应用于燃油系统的高性能材料优秀课件.ppt

Click to edit Master title style,Click to edit Master text styles,Second level,Third level,Fourth level,Fifth level,*,SOLVAY ADVANCED POLYMERS,*,BUSINESS CONFIDENTIAL,2007 Solvay Advanced Polymers,LLC,Click to edit Master title style,Click to edit Master text styles,Second level,Third level,Fourth level,Fifth level,*,BUSINESS CONFIDENTIAL,2007 Solvay Advanced Polymers,LLC,SOLVAY ADVANCED POLYMERS,1,Advanced Fuel System Materials,应用于燃油系统的高性能材料,Solvay Shanghai,苏威（上海）有限公司,Jim Doty,September 14,2007,MORE PLASTICS WITH MORE PERFORMANCE,2,Todays Topics/,内容概要,Introduction to Fuel Systems,燃油系统介绍,Fuel System Trends,燃油系统的发展趋势,Solvay Value Proposition,苏威的产品特点,Key Products,主要产品,Injection Molded Applications,注塑应用,Extruded Applications,挤出应用,Blow Molded Applications,吹塑应用,Summary,总结,3,Market Summary,Market definition,FUEL SYSTEMS,-HPP applications in automotive fuel systems requiring low permeation and any combination of temperature resistance,fuel resistance,and chemical resistance,connectors,sender units,valves,fill pipes and tanks,FUEL/VAPOR LINE,-Extruded line used to carry fuel and vapor within theautomotive fuel system,Trends,Low permeation,Increased fuel resistance,Higher temperature,4,Application Slide,Valves(Rollover,OBVR,AMODEL,AT-5001/AT-1002 HS,Vapor Line,Intank Line,Fuel Line,Amodel EXT-1800<m,Quick Connect,AMODEL,AT-1116/A-1625,Fuel Rail,AMODEL,AS-1145 HS/AS-4133 HS,Fuel Flange,AMODEL,AT-1002 HS/,AT-1116 HS/AS-1133 HS,Fuel Level Indicator,AMODEL,AT-1116 HS,Fuel Injector SealsTecnoflon,PL 557,Permeation Barrier,Ixef BXT Series,5,Fuel System Trends,发展趋势,Increased use of Direct Injection Engines,更多的使用直接喷射引擎,Both gasoline and diesel,包括汽油机和柴油机,New fuel injection technology,新的燃油喷射技术,Piezo electric fuel injectors,压电燃油喷射器,Increased use of low permeation materials,更多使用低渗透材料,Replacement of PA 11/12,and POM in quick connects,line,and fuel senders,代替,PA11/12,和,POM,，在快速接头，油管和送油器应用,Increased use of cap-less fuel system(North America),更多的使用无接头燃油系统（北美）,Increased use of Electro-static dissipative components(North America),更多的使用抗静电部件（北美）,Further development in diesel emission control,更加深入的研究在柴油喷射控制方面,Urea injection,particulate filters,NO,X,scrubbers,Increased use in Bio-Fuels and Hybrid Technology,更多的使用生物燃料和混合动力技术,Ethanol,RME&SME Bio-diesel,乙醇，,RME&SME,生物柴油,6,Euro 4&5,（欧洲）,Maximum 2 g/car/24 hr,小于,2,克,/,车,/24,小时,Test fuel contains 2.3%O,2,测试油氧含量,2.3,Lev II,0.5 g/car/24 hr 0.5,克,/,车,/24,小时,Test fuel contains 3.3%,测试油含量,3.3,Certification based on CARB,测试燃油为,CARB,Phase 2 test fuel,PZEV,0.054 g/car/24 hr 0.054,克,/,车,/24,小时,Test fuel contains 3.3%O,2,测试含氧量,3.3,Certification based on CARB,测试燃油为,CARB,Phase 2 test fuel,Amodel,PPA,Flanges/Sender units,法兰、送油单元,Quick connects,快速接头,Rollover valves,翻转阀,Filter housings,过滤器外壳,Level indicators,液面指示器,Fuel&air rails,油轨,Air valves&throttle bodies,空气阀和节气阀,Fuel Line,燃油管,Vapor Line,蒸汽管,In Tank