食品和食品安全热点应用.pdf

020004000123456789101112131415 min.2.750500810123456789101112131415 min.8.250200010002930123456789101112131415 min.7.97050001.3e41.0e4123456789101112131415 min.8.89IntensityIntensityIntensityIntensityApp ID 16402?Luna 3 m C18(2)150 x 2.0 mm 40 C A:0.1%Formic acid in water B:Acetonitril e 0.2 mL/min 30?LGradi ent:Time%A%B 0 22 78 6.0 99 1 9.0 99 1 9.1 22 78 16.0 22 78Anal ytes:1.3-amino-5-morpholinomethyl-2-oxazol idinone(AMOZ)2.Semicarbazide(SC)3.Aminohydantoin(AH)4.3-amino-2-oxazol idinone(AOZ)?硝基呋喃及其代谢物?色谱柱：规 格：柱 温：流动相：流 速：进 样：?9.859.760.01234567891011121314 min.1234567891011121314 min.2.0e44.0e46.0e48.0e41.0e51.2e51.4e51.6e51.8e5Intensity0.02000.04000.06000.08000.01.0e41.2e41.4e41.6e4IntensityApp ID 16401 2.5e42.0e41.5e41.0e45000.00.0Intensity2.5e43.0e43.5e44.0e42.0e41.5e41.0e45000.00.0Intensity1234567891011121314 min.1234567891011121314 min.2.412.193.112.361.453.43App ID 16400?结晶紫孔雀石绿隐性结晶紫隐性孔雀石绿?Fi gure 1.LC/MS/MS of SPE extract of sul f a drugs(see Tabl e 1 f or MRM detail s)6.0e54.0e52.0e5002468101214 min6002.26Sul f anil amide173.1/93.1400200002468101214 min2.5e52.8e56.01Sul f amethoxazol e265.1/92.01.0e55.0e4002468101214 min1.5e52.0e502468101214 min6.0e54.06Sul f athiazol e256.0/92.14.0e52.0e50Fi gure 1.Cont d600400200002468101214 min02468101214 min6.0e54.064.31Sul f amerazine265.1/108.26.66Sul f aquinoxal ine301.2/92.103.0e52.0e51.0e50Tabl e 1 Physicochemical Characteristics and Recovery Yiel ds of Sul f a DrugsAnal ytesSpi ked Conc.(ng/mL)MRMLog P of Anal ytepKa of Anal yte%Re-covered%RSDSul f anil amide100173-93.1-0.622.4,10.434%2-5%Sul f athiazol e100256-92.00.092.08,7.0781%2-5%Sul f amerazine100265.1-108.20.541.16,1.54,2.0,9.5578%2-5%Sul f amethoxazol e100254.1-92.01.581.83,5.6594%2-5%Sul f aquinoxal ine100301.2-92.11.681.86,5.56IS2-5%?1.维生素C2.Acesulphame K3.糖精4.阿斯巴甜5.奎宁6.山梨酸盐7.苯甲酸盐8.咖啡因?3、核黄素（维生素B2）4、盐酸 5、吡哆醇（维生素B6）6、硫胺（维生素B1）7、抗坏血酸（维生素C）8、维生素B12 9、叶酸?0.040.212.423.114.445.677.217.338.448.559.6911.0013.5314.14XIBIZHEZHOYIDIZHEYIW4-J IA123456789101112131415Time min051015Response mV?!?