水和乙醇气液平衡（VLE）数据.doc

Isobaric P-T-X-Y Data : ETHANOL + WATER at 760mmHg Reference Rieder,R.M. and A.R.Thompson, I&EC, 41, 2905 (1949) Method Number of Data Points = 36 T,deg.C P,mmHg X Y T Err P Err X Err Y Err 100.0 760 0 0 +-0.2 99.3 760 0.0028 0.032 +-0.2 96.9 760 0.0118 0.113 +-0.2 96.0 760 0.0137 0.157 +-0.2 96.0 760 0.0144 0.135 +-0.2 95.6 760 0.0176 0.156 +-0.2 94.8 760 0.0222 0.186 +-0.2 93.8 760 0.0246 0.212 +-0.2 93.5 760 0.0302 0.231 +-0.2 92.9 760 0.0331 0.248 +-0.2 90.5 760 0.0519 0.318 +-0.2 90.5 760 0.0530 0.314 +-0.2 89.4 760 0.0625 0.339 +-0.2 88.4 760 0.0673 0.370 +-0.2 88.6 760 0.0715 0.362 +-0.2 87.2 760 0.0871 0.406 +-0.2 85.4 760 0.126 0.468 +-0.2 84.5 760 0.143 0.487 +-0.2 84.0 760 0.172 0.505 +-0.2 83.4 760 0.206 0.530 +-0.2 83.0 760 0.210 0.527 +-0.2 82.3 760 0.255 0.552 +-0.2 82.0 760 0.284 0.567 +-0.2 81.4 760 0.321 0.586 +-0.2 81.5 760 0.324 0.583 +-0.2 81.2 760 0.345 0.591 +-0.2 80.9 760 0.405 0.614 +-0.2 80.5 760 0.430 0.628 +-0.2 80.2 760 0.449 0.633 +-0.2 80.0 760 0.506 0.661 +-0.2 79.5 760 0.545 0.673 +-0.2 78.8 760 0.663 0.733 +-0.2 78.5 760 0.735 0.776 +-0.2 78.4 760 0.804 0.815 +-0.2 78.3 760 0.917 0.906 +-0.2 78.3 760 1.000 1.000 +-0.2 Isobaric P-T-X Data : ETHANOL + WATER Reference KENJI OCHI and KAZUO KOJIMA, J. Chem. Eng. Japan, 20, 6 (1987) Method EBULLIOMETRIC METHOD Number of Data Points = 22 T,K P,kPa X Y T Err P Err X Err Y Err 373.13 101.325 0.000070 373.12 101.325 0.000090 373.11 101.325 0.000102 373.11 101.325 0.000148 373.10 101.325 0.000169 373.07 101.325 0.000238 373.04 101.325 0.000317 373.03 101.325 0.000326 373.00 101.325 0.000436 372.97 101.325 0.000560 372.93 101.325 0.000602 372.85 101.325 0.000854 372.78 101.325 0.000963 372.65 101.325 0.00132 372.55 101.325 0.00161 372.25 101.325 0.00265 372.02 101.325 0.00330 371.70 101.325 0.00447 371.54 101.325 0.00499 371.00 101.325 0.00638 370.69 101.325 0.00756 370.30 101.325 0.00858 Isothermal P-T-X Data : ETHANOL + WATER at 150.5C Reference KOLBE,B. and J.GMEHLING, Fluid Phase Equilib., 23, 213 (1985) Method STATIC METHOD Number of Data Points = 32 T,deg.C P,bar X Y T Err P Err X Err Y Err 150.5 5.1737 0.00732 +-0.1 150.5 5.3805 0.01210 +-0.1 150.5 5.6954 0.02040 +-0.1 150.5 6.0277 0.03012 +-0.1 150.5 6.4920 0.04669 +-0.1 150.5 7.0251 0.07205 +-0.1 150.5 7.3942 0.09619 +-0.1 150.5 7.8150 0.13497 +-0.1 150.5 7.9785 0.15447 +-0.1 150.5 8.1250 0.17469 +-0.1 150.5 8.2394 0.19253 +-0.1 150.5 8.5110 0.24227 +-0.1 150.5 8.7156 0.28690 +-0.1 150.5 8.5599 0.25252 +-0.1 150.5 8.7775 0.30256 +-0.1 150.5 8.9686 0.35235 +-0.1 150.5 9.1413 0.40204 +-0.1 150.5 9.3007 0.45219 +-0.1 150.5 9.4431 0.50193 +-0.1 150.5 9.5745 