Line,油箱内管,Ixef,PA MXD6,Filler Pipes,加油管,Fuel Tank,油箱,Low permeation resins for the most aggressive environments,Solvay Products for Fuel System Applications,苏威高性能材料在燃油系统中的应用,7,Amodel PPA is.,Modified with addition of.,Amodel compounds have,enhanced performance characteristics vs.conventional midrange engineering polymers,(CH,2,),6,C,O,O,C,N,n,N,H,H,Modified 6,T semi-aromatic polyamide,PA 6,T,HO,OH,C,O,C,O,HO,OH,C,O,C,O,(CH,2,),4,or,8,Ixef PAA is.,Semi-aromatic polyarylamide,Unique structure imparts unique properties,(CH,2,),4,O,C,H,n,N,O,C,CH,2,CH,2,H,N,Ixef compounds have,the highest strength to weight ratio of any semi-crystalline material,the lowest cost per unit of stiffness of any semi-crystalline material,9,Solvay Value Proposition,Fuel Systems,Requirements,燃油系统的需求,Low Permeation,低渗透,Static Charge Dissipation,抗静电,High Temperature Resistance,耐高温,Alcohol Resistance,耐醇性,Diesel&Bio-Diesel Resistance,耐柴油和生物燃油,Solvay Fuel System Value Proposition,苏威高性能材料在燃油系统中的价值,10,Value Proposition,Focused new materials development,Amodel,EXT1800 Extrusion Grade,Low Permeation and high chemical resistance.,Vapor line,In-tank line,Oil line,Water Glycol line.,Amodel,LTm Co-extrusion with PA 11/12.,Low Permeation Fuel Line.,Low cost solution to ETFE,PVDF.,Ixef,BXT-1000 Blow Molding and Extrusion Grade,Low Permeation,Alcohol resistance material for 5/6 layer blow molding,Ixef,BXT-2000 Impact Modified Blow Molding and Extrusion Grade,Low Permeation,Alcohol resistance material for 2/3 layer blow molding,Conductive Portfolio,Amodel A-1625 HS&A-6625 HS for injection molding,Ixef BXT-3000 for Blow molding,11,High Temperature Resistance,Tensile Strength Half Life for Glass Reinforced Polyamides,ISO 2578 Thermal Aging,耐高温,5.000 Hrs,Amodel A-1133,35%GR PA 66,23%GR PA 12,185,o,C,150,o,C,120,o,C,ISO 2578,热老化,玻纤增强聚酰胺拉伸强度的半衰期,12,Bio-Diesel Resistance,耐生物柴油,50%Diesel+50%RME Bio-diesel+5%Water(1),100%Diesel+5%Water(1),Initial Value After 5,000 Hrs Exposure 110,o,C,(1)Solution also contains 100 mg each Cu,Fe,Al metals (1)Solution also contains 100 mg of Cu,Fe,Al metals,100,柴油,+5,水（,1,）,溶液中含有铜，铁，铝各,100mg,50,柴油,+50,RME,生物柴油,+5,水（,1,）,（,1,）溶液钟还含有铜，铁，铝各,100mg,原始值,100,C5000,小时浸泡后,13,Ethanol/Methanol Resistance,耐乙醇,/,甲醇,Amodel AT-1002 Comparison to acetal(POM),Mechanical Strength,Similar to POM after long term exposure in methanol fuel,Dimensional Stability,Less dimensional change(swell)after long term exposure to methanol fuel,Fuel Immersion 60,o,C for 1000 Hours,燃油浸泡,1000,小时,60,C,Amodel,AT-1002,与,POM,的对比,机械强度,长时间浸泡与甲醇溶液中后与,POM,类似,尺寸稳定性,长时间浸泡与甲醇溶液中后尺寸发生很小的变化,14,Static Charge Dissipation,防静电,Applications requiring stiffness,impact strength and,static charge dissipation,Fuel flanges,燃油发兰,Connectors,连接器,Pump components,油泵部件,Fuel filter housings,燃油过滤器壳体,Amodel A-1625 HS,应用需要强度,抗冲击和防静电,15,Low Permeation,低渗透,Test Fuel CE10,Testing 60,CThe film sample is in contact with fuel(300-500 