（7H M-G 005-31）?0.771.852.142.472.803.213.493.743.954.294.704.945.276.887.087.337.629.129.9510.9712.3813.2413.9918.0922.05YIQYISJ IABINZHDINZHYIDXIBIZHYISHXJ ISRUKA24681012141618202224Time min510152025303540Response mV?样 品：?（7H G-G 007-11）（7H G-G 007-11）?0.040.212.222.482.562.703.083.313.583.813.994.384.568.859.2610.79-P+PYIYIJ IAYIZH1234567891011Time min05101520Response mV?（7H G-G 007-11）?Zebr on ZB-WAXPLUS 30 meter x 0.25 mm x 0.25 m7HG-G013-11Split 30:1 140 C,0.2 LHelium 1.4 mL/min(constant flow)35 C f or 5 min to 200 C 30 C/min f or 1 minFI D 280 CI nj ection of pur e Glenfiddich1.2.3.4.5.App I D 16046 6.7.8.9.Zebr on ZB-624 20 meter x 0.18 mm x 1.00 m7FDG005-22Split 40:1 140 C,0.2 LHelium 1.5 mL/min(constant flow)35 C f or 4 min to 85 C 10 C/min to 200 C 25 C/min f or 1 minFI D 200 CI nj ection of pur e Glenfiddich1.2.3.4.5.App I D 16044 6.7.8.9.221044356688,9710min01324245667898101214min格兰菲迪士苏格兰威士忌格兰菲迪士苏格兰威士忌色谱柱:规 格:进 样:载 气:温度程序:检测器:样 品:色谱柱:规 格:进 样:载 气:温度程序:检测器:样 品:货 号:货 号:乙醛乙酸乙酯乙缩醛 甲醇乙醇 1-丙醇异丙醇异戊醇2-甲基丁醇 乙醛甲醇乙醇1-丙醇乙酸乙酯 异丙醇乙缩醛异戊醇2-甲基丁醇 AcetaldehydeEthyl AcetateAcetalMethanolEthanol1-Pr opanol I sobutanol I soamyl alcohol 2-MethylbutanolAcetaldehydeMethanolEthanol1-Pr opanolEthyl Acetate I sobutanol Acetal I soamyl alcohol 2-Methylbutanol?681234510121416182022242628303234minminminmin10121416186981011 12131415161718192023242526272829303132333435-3740454647-4954535051,5238-394142-4421,2272628303292949596,979899111,112114113100101102103104105106107108109110932055222456,5759625860,6163646566,677068,69717273757776747879-8187828583,848688899091 色谱柱:Zebron MultiResidue-2 尺寸:30 meter x 0.25 mm x 0.20 m 货号:7HG-G017-10 进样:不分流 260 C.1 L 载气:氦气 0.9 mL/min(恒速)升温程序:80 C 保持 0.5 min,10 C/min 至150 C,4 C/min至 240 C,15 C/min至 320 C 并保持 3 min 检测器:MSD 320 C;45-400 amuApp I D:16183=MR-2?81012141618202224262830323413421192422252023282926313037183649324353525051394061605965626369,64,6766687072738480,767786878388818927162438,55457585655961112-141510141618minmin22249194,959610010299101103104105106107108109110111112,11311496,9792939033,3541,44,4542,4746,4871,74,78,7579,82717App I D:16184=MR-1 色谱柱:Zebron MultiResidue-1 尺寸:30 meter x 0.25 mm x 0.20 m 货号:7HG-G016-10 进样:不分流 260 C.1 L 载气:氦气 0.9 mL/min(恒速)升温程序:80 C 保持 0.5 min,10 C/min 至150 C,4 C/min至 240 C,15 C/min至 320 C 并保持 3 min 检测器:MSD 320 C;45-400 amu 峰 样品分析物 1.