有机物换算成cod表-secret.doc

表1 常见化合物的CODCr、CODMn、BOD5、TOD和TOC之相关值（1） 烃及卤代烃类序号化合物名称结构式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODcrCODcrTHOD (%)BOD5BOD5THOD (%)TODTODTHOD (%)THODTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲烷CH4100040007505.532一氯甲烷CH3Cl10009504772872380.64.03二氯甲烷CH2Cl21000376(360)014122.664三氯甲烷CHCl310005363351005(101)5.335三溴甲烷CHBr31000(253)047.5(48)6四氯化碳CCl41000(416)208078(78)7乙烷CH3CH3100037257988197.24.678环氧乙烷CH2CH2O10001877(2210)117084.72005452.539二氯乙烷C2H4Cl210001132(810)2425(243)4.66101、2二氯乙烷ClCH2CH2Cl1000(258)11325451982431854.66111.1.1三氯烷Cl2CHCH2Cl1000840179.9(180)4.6712四氯乙烷Cl2CHCHCl21000(201)667496242143(143)2230.494.6613丙烷H3CCH2CH3100036298174.4414环氧丙烷CH2CHCH3O10002203(2210)6203.5515CH2CHCH2Cl Cl1000(182）11324802473491970.513.5516CH2CHCH2Cl Br Br1000425(440)1532.7817CH2=C-CH=H3C10003294(3240)425(440)8823.7318CF3CH2ClCH21000727(350)2732.6619正十二烷C12H2010003482(3480)2808474.1120汽油7821石油1000(35004500)3000430030043022重油3000366033023煤油53024乙烯H2C=CH2100034298574.0251.1二氯乙烯Cl2C=CH210006679902502.67（2） 醇类化合物序号化合物名称结构式化合物浓度（mg）THODCODcrCODcTHOD (%)rCODmnCODmn THOD (%)rBOD5BOD5THOD (%)rTODTODTHOD (%)rTHOCTOCTOC THOC(%)rBOD5COD5THOD THOCTHON1甲醇CH3OH1000100501500226.27514201440904007.62710.11020112051.2887568.25138594.287.0374.537.53739981030.784.02乙醇C2H3OH1000100502080243.8104.31980109094.795.22301188.611.07510.56.4157010007223998.2520.95253.5102.80.803.993苯甲醇C6H5CH2OH1000251548119.0730776.83.234氯乙醇ClCH2CH2OH10009930.12983.335氰乙醇NCCH2CH2OH1000135080059.3506.52.671976氨基乙醇NH2CH2CH2OH10001310388.91200(198.3)51.0930(132.2)3435691.53930.720.673.33229.27乙酰氨基乙醇CH2CH2OHNH2COCH310001400110078.7465.73.01135.88甲氧基乙醇CH2CH2OHOCH310001682（1680）110065547313569乙氧基乙醇CH2CH2OHOC2H610001953(1960)106054.3532.63.6710苯乙醇C6H5CH2CHOH210002619.5(2620)1500158080.6785.83.3311正丙醇C3H2OH10001002396(2400)2402220224092.593.531013.01540158065.923397.059948.64490.60.74.012异丙醇CH3CHOHCH310002396(2400)376.122402250(349.8)93.993.064(26.3)3.07.0159066.2392104.25990.714.0133.氯丙醇CH2CH2CH2OHCl10001354(1350)1360101.00.064.0380.80.013.56141,3二氯丙醇CH2CH2CHOHCl Cl1000868(1200)8401160133.6101.2279.10.013.1015丙烯醇CH2=CHCH2OH10002203(2216)168242096.2179081.316296.0619.70.843.5516丁醇C4H9OH10002590(2600)2400241093.128011.01140126048.6647.60.524.017异丁醇CH3CHCH2OHCH3/10002590(2600)2299230088.82409.01600166064.1647.60.724.018特丁醇C4H9OH10002590(2600)336.82180(282.9)848400032596.5647.64.019戊醇C5H11 OH10002723(2730)1230162059.5680.74.020异戊醇CH3CHCH2OHCH3/10002723(2730)150055.1680.74.020异戊醇50136(120)63.3766310083.33435102.84.021己 醇C6H16OH10002819(2820)704.74.022环己醇C6H6OH10002819(2820)160056.3704.74.0234.