0.55175 +-0.1 150.5 9.6908 0.60191 +-0.1 150.5 9.7896 0.65002 +-0.1 150.5 9.8763 0.70150 +-0.1 150.5 9.9412 0.75054 +-0.1 150.5 9.9881 0.80043 +-0.1 150.5 10.0107 0.85005 +-0.1 150.5 10.0130 0.87336 +-0.1 150.5 10.0088 0.90035 +-0.1 150.5 9.9961 0.92868 +-0.1 150.5 9.9759 0.95460 +-0.1 150.5 9.9445 0.98400 +-0.1 150.5 9.9251 0.99751 +-0.1 Isothermal P-T-X Data : ETHANOL + WATER at 90.1C Reference KOLBE,B. and J.GMEHLING, Fluid Phase Equilib., 23, 213 (1985) Method STATIC METHOD Number of Data Points = 23 T,deg.C P,bar X Y T Err P Err X Err Y Err 90.1 1.0413 0.05444 +-0.1 90.1 1.2121 0.11396 +-0.1 90.1 1.2930 0.17001 +-0.1 90.1 1.3407 0.22053 +-0.1 90.1 1.3814 0.27556 +-0.1 90.1 1.4153 0.32859 +-0.1 90.1 1.3620 0.24604 +-0.1 90.1 1.3951 0.29404 +-0.1 90.1 1.4232 0.34348 +-0.1 90.1 1.4490 0.39170 +-0.1 90.1 1.4721 0.43922 +-0.1 90.1 1.4944 0.48771 +-0.1 90.1 1.5147 0.53597 +-0.1 90.1 1.5333 0.58487 +-0.1 90.1 1.5489 0.62981 +-0.1 90.1 1.5631 0.67564 +-0.1 90.1 1.5752 0.72155 +-0.1 90.1 1.5849 0.76903 +-0.1 90.1 1.5916 0.81658 +-0.1 90.1 1.5956 0.86455 +-0.1 90.1 1.5948 0.91231 +-0.1 90.1 1.5916 0.95921 +-0.1 90.1 1.5854 0.99755 +-0.1 Isothermal P-T-X Data : ETHANOL + WATER at 108.2C Reference KOLBE,B. and J.GMEHLING, Fluid Phase Equilib., 23, 213 (1985) Method STATIC METHOD Number of Data Points = 29 T,deg.C P,bar X Y T Err P Err X Err Y Err 108.2 1.5332 0.01269 +-0.1 108.2 1.6890 0.02499 +-0.1 108.2 1.9348 0.05136 +-0.1 108.2 2.0864 0.07390 +-0.1 108.2 2.2076 0.09903 +-0.1 108.2 2.2985 0.12425 +-0.1 108.2 2.3672 0.14912 +-0.1 108.2 2.4218 0.17340 +-0.1 108.2 2.4697 0.19843 +-0.1 108.2 2.5114 0.22372 +-0.1 108.2 2.5488 0.24947 +-0.1 108.2 2.5828 0.27460 +-0.1 108.2 2.6093 0.29572 +-0.1 108.2 2.6146 0.29963 +-0.1 108.2 2.6691 0.34909 +-0.1 108.2 2.7186 0.39929 +-0.1 108.2 2.7598 0.44411 +-0.1 108.2 2.8039 0.49674 +-0.1 108.2 2.8421 0.54597 +-0.1 108.2 2.8761 0.59357 +-0.1 108.2 2.9104 0.64923 +-0.1 108.2 2.9360 0.69944 +-0.1 108.2 2.9564 0.74811 +-0.1 108.2 2.9718 0.79934 +-0.1 108.2 2.9808 0.85240 +-0.1 108.2 2.9816 0.89534 +-0.1 108.2 2.9758 0.94316 +-0.1 108.2 2.9663 0.98044 +-0.1 108.2 2.9597 0.99756 +-0.1 Isothermal P-T-X Data : ETHANOL + WATER at 130.3C Reference KOLBE,B. and J.GMEHLING, Fluid Phase Equilib., 23, 213 (1985) Method STATIC METHOD Number of Data Points = 30 T,deg.C P,bar X Y T Err P Err X Err Y Err 130.3 2.9679 0.00820 +-0.1 130.3 3.2267 0.01827 +-0.1 130.3 3.6552 0.03953 +-0.1 130.3 3.8185 0.05007 +-0.1 130.3 4.0152 0.06550 +-0.1 130.3 4.1138 0.07444 +-0.1 130.3 4.3251 0.09795 +-0.1 130.3 4.4623 0.11776 +-0.1 130.3 4.5764 0.13769 +-0.1 130.3 4.6689 0.15673 +-0.1 130.3 4.7442 0.17471 +-0.1 