3.2mM Na,2,CO,3,奶粉,：,1,I,17.6,ppm,1,C,A Supp 5-150；1mM,NaHCO,3,/3.2mM Na,2,CO,3,；0.7mL/min;,20 L,肥料,1,Cl,-,2,NO,3,623,3,SO,4,2,135,g/kg,A Supp 5-150；1mM,NaHCO,3,/3,.2,mM Na,2,CO,3,；,超纯水,20,mL,预浓缩,1,F,2,2,乙酸,22,3,Cl,13,4,NO,3,6,5,PO,4,3,17,6,SO,4,2,9,7,草酸,12,ppt,A Supp 5-150；1mM,NaHCO,3,/3.2mM Na,2,CO,3,；,电路板萃出液,异丙醇/水（82/20）,80,C,1hr,1,Cl,1.39,2,Br,n.q.,3,NO,3,0.14,4,PO,4,3,0.40,5,SO,4,2,0.70,ppm,在线透析；,A Supp 5-250;,1,mM NaHCO,3,/3.2mM Na,2,CO,3,尿样：,1,Cl,741.0,2,SP,3,n.d.,4,NO,3,8.8,5,PO,4,3,504.3,6,SO,4,2,238.5,7,草酸,9.0,ppm,C,A Supp 4-250,；1,mM NaHCO,3,/6mM Na,2,CO,3,药液,：,在线透析,1,乙酸,n.q.,2,Cl,0.39,3,SO,4,2,10.76,4,SP,n.q.,5,柠檬酸,41.81,ppm,C,药物妥普利,A Supp 5-250,NaHCO,3,/Na,2,CO,3,;,1.0/3.2 mM;,0.7 mL/min;10 L,1,氨基磺酸根,88.7,2,n.d.,-,3,SO,4,2,155.7,ppm,SO,4,2,氨基磺酸,炸药粉末,A,：,各10,ppm,1,Cl,2,NO,2,3,CN,4,叠氮化物,5,NO,3,6,ClO,3,7,SO,4,2,8,SCN,9,S,2,O,3,2,10,ClO,4,A Supp 3-250；,Na,2,CO,3,/NaHCO,3,/p-,氰基苯酚,/,丙酮，,1/1/0.5/10 mM/L/%,炸药粉末,B,：,1,ClO,3,386,2,NO,3,268,3,ClO,4,260,ppm,A Supp 4-250；,1.9/1.9/5 mmol/L/%Na,2,CO,3,/NaHCO,3,/,乙腈,50%,苛性钠,在线中和,1,Cl,25.08,2,SP,n.q.,3,ClO,3,4.76,4,SO,4,2,10.43,ppm,Metrosep Dual 2；,NaHCO,3,/Na,2,CO,3,;2.0/1.3 mM,阳离子分析,常规标准品,ppm,1,Li,1,2,Na,5,3,NH,4,+,5,4,K,10,5,Ca,10,6,Mg,10,阳离子标准品,Metrosep C 2150；,酒石酸,/,二甲基吡啶酸,;4/0.75mM,过渡金属标准,ppm,1,Pb,10,2,Zn,2,3,In,10,4,Cd,5,5,Co,5,6,NH,4,+,2,7,K,5,8,Mn,5,9,Mg,5,10,Ca,5,Metrosep C2250；,酒石酸,/,二甲基吡啶酸,，,5/0.9 mM,自来水：,1,Na,4.78,2,K,1.45,3,Ca,92.97,4,Mg,19.46,ppm,Metrosep C 2100；,酒石酸,/,二甲基吡啶酸,，4/0.75mM；,1 mL/min,城市生活用水,1,Li,0.009,2,Na,3.85,3,K,0.59,4,Ca,18.6,5,Mg,3.65,ppm,Metrosep Cation 12；,酒石酸,/,二甲基吡啶酸,，4/0.75mM；,1 mL/min;10 L,生活污水:,1,Na,2700,2,NH,4,+,31.0,3,DEA,72.3,4,DGlyA,25.9,5,K,14.5,ppm,Metrosep C 2100；,酒石酸,/18-,冠,-6;4/0.5 mM;1 mL/min;10 L,1,Na,0.07,2,NH4+,0.26,3,K,0.32,4,Ca,4.18,5,Mg,1.04,ppm,Metrosep Cation 12；,酒石酸,/,二甲基吡啶酸,，4/0.75mM；,1 mL/min;10 L,雨水,血液透析液,1,Na,106.1,2,K,2.13,3,Ca,2.45,4,Mg,0.79,ppm,Metrosep Cation 12；,酒石酸,/,二甲基吡啶酸,，4/1 mM；,药物分析：,乌拉胆碱,、,HPTA,USP 27-NF22,1,Na,n.q.,2,Ca,10,3,HPTA,10,4,乌拉胆碱,10,ppm,Metrosep C 2 150；3.5mM,硝酸/10%丙酮,;1 mL/min;20 L,Metrosep C 2100；,酒石酸,/,二甲基吡啶酸,，,4/0.5mM,；,1 