甲基戊醇(2)CH3CHCH2CHCH8CH3/ OH10002829(2820)704.74.024辛醇C5H17OH10002949(2950)全12007374.025异壬醇C9H10OH10002995(3000)2800937494.026乙二醇CH2OHCH2OH1000100501289(1290)230.764.51240(221.5)9693.9100490(66.9)503882977.522162595.896.838738.739100.80. 40.33.3327聚乙二醇（CHCHOHOH）n10003003028丙二醇(1,2)CH2CHCH3OH OH10001682(1690)163096.4116068.64730.713.5629丙二醇(1,3)CH2CH2CHOH OH10001682(1680)164097.6全27616.14730.163.5630甲基,丁二醇(1,3)CH3C CH2CH2OHCH3 OH10002151(2140)全13505763.73311,氯丙二醇(1,2)ClCHCHCH3 OH OH10001017(920)3273.11322,甲基戊二醇(2,4)CH3CCH2CHCH3CH3/ OH OH10002302(2301)653296093.7833丙三醇CH2 CH CH2 OH OH OH1000454.7100601216(1200)553.8297.4221.510060.911701180527.5(282.8)212.696.79595.136630195231.281077046.466.063.176.228420357.595.510394.4390.948.939.1513910499.80.693.1134季戊四醇C(CH2OH)410001410(1420)604.2440.73.235ClCH2 /CH2OHCClCH2/ CH2OH1000940.5293.03.236聚乙烯醇(CH2=CHOC)nn=17501818301.737正十二烷醇1000304046015.1（3） 醚类化合物 化合物名称化合物浓度（mg）THODCODCrCODCr/THOD (%)CODMnCODMn/THOD (%)BOD5BOD5/THOD (%)TODTOD/THOD (%)THODTOCTOC /THOC(%)BOD5/CODcrTHOD THOC1乙醚C2H5OC2H510002595(2590)362.6827849(136.7)34.932.437.710034394.6615.4(647.6)4.222O(C2H4OH)2100010001507.491060全176565.32.673O(C2H4OC2H5)210002173(2180)1004.6592.63.674苯甲醚C5H6OCH3100025161709.47773.24（4） 醛类化合物序号化合物名称结 构 式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODmnCODmnTHOD (%)BOD5BOD5THOD (%)TODTODTHOD (%)THOCTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲醛HCHO100010050107053.3499813761904606.37311.856068012.663.623.62648.74004020361890900.0842.682苯甲醛C6H5CHO10002412(2420)287120.81980808057.047.61500 162066.4676754.9262.5113.591.593.5791.669.55383.50.823.053二甲氧基缩甲醛CH(OCH3)210001620(1680)16402702704800.163.334乙醛CH3CHO10001618(1820)369.8820105057.815019010.565091050.136899.5544.80.873.335丙醛C2H5CHO10002204(2200)全1190619.83.566丙烯醛CH=CHCHO10001998(2000)17208066033642(643)0.383.117苯基丙烯醛C6H5CH2=CHCHO10002523(2559)3.118丁醛C3H7CHO10002441(2440)11603.019丁烯醛CH3CH=CHCHO10002280(2410)800684.73.33103羟基丁醛H3CCHCH2CHOOH10001820(1750)544.83.3411糠醛- CHOO10001665(1670)770791.92.1012苯甲醛C6H5CHO10002412(2420)287120.81980(229.6)82.18057.647.615001620192.366.462.267.26754.9262.5113.593.579260.55883.50.843.0513三氯乙醛Cl3CCHO1000220162.814二甲氧缩甲醛OCH3CHOCH310001620(1680)16402704863.33（5） 酮类化合物序号化合物名称结 构 式化合物浓度（mg）THODCODcrCODcrTHOD (%)CODmnCODmnTHOD (%)BOD5BOD5THOD (%)TODTODTHOD (%)THODTOCTOC THOC(%)BOD5CODcrTHOD THOC1丙酮CH3COCH310001002204(2210)220178.51102218802707(149.4)18.585948484.18101120(66)7.63750.83737.3215176.51039898.09462054.740770.540.440.413.552甲乙酮CHCOC2H51000100502440374.5122.119202200(286)78.790775.44.41810(274.9)60.7747449.7352.58910494.072.885.7665.766.660659097.50.820.963.673甲基异丙基酮H3CCOCH(CH3)210002002692.9726793.13.734环乙酮C6H6O26122610)100038.4734.73.565甲基异丁基酮CH3COCH2CH(CH3)2100027122720）120471933786甲基戊基酮CH3COC5H1110002805（2800）7氧甲基吡咯烷酮N =OCH38苯乙酮C6H5COCH3表2 工业中常见有机化合物的一些有关参数序号化合物名称熔点沸点密度kg/L水中溶解度g/L动物半死量LDmg/kgCOD值g/gBOD值g/g生物可降解性毒性mg/L1一乙胺-80.616.60.71易2.130.80.375+292一甲胺-92.5-7.50.769易2.5+3一氯乙酸611891.58易1650.59-0.30.51+4一氯甲烷-97.7-245005乙二胺8.51170.898互溶11601.050.01(1.0)0.008+0.856乙二醇-131981.116互溶85401.291.51.150.67(0.91)0.84+100007乙二醇单乙醚1350.93互溶3000(致死量)1.921.580.806+8乙二醇单丁醚-401700.9032.20.71.689乙二醇单甲醚-851240.97互溶3400(致死量)1.690.120.50(1.10)0.6551000010乙苯-95136.20.8670.1435001.73+1211乙苯胺（混合物）0.3780.0480.127+12乙炔-81.8-840.620.3200-132-乙基已醇-76183.50.834110602.95(-2.29)0.78+8214乙基仲戊基酮1601620.852515乙烯亚胺-7155560.832互溶5.516乙脯-44.981.60.783互溶6121.561.40.898+68017乙酰乙酸乙酯1801811.0218乙酰丙酮-23.21390.9761250.1(1.24)6719乙酰马啉141521.126130020乙酰苯汞1534.37100021乙酰苯胺1143051.215.644001.222乙酰胺82.52221.159易300001.080.630.740.583+1000023乙酸16.7118.11.049互溶33001.070.340.880.805+24乙酸乙烯酯-100730.9372516130.80.597+625乙酸乙酯-8.3677.20.901801.541.880.86(1.57)0.80+26乙酸丁酯-73.5126.10.8821432002.20.520.236+11527乙酸丙酯-951020.8918.917028乙酸戊酯-751480.8791.82.340.310.90.132+14535029乙酸异丁酯-98.91180.8716.352.20.67(2.05)0.932+20030乙酸异丙酯-73900.877182.020.260.129+19031乙酸环已酯17718332乙酸苯酯1961.111533乙酸叔丁酯960.8967834乙酸钙39.842800.710.420.592+35乙酸钠1230.580.520.75+36乙酸钾25532500.640.320.50+37乙酸铵易38乙醇-11778.40.789互溶65002.08-1.820.875+650039乙醇胺111721.02互溶6501.271.310.780.93(1.88)0.61+630040乙醛-12420.80.783互溶19301.820.91(1.07)0.59+41乙醛酸790.630.1750.24842乙醚-116350.714690.0343二乙汞440044二乙铵-4550.30.711互溶6482.951.30.445+45N,N-二乙基苯胺-38.82160.93514.42.592.790046N,N-二乙基羟胺2.540.4947二乙烯三胺五醋酸1.020.010.01548二乙醇胺282691.092互溶1201.061.520.10.095+1000049二丙酮醇-571690.9340002.110.070.5882550二甘醇单乙醚2020.99互溶859097401.860.20.5825551二甘醇单丁酯-682310.96互溶52二甘醇单丁醚-68231-0.96互溶550066002.080.2853二甲苯0.133.170.980.309+54二甲苯胺（混合物）2.640055二甲氧基甲烷440.85633056二甲胺-92.26.90.68易2402.151.3(0.4)0.653+572,5二甲基-1,4二恶烷2001.2-0.40.205-582,4-二甲酚26211.51.0360592,5-二甲酚732120.9710602,6二甲酚462035762.6200.8200.313,+613,4二甲酚652251.0231.5623,5二甲酚682190.8263二异丙胺-96.383.40.72250064二异丙醚-86690.73950006500（致死量）0.1965二苯醚282591.0730.0213990662,6二叔丁基-4-甲基酚702651.0480.000418002.270.5167N,N二甲基甲酰胺-611530.95互溶42001.540.02(0.10)0.065,683,3-二甲基戊二酸1020.02,1.47)69二甲基亚砜18.51891.170N,N-二甲基苯胺21920.9612.532.630.250.095,712,4-二甲基苯胺2180.988722,5-二甲基苯胺15.52170.980734,4二氨基二苯甲烷93231/1115742,6-二氨基吡啶1212851.4700752,6-二羟基异菸酸3000.980.086,(0.10)0.092762,4-二硝基甲苯703001.5210.31.330057772,6-二硝基甲苯646626782,4-二硝基苯酚1141.6835.63011579二硫化碳108.646.31.2632.335(N)80二硫代磷酸-0,0-二甲酯49.92510000811,1-二氯乙烷-97.457.31.1745.50.002135821,2-二氯乙烷-35.983.71