hours),Film thickness 50-100 microns,Similar to SAE J2659,=,Permeate,Collection Cup,Polymer,Film,Vent,Fuel,Thermal Chamber,To Gas Chromatograph,Helium,Purge Gas,=,Permeation Test Set Up for Film,薄膜渗透测试,试验用燃油,CE10,试验温度,60,C,薄膜与燃油接触（,300-500,小时）,薄膜厚度,50100,微米,类似,SAE J2659,16,Low Permeation,低渗透,Material Barrier Properties -Test Fuel CE 10 60,o,C,(1),Fuel CE 10=45%Isooctane,45%Toluene,10%Ethanol,17,Injection Molded Applications,注塑应用,18,APPLICATION PROFILE,Application:Fuel&Vapor Line Quick Connectors,应用：燃油,&,蒸汽管快速接头,Material,（材料）,:,Amodel AT-1116 HSApplication Requirements,应用要求,High continuous use temperature (170,C),连续使用温度,170,C,Low permeation(0.54 g.mm/m,2,.d),低渗透,0.54 g.mm/m,2,.d,Low swell in all fuels,各种燃油中保持低膨胀,Resistance to ZnCl,2,attack,耐,ZnCl,2,腐蚀,Resistant to all fuels,耐任何燃油,Cost effective vs.GR PA 12,低成本,vs.GR PA 12,APPLICATION PROFILE,应用解析,19,Application:ESD Fuel Line Quick Connectors,应用：,ESD,燃油管快速接头,Material,（材料）,:,Amodel A-1625 HS,Application Requirements,应用要求,High continuous use temperature(170,C),连续使用温度,170,C,Low permeation,低渗透,(0.54 g.mm/m,2,.d),Resistance to fuel attack,耐燃油腐蚀,Flex fuels,alcohol fuels,bio-fuels,乙醇燃料，生物燃料Resistance to ZnCl,2,attack,耐,ZnCl,2,腐蚀,Electro-static charge dissipation,防静电,Cost effective vs.conductive GR PA 12,低成本,VS.,防静电的,GR PA 12,APPLICATION PROFILE,应用解析,APPLICATION PROFILE,应用解析,Application:Fuel Pump End Cap,应用：燃油泵节流阀端盖,Material,材料,:,Amodel AT-1002 HS,Application Requirements,应用要求,Resistance to all fuels,耐各种燃油腐蚀,Good elongation/impact resistance for press fit of tubes and connectors,在压装油管和连接器时有良好的断裂生长率和耐冲击性能,Improved thermal performance vs POM(120,o,C vs 80,o,C),提高热性能,Superior creep resistance vs.POM,较好的抗蠕变性,vs.POM,Superior fatigue resistance vs.POM,较好的抗疲劳性,vs.POM,20,APPLICATION PROFILE,应用解析,Application,应用,:Fuel Rail,油轨,Material,材料,:,Amodel AS-1145 HS,Application Requirements,应用要求,Dimensional stability,尺寸稳定,High strength&stiffness,高强度和硬度,Thermal shock resistance-40,o,C to 121,o,C with 0-2 bar pressure,在,0-2 bar,压力下抗热冲击,-40,o,C,到,121,o,C,Resistance to all fuels(121,o,C),耐各种燃油的腐蚀,(121,o,C),Resistance to under hood chemical environment,抵抗引擎下的化学环境,Low permeation,低渗透,21,22,APPLICATION PROFILE,Application:Diesel Fuel Sending Unit,应用：柴油机送油单元,Material,材料,:,AMODEL,AT-1002 HS,Application Requirements:,应用要求,Chemical resistance to diesel fuel/bio diesel 125,C,在,125,C,下耐柴油和生物燃油,Increased temperature performance over POM,PBT or PA 66,比,POM,PBT,或,PA 66,提高了耐热性能,High impact and stiffness over the temperature range(-40,o,C to125,o,C),在,(-40,o,C to125,o,C),的温度范围外保持较高的耐冲击性和强度,Elongation for snap fits,press fits,and living hinges,在装配中保持良好的伸长率,Resistance to acids,耐酸性,Creep and fatigue resistance,抗蠕变和疲劳性,APPLICATION PROFILE,应用解析,23,APPLICATION PROFILE,APPLICATION PROFILE,应用解析,Head,Bowl,Application:Diesel Fuel Filter,应用：柴油过滤器,Material,材料,:,AMODEL,AS-1145 HS,Application Requirements:,应用要求,Chemical resistance to diesel