敌敌畏 2.丙草丹 EPTC 3.异丁草丹 4.3,5-二氯苯甲酸(甲酯)5.灭草猛 6.克草猛 7.速灭磷 8.4-硝基苯酚(甲酯)9.速灭磷异构体 10.敌百虫 11.麦草畏（甲酯）12.2-甲-4-氯丙酸（MCPP）(甲酯）13.禾草敌 14.丁噻隆 15.2-甲-4-氯苯氧基乙酸 (MCPA）（甲酯）16.避蚊胺 17.焦磷酸四乙酯（甲酯）18.内吸磷 19.二氯丙烯（甲酯）20.氟乐灵 21.虫线磷 22.草灭特 23.氟草胺 24.毒草胺 25.灭克磷 26.氯苯胺灵 27.2,4-D(甲酯）28.治螟磷 29.二溴磷 30.甲拌磷 峰 样品分析物 31.百治磷 32.五氯苯酚（甲酯）33.环丙氟灵 34.内吸磷异构体 35.扑灭通 36.阿特拉通 37.久效磷 38.阿特拉通异构体 39.2,4,5-涕丙酸 40.特丁硫磷 41.扑灭津 42.二嗪磷 43.拿草特 44.莠去津 45.西玛津 46.特丁津 47.敌杀磷 48.地虫硫磷 49.乐果 50.2,4,5-T甲酯 51.乙拌磷 52.草灭平（甲酯）53.磷胺异构体 54.仲丁通 55.除线磷 56.2,4-DB（甲酯）57.特草定 58.地乐酚（甲酯）59.甲草胺 60.甲基氯吡磷 峰 样品分析物 61.磷胺 62.皮蝇磷 63.扑草净 64.莠灭净 65.苯达松（甲酯）66.丙硫特普 67.西草净 68.嗪草酮 69.甲基对硫磷 70.去草净 71.异丙甲草胺 72.马拉硫磷 73.四氯对苯二甲酸二甲酯 (DCPA)74.杀螟硫磷 75.氯吡磷 76.氯甲硫磷 77.三唑酮 78.毒莠定（甲酯）79.异乐灵 80.倍硫磷 81.MGK-264异构体 82.对硫磷 83.脱叶亚磷 84.除草定 85.氯芬磷异构体 86.MGK-624 87.二甲戊乐灵 88.双苯酰草胺 89.氯芬磷 90.丁草胺 峰 样品分析物 91.丁烯磷 92.司替罗磷 93.丙硫磷 94.恶草酮 95.氧化脱叶亚磷 96.敌草胺 97.苯线磷 98.乙氧氟草醚 99.三氟羧草醚 100.萎锈灵 101.乙硫磷 102.三环唑 103.丰索磷 104.卡波硫磷 105.伐灭磷 106.哒草伏 107.环嗪酮 108.苯硫磷（EPN）109.亚胺硫磷 110.溴苯磷 111.甲基谷硫磷 112.氯苯嘧啶醇 113.乙基谷硫磷 114.蝇毒磷?保留时间 化合物6.34 四聚乙醛7.14 苯敌草（碎片1）7.81 氯谷隆IP（碎片）8.28 残杀威-C2H3NO8.61 抑草威9.07 异丙隆（碎片）10.21 恶虫威-C2H3NO10.70 克百威-C2H3NO10.85 利谷隆IP（碎片）11.43 EPTC/扑草灭11.85 敌草腈12.52 联苯12.78 异丁草丹13.36 灭草猛13.49 二氧威-C2H3NO13.73 克草猛13.88 土菌灵14.00 3,4-二氯苯胺14.36 苯胺灵14.68 速灭威14.96 d10-Acena-phthal ene15.30 福尔培 IP(碎片)15.44 地茂散15.71 五氯苯15.91 邻苯基苯酚15.92 克菌丹IP碎片(THPI)15.95 甲萘威-C2H3NO16.14 禾草敌16.24 丁噻隆16.38 异丙威17.80 四氯硝基苯18.08 仲丁威18.14 毒草胺18.31 草灭特18.40 残杀威-C2H3NO18.50 Ethafluralin18.53 2,3,5,6-四氯苯胺保留时间 化合物18.82 氟乐灵18.86 二苯胺18.99 氟草胺19.27 杀虫脒19.50 CI PC19.57 2,3,5-三甲基苯酚19.63 牧草胺19.67 燕麦敌-119.83 Penmediapham(碎片-2)20.11 恶虫威-C2H3NO20.16 MBTZ20.19 燕麦敌-220.31 猛杀威20.36 -六六六(-BHC)20.55 2,6-二异丙基 萘 (2,6-DI PN)20.66 六氯苯21.30 乙氧喹啉21.56 扑草通21.58 环丙氟灵21.65 3,4,5-三甲基苯酚21.68 合杀威-121.77 双苯胺灵21.79 氯硝胺21.86 广灭灵/异恶草酮21.97 克百威21.98 西玛津22.01 氯谷隆22.02 莠去津22.02 特丁通22.23 五氯硝基苯22.38 -六六六(林丹)22.45 环莠隆22.46 特丁津22.47 灭害威22.63 氯乙氟灵22.74 拿草特22.76 七氟菊酯22.84 草特灵22.98 野麦畏23.11 氨基乙氟灵2319 嘧霉胺23.19 五氯苯甲腈23.25 合杀威-223.58 仲丁通23.59 自克威23.93 Pirimacarb23.99 -六六六(-BHC)23.99 甲呋酰胺24.19 辛噻酮保留时间 化合物24.22 -螺环菌胺24.48 