mL/min,尿：,稀释50倍,1,Na,2055.3,2,NH4+,531.7,3,K,3952.7,4,n.d.,-,5,Ca,70.1,6,Mg,49.3,ppm,伏特加酒,1,Na,1.59,2,K,5.96,3,Ca,0.55,4,Mg,0.03,ppm,Metrosep Cation 12；,酒石酸,/,二甲基吡啶酸,，,4/1 mM,；,100 L,葡萄酒,：,ppm,1,Na,9.8,2,K,822.1,3,Ca,306.1,4,Mg,72.2,Metrosep Cation 12；,酒石酸,/,二甲基吡啶酸,，,4/1 mM,Metrosep C1；2.5mM,硝酸/10%丙酮,;3 L,西班牙红葡萄酒中生物胺,ppm,2,Na,11.8,4,K,849.4,8,Mg,116.0,9,Ca,61.4,10,腐胺,25.7,11,组胺,8.7,生物有机胺,1,Na,10.0,2,K,998.8,3,Mg,75.5,4,Ca,75.9,5,腐胺,14.9,6,尸胺,4.2,7,组胺,4.1,ppm,Metrosep C1；2.5mM,硝酸/10%丙酮,;3 L,标准溶液,Metrosep C2150；6mM,硝酸,;20 L,欧蝶鱼体内生物胺,ppm,2,二甲胺-,N,10.5,6,氧化三甲胺-,N,3.9,7,三甲胺,-N,129.6,8,腐胺-,N,7.1,10,尸胺-,N,5.4,油田开采水,ppm,1,Sr,33.8,2,Ba,53.9,3,Mg,29.0,Nucleosil 5 SA,；,酒石酸,/,乙二胺,/,二甲基吡啶酸,/,丙酮,；,4/3/0.5/5 mM/%,低浓度阳离子,ppt,1,Li,50,2,Na,100,3,NH,4,+,100,4,K,100,5,Mg,100,6,Ca,100,Metrosep C2250；4 mM,酒石酸;43,mL,样品预浓缩,油田开采水样,ppm,1,Ni,140,2,Zn,151,3,Co,137,4,Fe(II),167,5,Mn,129,Nucleosil 5SA 125；,草酸,/,抗坏血酸，,1.75/2 mM;PCRPAR,沙特阿拉伯油田水,有机阴离子分析,标准溶液,各1,ppm,1,乳酸,2,甲酸,3,乙酸,4,丙酸,5,丁酸,6,异丁酸,7,戊酸,8,异戊酸,Metrosep Organic Acids，MSM,；,0.5,mM H,2,SO,4,;,标准溶液,1,柠檬酸,50,2,酒石酸,25,3,苹果酸,50,4,琥珀酸,100,5,乳酸,50,6,甲酸,50,7,乙酸,100,8,System,-,ppm,Metrosep Organic Acids，MSM,；,0.5,mM H,2,SO,4,;,C,香槟酒,1,柠檬酸,251,2,酒石酸,1140,5,苹果酸,225,10,琥珀酸,563,11,乳酸,1361,12,草酸,588,13,System,n.q.,ppm,3,4,6,7,8,9=n.d.,Metrosep Organic Acids，MSM,；,0.5,mM H,2,SO,4,;,苹果汁,1,柠檬酸,63.4,2,酒石酸,48.1,3,苹果酸,7281.3,4,n.d,-,5,乳酸,29.9,6,System,-,ppm,Metrosep Organic Acids，MSM,；,0.5,mM H,2,SO,4,;,纸浆工艺水,4,羟乙酸,3.35,5,甲酸,0.99,7,戊二酸,0.96,8,乙酸,723,9,丙酸,533,10,碳酸,-,11,丁酸,24.5,12,硫化物,-,ppm,Metrosep Organic Acids 250；,0.5 mM H,2,SO,4,Ions with UV/VIS detection,C,盐溶液中的亚硝酸根和溴离子,Metrosep A Supp 8 150,1,亚硝酸盐,0.050,2,Br,1.400,3,硝酸根,0.120,ppb,NaCl 100 g/L;1.0 mL/min;100 L;UV 215 nm;30 C,C,Metrosep A Supp 5 100,1,硫离子,1.0,2,System,-,3,亚硫酸盐,1.0,4,硫代硫酸盐,1.0,ppm,Na,2,CO,3,;4.0 mmol/L;0.7 mL/min;1 mL;UV 205 nm,硫磺混合物,C,皮革萃取液中的铬酸根,Metrosep A Supp 5 150,1,Chromate,19,ppb,NaHCO,3,/Na,2,CO,3,;4/12.8 mmol/L;0.7 mL/min;50 L;VIS 540 nm;PCR with diphenylcarbazide;dilution 1:10;dialysis,Nucleosil 5SA125，70mM,酒石酸,;pH=3.3(NH,3,);1 mL/min;,VIS 530 nm;PCR with PAR,过渡金属,ppm,1,Cu,1,2,Pb,1,3,Zn,1,4,Ni,1,5,Co,1,6,Cd,1,7,Mn,1,ProntoSIL 120-5-C18-AQ,150*4；15/85(v/v),乙腈,/,水中含20,mM H,2,SO,4,;1.0 mL/min,220nm(,黑),254,nm(,红,),270,nm(,绿,),peak-ratio(,蓝,),1.