fuel/bio diesel 125,C,在,125,C,时耐柴油和生物燃油,Metal like performance,具有金属性能,Strength,强度,Stiffness,硬度,Creep,蠕变,May need to be ESD for future North American Applications,抗静电（北美）,24,APPLICATION PROFILE,Application,应用,:Fuel Flange,燃油法兰,Material,材料,:,AMODEL,AT-1125 HS,Application Requirements:,应用要求,Chemical resistance to hot diesel/bio-diesel up to 140 C,在,140 C,以下耐柴油和生物燃油,Higher continuous use temperature than POM,PBT or PA 66,连续使用温度高于,POM,PBT,或,PA 66,High impact resistance,抗高冲击性,Resistance to acids,耐酸性,Creep and fatigue resistance,抗蠕变和疲劳性,APPLICATION PROFILE,应用解析,25,APPLICATION PROFILE,Application,应用,:Roll Over Valve,翻转阀,Material,材料,:,AMODEL,AT-1002 HS,Application Requirements:,应用要求,Chemical resistance to all fuels,耐各种燃料,Resistance to acids,耐酸性,Meet PZEV Permeation,符合,PZEV,标准,High impact resistance,抗高冲击,Over-mold capability,可以,2,次成型,APPLICATION PROFILE,应用解析,26,Extruded Applications,挤出应用,27,Application,应用,:Fuel&Vapor Line,燃油,&,蒸汽管,Material,材料,:,Amodel EXT-1800,Application Requirements,应用要求,Thermal resistance to 90,o,C with peek temperatures of 115,o,C,耐温到,90,o,C,，短期温度可达,115,o,C,-40,o,C cold temperature impact resistance -40,o,C,的低温下抗冲击,Resistance to all fuels.,耐化学性,Low permeation,低渗透,Spin welded connections to improve joint integrity,旋转焊接,Acid resistance,耐酸,Fatigue resistance,耐疲劳,Cost effectiveness,低成本,APPLICATION PROFILE,应用解析,28,Application:Convoluted Tubing for,In-Tank and Vapor Line Applications,应用：波纹管,Material,材料,:,Amodel EXT-1800,Application Requirements,应用要求,Thermal resistance to 90,o,C with peek temperatures of 115,o,C,耐温到,90,o,C,，短期温度可达,115,oC,-40,o,C cold temperature impact resistance -40,o,C,的低温下抗冲击,Resistance to all fuels.,耐化学性,Low permeation,低渗透,Cost effectiveness,低成本,Improved Flexibility,提高弹性,Acid resistance,耐酸性,Fatigue resistance,耐疲劳性,APPLICATION PROFILE,应用解析,29,Introducing New Amodel,Low Tm PPA,低熔点,Amodel,PPA,Improved Processing vs.Amodel EXT-1800,改善加工,vs.Amodel EXT-1800,Similar type chemistry as EXT-1800,与,EXT-1800,类似的化学性能,Much wider extrusion window,更加宽的加工窗口,Extrudes in the same range as ETFE(290-310,o,C),与,ETFE(290-310,o,C),相同的挤出温度,Designed for Co-extrusion with PA 11/12,可以与,PA 11/12,共挤,Performance,性能,High elongation(100%),高延展性大于,100%),High impact(No Break -40,o,C),高冲击（不断,-40,o,C),Excellent thermal aging(125,o,C),卓越的耐热老化,(125,o,C),Low permeation(1.0 g.mm/m,2,.day),低渗透,(80%Retention of properties after exposure to automotive fluids,在各种汽车液中，仍能,保持,80,以上的性能,ESD Conductivity,抗静电,Quick connect grades and blow molding grades available,others in development,用于快速结头和吹塑等级。,Cost,成本,Lower than current high performance systems,成本,低,39,To Learn More About Solvay Advanced Polymers,了解更多关于苏威高性能塑料,Solvay Shanghai Co.Ltd.,Shanghai China,+86.21.5080.5080,Solvay Korea Company Ltd.,Seoul,South Korea,+82.2.756.0355,Solvay Advanced Polymers,KK,Tokyo,Japan,+81.3.5210.5570,Solvay Advanced Polymers,L.L.C,Alpharetta,Georgia,USA,+1.770.772.8200,THANK YOU,谢谢,