五氯苯胺24.83 乙硫苯威24.84 二甲草胺24.98 -六六六(-BHC)25.08 敌草净25.23 七氯25.29 乙烯菌核利25.51 二氧威-C2H3NO25.55 百菌清25.59 -螺环菌胺25.66 敌稗25.73 螨蜱胺25.91 甲霜灵25.94 扑草净25.98 Metribuzen25.98 莠灭净25.98 西草净26.20 醚菌酯26.35 甲萘威-C2H3NO26.37 3-OH 克百威26.55 去草净26.57 麦穗宁26.70 五氯茴香硫醚26.84 艾氏剂26.86 乙呋草黄26.95 芬普福26.95 抑菌灵27.04 异丙甲草胺27.05 灭梭威27.14 乐斯本27.15 草完隆27.25 敌草索/DCPA27.49 萘乙酰胺27.66 仲丁灵27.74 乙霉威27.97 三唑酮28.09 异乐灵28.10 酞菌酯28.28 MGK-264(峰-1)28.39 Methf uroxan28.44 氟醚唑28.50 p,p -三氯 杀螨醇 (碎片)28.51 氰草津28.81 二甲戊乐灵Continued on next page使用Zebron Mul ti Resi due-1得到的其他农药的保留时间 色谱柱:Zebron MultiResidue-1 尺寸:30 meter x 0.25 mm x 0.25 m 货号:7HG-G016-11 进样:不分流 280 C.1 L 载气:恒速 氦气 1.2 mL/min 升温程序:60 C,10 C/min 至130 C,4 C/min 15 C/min至 320 C 并保持 3 min 至:230 C,10 C/min至300 C 检测器:MSD 300 C?保留时间 化合物28.86 大芬灭 28.89 去甲基大芬灭28.91 氧化氯丹29.01 增效胺MGK-264(峰-2)29.20 环氧七氯29.24 嘧菌环胺29.25 吡喃灵29.34/29.40 丙烯菊酯29.48 甲抑菌灵29.60 啶斑肟-129.64 Penaconazole29.85 氟虫腈30.00 呋霜灵30.06 氟菌唑30.18 腐霉利30.33/30.76 三唑乙醇(2 峰)30.51 反式-氯丹30.55 Aniten/抑草丁E.30.60 克菌丹30.81 啶斑肟-230.82 福尔培30.86 顺式氯丹30.88 噻苯咪唑30.97 硫丹-I30.98 反式九氯31.62 草萘胺31.94 恶草酮32.02 己唑醇32.04 稻瘟灵32.10 氟酰胺32.18 勿落菌恶32.24 p,p-DDE32.25 抑霉唑32.36 除虫菊酯-132.39 狄氏剂32.42 噻嗪酮32.49 乙嘧酚磺酸酯33.13 盖草津33.20 氟哇唑33.30 萎锈灵33.36 灭克落33.36 三环唑33.39 异狄氏剂33.85/33.95 环唑醇(2 峰)33.88 杀螨酯34.01 除草醚34.06 o,p-DDT34.10 顺式九氯34.20 烯唑醇34.32 乙环唑-134.49 乙环唑-2保留时间 化合物34.51 硫丹-I I34.62 除虫菊酯-234.81 恶霜灵35.05 苯霜灵35.11 灭锈胺35.14 肟菌酯35.53 Propiconizole/敌力脱-135.55 喹氧灵35.68 p,p-DDT35.73 o,p-甲氧氯35.86 Propiconizole/敌力脱-235.92/35.97 克螨特35.95 环草定36.00 硫丹硫酸盐36.04 增效醚36.09 苄呋菊脂36.17 氯苯嘧啶醇36.27 环嗪酮36.30 丁硫克百威36.34 戊唑醇36.44 磺乐灵36.45 拿捕净36.65 联苯菊酯36.70 氟环唑36.91 胺菊酯-137.05 溴螨酯37.13 甲氰菊酯37.16 胺菊酯-237.36 p,p-甲氧氯37.39 异菌脲37.40 吡螨胺37.45 双氧威37.47 联苯肼酯37.48 环酰菌胺37.55 喹螨醚37.80 右旋苯醚菊酯37.93 啶虫脒38.08 四氯杀螨砜38.22 百利普芬38.24 氯氟氰菊酯38.29 氟丙菊酯38.34 灭菌唑38.37 灭蚁灵38.42 双甲脒38.66 肟草酮38.93 氯苯嘧啶醇38.98 Spirodiclof en38.99 Naproanalid39.29 顺式氯菊酯39.49 反式氯菊酯39.56 双苯唑菌-1保留时间 化合物39.72 双苯唑菌-239.72 达螨酮39.87 咪鲜胺39.96 氟喹唑40.42 Cypermethrins(4 峰)40.61 腈苯唑40.73/40.99 氟氰戊菊酯(2 峰)40.88 醚菊酯41.00 啶酰菌胺41.78/41.91 氟胺氰戊菊酯(2 峰)41.80 氰戊菊酯-142.12 氰戊菊酯-242.24/44.98 烯酰吗啉(2 峰)42.41 唑菌胺酯42.75/43.12 溴氰菊酯(2 峰)43.06/43.18 苯醚甲环唑(2 峰)43.87 嘧菌酯44.63 恶唑菌酮 7HG-G016-11Mul tiResidue-1,30 m x 0.25 mm x 0.25 m7HG-G017-10Mul tiResidue-2,30 m x 0.25 mm x 0.20 m订货信息：货号描述?