130.3 4.8650 0.20862 +-0.1 130.3 4.9844 0.24866 +-0.1 130.3 5.0867 0.28851 +-0.1 130.3 5.0990 0.29553 +-0.1 130.3 5.2157 0.34797 +-0.1 130.3 5.3046 0.39214 +-0.1 130.3 5.3872 0.43622 +-0.1 130.3 5.4785 0.48912 +-0.1 130.3 5.5561 0.53998 +-0.1 130.3 5.6209 0.58560 +-0.1 130.3 5.6866 0.63966 +-0.1 130.3 5.7390 0.69011 +-0.1 130.3 5.7788 0.73563 +-0.1 130.3 5.8120 0.78834 +-0.1 130.3 5.8311 0.85036 +-0.1 130.3 5.8323 0.88909 +-0.1 130.3 5.8233 0.92932 +-0.1 130.3 5.8040 0.97057 +-0.1 130.3 5.7854 0.99751 +-0.1 Isobaric P-T-X-Y Data : ETHANOL + WATER at 760mmHg Reference DALAGER,P., J.Chem.Eng.Data, 14, 298 (1969) Method THE METHOD IS BASED ON RADIOACTIVE TRACERS Number of Data Points = 27 T,deg.C P,mmHg X Y T Err P Err X Err Y Err 100.00 760 0.000002 0.000034 +-0.02 +-1 100.00 760 0.000002 0.000024 +-0.02 +-1 100.00 760 0.000022 0.000308 +-0.02 +-1 100.00 760 0.000014 0.000280 +-0.02 +-1 100.00 760 0.000014 0.000183 +-0.02 +-1 100.00 760 0.000208 0.002454 +-0.02 +-1 100.00 760 0.000148 0.001591 +-0.02 +-1 100.00 760 0.000187 0.002475 +-0.02 +-1 100.00 760 0.000150 0.001957 +-0.02 +-1 98.50 760 0.004815 0.072680 +-0.02 +-1 98.60 760 0.004014 0.059219 +-0.02 +-1 98.55 760 0.004307 0.059815 +-0.02 +-1 93.00 760 0.0315 0.2582 +-0.02 +-1 92.95 760 0.0370 0.3625 +-0.02 +-1 87.95 760 0.0740 0.3881 +-0.02 +-1 85.10 760 0.1218 0.4658 +-0.02 +-1 84.85 760 0.1283 0.4878 +-0.02 +-1 81.85 760 0.2548 0.5626 +-0.02 +-1 81.90 760 0.2597 0.5539 +-0.02 +-1 80.50 760 0.3937 0.6201 +-0.02 +-1 80.35 760 0.3971 0.6128 +-0.02 +-1 79.30 760 0.5472 0.6789 +-0.02 +-1 78.50 760 0.6980 0.7568 +-0.02 +-1 78.20 760 0.8400 0.8416 +-0.02 +-1 78.20 760 0.8393 0.8391 +-0.02 +-1 78.20 760 0.9140 0.9223 +-0.02 +-1 78.20 760 0.9099 0.9189 +-0.02 +-1 Isothermal P-T-X-Y Data : ETHANOL + WATER at 363.15K Reference Pemberton,R.C. and C.J.Mash, J.Chem.Thermodyn., 10, 867 (1978) Method Number of Data Points = 24 T,K P,kPa X Y T Err P Err X Err Y Err 363.15 73.726 0.00429 0.0520 363.15 81.909 0.01507 0.1539 363.15 89.620 0.02693 0.2337 363.15 99.667 0.04594 0.3200 363.15 108.298 0.06731 0.3823 363.15 119.548 0.10939 0.4530 363.15 128.811 0.17057 0.5058 363.15 135.640 0.24642 0.5449 363.15 140.677 0.32356 0.5763 363.15 144.188 0.38800 0.6010 363.15 145.622 0.41705 0.6123 363.15 149.595 0.50445 0.6480 363.15 152.616 0.58044 0.6830 363.15 154.470 0.63399 0.7106 363.15 157.003 0.72433 0.7639 363.15 157.811 0.76364 0.7901 363.15 158.489 0.80833 0.8224 363.15 158.914 0.85783 0.8618 363.15 158.987 0.89065 0.8903 363.15 158.963 0.89935 0.8981 363.15 158.868 0.92445 0.9216 363.15 158.600 0.95370 0.9506 363.15 158.354 0.97315 0.9708 363.15 158.227 0.98153 0.9797