扑热息痛,2.咖啡因,3.羟基苯甲酸,各20,ppm,Ions with Bioscan,C,Metrosep A Supp 1 250,1,Cyanide,0.01,ppb,NaOH/aceton;100/10 mmol/L/%,水中的氰离子,C,尿液中的碘离子,Metrosep A Supp 5 150,1,Iodide,68.5,ppb,Urine sample,dialysis,Na,2,CO,3,/NaHCO,3,;3.8/1.2 mmol/L;0.7 ml/min;Ag 150 mV,C,Metrosep Carb 1 250 ppm,1,肌醇,5.00,2,阿拉伯糖醇,10.00,3,山梨糖醇,10.00,4,盐藻糖,10.00,5,阿拉伯糖,10.00,6,葡萄糖,10.00,7,木糖,10.00,8,果糖,10.00,9,乳糖,10.00,10,蔗糖,10.00,100 mmol/L NaOH,标准糖谱图,糖分析：,Metrosep Carb 1-250;,100mM NaOH；,1000倍稀释,百事可乐,：,1.,葡萄糖,20368,2.,果糖,19947,3.,蔗糖,60125,ppm,糖分析：,Metrosep Carb 1-250;,100mM NaOH；,1000倍稀释,可口可乐,：,1.,葡萄糖,19082,2.,果糖,18517,3.,蔗糖,67584,ppm,速溶咖啡中糖：,5,甘露醇,5.3,6,蔗糖,121.5,7,树胶醛糖,1.7,8,半乳糖,69.4,9,葡萄糖,24.9,10,木糖,6.4,11,甘露糖,14.0,12,果糖,0.65,ppm,Metrosep Carb 1-250,；,2.5/0.65 mM NaOH/NaAc;,1.25 mL/min;,PCR 0.3 mol/L NaOH,庆大霉素硫酸盐：,1-7 n.q.,8,庆大霉素,C1a,17.9,9,庆大霉素,C2b,1.5,10,庆大霉素,C2,27.0,11,庆大霉素,C2a,15.2,12,庆大霉素,C1,29.2,%,Polymer Lab.RP-S 1000 A 8 m；1 mL/min,pH=3，H,3,PO,4,；60 g/L Na,2,SO,4,；1.75 g/L Na-Octanesulfonate；1.34 g/L NaH,2,PO,4,;8 mL/L THF;,55,C,PCR 300mM NaOH.,C,Metrosep Carb 1-150,；,A:80,/10 mM NaOH/NaAc；B:H,2,O；,C:250/500 mM NaOH/NaAc;,氨基酸分析：,ppm,1,精氨酸,5,2,赖氨酸,20,3,谷氨酸,10,4,天冬酰氨酸,10,5,苏氨酸,/,丙氨酸,5/5,6,氨基乙酸,10,7,丝氨酸,5,8,颉氨酸,20,氨基酸标准品,氨基酸分析：,ppm,9,脯氨酸,10,10,组氨酸,10,11,异亮氨酸,20,12,蛋氨酸,10,13,亮氨酸,20,14,谷氨酸,20,15,天冬氨酸,20,16,n.q.,-,17,半胱氨酸,5,18,巯基并氨酸/,酪氨酸,5/5,氨基酸标准品,C,Ions with IC/MS detection,C,Anions with IC/MS detection,EPA 332.0,标准,Metrosep A Supp 5 100,Cl,1000000,CO3,1000000,SO4,1000000,1,ClO4,1,ppb,MIC 2 A+Agilent MSD 110030/30;NaOH/MeOH;mmol/L/%,0.8 mL/min;100 S;m/z=99,1,C,EPA 332.0:,磺酸盐污染的地下水,Metrosep A Supp 5 100,1,ClO,4,0.35,1,ClO,4,(spiked),1.35,ppb,MIC 2 A+Agilent MSD 1100 30/30;NaOH/MeOH;mmol/L/%,0.8 mL/min;100 uS;m/z=99,1,Anions with IC/MS detection,C,氯化钠中的溴酸盐,Metrosep A Supp 5 250,1,BrO3,50,2,Cl,-,ppt,MIC 2 A+Agilent MSD 1100;,NaHCO,3,/Na,2,CO,3,;1.0/3.2 mmol/L;,0.7 mL/min,Anions with IC/MS detection,1,2,您有离子分析的问题吗？,欢迎登陆,中文网站：,英文网站：,