分析物注：所有分析物为20ppm?十氯联苯?15881图15785图组分组分?分析物：?十氯联苯分析物：注：所有分析物为20ppm?十氯联苯?样 品：1.Dichlorvos 敌敌畏2.M evinphos 速灭磷3.Trichlorfon 敌百虫4.Thopazom 硫磷嗪5.Demeton 内吸磷6.Ethoprop 灭克磷7.N aled 二溴磷8.Dicrotophos 百治磷9.Phorate 甲拌磷10.Demeton isomer 内吸磷异构体11.Terbufos 特丁硫磷12.Fonofos 地虫磷13.Diazinon 二嗪农 14.Disulfonton15.Phosphamidon 磷胺16.Dichlofenthion 除线磷17.Chlorpyrifos-methyl 甲基毒死蜱18.M ethyl parathion 甲基对硫磷19.Ronnel 皮蝇磷20.Fenitrothion 杀螟硫磷21.Aspon 丙硫特普22.Chlorpyrifos 毒死蜱23.Fenthion 倍硫磷24.Trichloronate 毒壤磷25.Chlorfenvinphos 氯芬磷26.M erphos 脱叶亚磷 27.Crotoxyphos 丁烯磷28.Stirofos 司替罗磷29.Tokuthion30.*M erphos oxone31.Fensulfothion 丰索磷32.Ethion 乙硫磷33.Bolstar34.Famphur 氨磺磷35.Carbophenothion 三硫磷36.Phosmet 亚胺硫磷37.Leptophos 对溴磷38.G uthion 谷硫磷39.Azinphos-ethyl 乙基谷硫磷40.Coumaphos 蝇毒磷 分析物：0，0，0-三乙基硫代磷酸酯燕麦敌丙虫硫磷甲基内吸磷燕麦敌丙溴磷乙硫磷乙拌磷拿草特定菌磷氨磺磷?1.Butyr ic acid methyl ester (C4:0)2.Capr oic acid methyl ester (C6:0)3.Caprylic acid methyl ester (C8:0)4.Capr ic acid methyl ester (C10:0)5.Undecanoic acid methyl ester (C11:0)6.Laur ic acid methyl ester (C12:0)7.Tr idecanoic acid methyl ester (C13:0)8.Myr istoleic acid methyl ester (C14:1)9.Myr istic acid methyl ester (C14:0)10.cis-10-Pentadecenoic acid methyl ester (C15:1)11.Pentadecanoic acid methyl ester (C15:0)12.Palmitoleic acid methyl ester (C16:1)13.Palmitic acid methyl ester (C16:0)14.cis-10-Heptadecenoic acid methyl ester (C17:1)15.Heptanoic acid methyl ester (C17:0)16.gamma-Linolenic acid methyl ester (C18:17 Oleic acid methyl ester (C18:1n9c)18.Linoleic acid methyl ester (C18:2n6c)19.Elaidic acid methyl ester (C18:1n9t)20.Linolelaidic acid methyl ester (C18:2n6t)21.Linolenic acid methyl ester (C18:3n3)22.Stear ic acid methyl ester (C18:0)23.Ar achidonic acid methyl ester (C20:4n6)24.cis-5,8,11,14,17-Eicosapentaenoic acid methyl ester (C20:5n3)25.cis-8,11,14-Eicosatr ienoic acid methyl ester C20:3n6)26.cis-11-Eicosenoic acid methyl ester (C20:1)27.cis-11,14-Eicosadienoic acid methyl ester (C20:2)28.cis-11,14,17-Eicosatr ienoic acid methyl ester (C20:3n3)29.Ar achidic acid methyl ester (C20:0)30.Heneicosanoic acid methyl ester (C21:0)31.cis-4,7,10,13,16,19-Docosahexaenoic acid methyl ester (C22:6n3)32.Eur ic acid methyl ester (C22:1n9)33.cis-13,16-Docosadienoic acid methyl ester (C22:2)34.Behenic acid methyl ester (C22:0)35.Tr icosanoic acid methyl ester (23:0)36.Nervonic acid methyl ester (C24:1)37.Lignocer ic acid methyl ester (C24:0)17.1020304050min12345678910111213151617,18192324,252826,273031323534332920,2122143736I Zebr on MultiResidue-2 30 meter x 0.25 mm x 0.20 m7HG-G017-10Split 5:1 250 C,1 LHelium 2 mL/min(constant flow)60 C f or 2 min to 160 C 13 C/min hold 5 min to 275 C/min 2 C/min hold 2 minFI D 280 CComposition r ange of analytes in standar d mix 2-4%App I D 16330 1.(C4:0)2.(C6:0)3.(C8:0)4.(C10:0)5.(C11:0)6.(C12:0)7.(C13:0)8.(C14:1)9.(C14:0)10.(C15:1)11.(C15:0)12.(C16:1)13.(C16:0)14.(C17:1)15.(C17:0)16.(C18:1 (C18:1n9c)18.(C18:2n6c)19.(C18:1n9t)20.(C18:2n6t)21.(C18:3n3)22.(C18:0)23.(C20:4n6)24.25.(C20:3n6)26.(C20:1)27.(C20:2)28.(C20:3n3)29.(C20:0)30.(C21:0)31.(C22:6n3)32.(C22:1n9)33.(C22:2)34.(C22:0)35.(23:0)36.(C24:1)37.(C24:0)食品工业脂肪酸甲酯色谱柱：规 格：货 号：进 样：载 气：温度程序：检测器：样 品：丁酸甲酯己酸甲酯辛酸甲酯癸酸甲酯蓖麻油酸甲酯 月桂酸甲酯十三酸甲酯肉豆蔻脑酸甲酯肉豆蔻酸甲酯顺-10-十五酸甲酯 十五酸甲酯软酯酸甲酯棕榈酸甲酯顺-10-十七酸甲酯十七酸甲酯 二十一烷酸甲酯顺-4,7,10,13,16,19-二十二碳六烯酸甲酯二十二碳烯酸甲酯顺-13,16-二十二碳二烯酸甲酯二十二烷酸甲酯二十三烷酸甲酯二十四碳烯酸甲酯二十四烷酸甲酯 C17.)gamma-亚麻酸甲酯油酸甲酯亚油酸甲酯异油酸甲酯反亚油酸甲酯亚麻酸甲酯硬酯酸甲酯花生四烯酸甲酯 顺-5,8,11,14,17-二十碳五烯酸甲酯顺-8,11,14-二十碳三烯酸甲酯顺-11-二十碳二烯酸甲酯顺-11,14-二十碳二烯酸甲酯 顺-11,14,17-二十碳三烯酸甲酯花生酸甲酯 （样品名称中英对照）Luna 3 m,CN 100 100 x 4.6 mm00D-4254-E0A:;B:80:20 A/B(95:5)0.5 min,A/B(75:25)1 min5 mL/minUV 254 nm1.4.7.2.5.8.3.6.9.Str ata-X,60 mg/3 mL8B-5100-UBJ2 mL 2 mL 2 mL 2 mL ()2 mL 2 mL (1:1)50 L (20.0 g/mL)N2 40 C.200 L?St rat a Fl ori si l?Sepra1009080706050403020100%Recovery氨基甲酸酯农药的有效萃取样品纯化/推荐产品：硅镁散装填料可供实验室用来填充自己的小柱水性基质萃取/推荐产品:StrataX节省90溶剂！各种不同基质具有一致的回收率。非草隆灭草隆氯吡脲敌草隆环草隆H PLC分析条件：色谱柱：规格：货号：流动相：梯度：流速：温度：检测器：样品：正己烷二氯甲烷：甲醇保持然后保持室温扑草净扑灭津莠灭净莠去津虫螨威燕麦灵西维因丁噻隆敌草隆SPE方法：规格：货号：活化平衡：上样：冲洗：洗脱：定容：二氯甲烷乙腈水自来水加入分析物去离子水真空干燥2min乙腈/二氯甲烷加入利谷隆吹干水定容。?Zebr on ZB-FFAP30 meter x 0.25 mm x 0.25 m7HG-G009-11Split 100:1 250 C,1 LHelium 1 mL/min(constant flow)50 C to 250 C 6 C/min f or 3 minMSD 270 C1.10.19.2.11.20.3.12.21.4.13.22.5.14.23.6.15.?7.16.8.17.9.18.App I D 14899 Zebr on ZB-FFAP60 meter x 0.25 mm x 0.25 m7KG-G009-11Split 40:1 220 C,0.2 LHelium 2.4 mL/min(constant flow)200 C to 260 C 2 C/min f or 30 minFI D 250 C1.Methyl Myr istate 10.Methyl Linelaidate2.Methyl Myr istoleate 11.Methyl Linolenate 3.Methyl Palmitate 12.Methyl Ar achidate 4.Methyl Palmitelaidate 13.Methyl Gondonate 5.Methyl Palmitoleate 14.Methyl Behenate 6.Methyl Stear ate 15.Methyl Er ucate 7.Methyl Oleate 8.Methyl Elaidate 9.Methyl LinoleateApp I D 14856 Zebr on ZB-FFAP60 meter x 0.25 mm x 0.25 m7KG-G009-11Split 40:1 220 C,0.2 LHelium 2.4 mL/min(constant flow)200 C to 260 C 2 C/min f or 30 minFI D 250 C1.Myr istic Acid 10.Linoleic Acid2.Myr istoleic Acid 11.Linolenic Acid3.Palmitic Acid 12.Ar achidic Acid 4.Palmitelaidic Acid 13.Gondonic Acid(C15)5.Palmitoleic Acid 14.Behenic Acid(C17)6.Stear ic Acid 15.Er ucic Acid(C19)7.Elaidic Acid 8.Oleic Acid 9.Linolelaidic AcidApp I D 14858 Zebr on ZB-530 meter x 0.25 mm x 0.10 m7HG-G002-02Splitless 220 C,1 LHelium 1.8 mL/min(constant flow)110 C f or 0.2 min to 140 C 30 C/min to 230 C 10 C/min f or 6 min to 340 C 10 C/min f or 15.8 minFI D 340 CApp I D 163310213456789101112131415161718202122231951015202530min45 min303540251520101234567,89,10111213141510123548679101112131415152025303540min1.Squalene2.FFA C24:0 3.?-Tocopher ol 4.?-Tocomonoenol 5.Campesta-3,5-diene 6.?-Tocopher ol 7.Stigmasta-3,5,22-tr iene18202224min12345678910111213148.?-Tocomonoenol9.Stigmasta-3,5-diene10.Cholester ol11.?-Tocopher ol12.Campester ol13.Stigmaster ol 14.?-Sitoster ol香料维生素E和类固醇色谱柱:规 格:货 号:进 样:载 气:温度程序:检测器:样 品:色谱柱:规 格:货 号:进 样:载 气:温度程序:检测器:样 品:乙醛乙酸乙酯乙醇癸烷丁酸乙酯柠檬油精2,3-二甲基吡嗪(z)-3-己烯醇正十四烷 乙酸癸醛丙二醇 橙花醛 癸酸乙酯-松油醇戊酸正癸醇玫瑰油癸酸 橙花醇乙酸酯香叶醛香草醛蒽 Acetone Ethyl Acetate Ethanol Decane Ethyl Butyr ate Limonene 2,3-Dimethylpyr azine(z)-3-Hexenol Tetr adecane Acetic Acid Decanal Pr opylene Glycol Ethyl Decanoate Ner al?-Ter pineolNeryl Acetate Ger anialValer ic AcidDecanolNonanoic AcidDecanoic AcidVanillinAnthr acene角鲨烷-生育酚-生育酚 胆固醇-生育酚菜油甾醇-谷甾醇?不饱和脂肪酸甲酯不饱和脂肪酸色谱柱:规 格:货 号:进 样:载 气:温度程序:检测器:样 品:色谱柱:规 格:货 号:进 样:载 气:温度程序:检测器:样 品:App I D 16248TMS Zebr on MultiResidue-