化合物的标准热力学数据.doc

无机化合物的标准热力学数据Standard Thermodynamic Data of Inorganic Compounds下表中的标准热力学数据是以温度25.0（298.15K）处于标准状态的1摩尔纯物质为基准的。物质状态表示符号为：g气态，l液态，cr晶体。Hf 物质的标准生成焓（298.15K）,单位为kJ/mol； Gf 物质的标准生成Gibbs自由能（298.15K）,单位为kJ/mol； S 物质的标准熵（298.15K）,单位为J/（molK）； Cp 物质的常压热容（298.15K）,单位为J/(molK)。 序号(No.) 分子式(Molecular formula) 状态(State) Hf /(kJ/mol) Gf /(kJ/mol) S /J/(molK) Cp /J/(molK) 1 Ac cr 0.0 - 56.5 27.2 g 406.0 366.0 188.1 20.8 2 Ag cr 0.0 - 42.6 25.4 2 Ag g 284.9 246.0 173.0 20.8 3 AgBr cr -100.4 -96.9 107.1 52.4 4 AgBrO3 cr -10.5 71.3 151.9 - 5 AgCl cr -127.0 -109.8 96.3 50.8 6 AgClO3 cr -30.3 64.5 142.0 - 7 AgClO4 cr -31.1 - - - 8 AgCN cr 146.0 156.9 107.2 66.7 9 Ag2CO3 cr -505.8 -436.8 167.4 112.3 10 Ag2CrO4 cr -731.7 -641.8 217.6 142.3 11 AgF cr -204.6 - - - 12 AgI cr -61.8 -66.2 115.5 56.8 13 AgIO3 cr -171.1 -93.7 149.4 102.9 14 AgNO3 cr -124.4 -33.4 140.9 93.1 15 Ag2O cr -31.1 -11.2 121.3 65.9 16 Ag2S cr -32.6 -40.7 144.0 76.5 17 Ag2SO4 cr -715.9 -618.4 200.4 131.4 18 Al cr 0.0 - 28.3 24.4 g 330.0 289.4 164.6 21.4 19 AlBr3 cr -527.2 - - 101.7 g -425.1 - - - 20 AlCl3 cr -704.2 -628.8 110.7 91.8 g -583.2 - - - 21 AlF3 cr -1510.4 -1431.1 66.5 75.1 g -1204.6 -1188.2 277.1 62.6 22 AlI3 cr -313.8 -300.8 159.0 98.7 g -207.5 - - - 23 Al2O3 cr -1675.7 -1582.3 50.9 79.0 24 AlPO4 cr -1733.8 -1617.9 90.8 93.2 25 Al2S3 cr -724.0 - - - 26 Am cr 0.0 - - - 27 Ar g 0.0 - 154.8 20.8 28 As (灰,gray) cr 0.0 - 35.1 24.6 As(黄,yellow) cr 14.6 - - - As(黄,yellow) g 302.5 261.0 174.2 20.8 29 AsBr3 cr -197.5 - - - g -130.0 -159.0 363.9 79.2 30 AsCl3 l -305.0 -259.4 216.3 - g -261.5 -248.9 327.2 75.7 31 AsF3 l -821.3 -774.2 181.2 126.6 g -785.8 -770.8 289.1 65.6 32 AsH3 g 66.4 68.9 222.8 38.1 33 AsI3 cr -58.2 -59.4 213.1 105.8 g - - 388.3 80.6 34 As2O5 cr -924.9 -782.3 105.4 116.5 35 As2S3 cr -169.0 -168.6 163.6 116.3 36 At cr 0.0 - - - 37 Au cr 0.0 - 47.4 25.4 g 366.1 326.3 180.5 20.8 38 AuBr3 cr -53.3 - - - 39 AuCl3 cr -117.6 - - - 40 AuF3 cr -363.6 - - - 41 AuI cr 0.0 - - - 42 B cr 0.0 - 5.9 11.1 g 565.0 521.0 153.4 20.8 43 BBr3 l -239.7 -238.5 229.7 - g -205.6 -232.5 324.2 67.8 44 BCl3 l -427.2 -387.4 206.3 106.7 45 BF3 g -1136.0 -1119.4 254.4 50 46 BH3 g 100.0 - - - 47 B2H6 g 35.6 86.7 232.1 56.9 48 BI3 g 71.1 20.7 349.2 70.8 49 B2O3 cr -1273.5 -1194.3 54.0 - g -843.8 -832.0 279.8 66.9 50 B2S3 cr -240.6 - - - g 67.0 - - - 51 Ba cr 0.0 - 62.8 28.1 g 180.0 146.0 170.2 20.8 52 BaBr2 cr -757.3 -736.8 146.0 - 53 BaCl2 cr -858.6 -810.4 123.7 75.1 54 BaCO3 cr -1216.3 -1137.6 112.1 85.3 55 BaF2 cr -1207.1 -1156.8 96.4 71.2 56 BaH2 cr -178.7 - - - 57 BaI2 cr -602.1 - - - 58 Ba(NO2)2 cr -768.2 - - - 59 Ba(NO3)2 cr -992.1 -796.6 213.8 151.4 60 BaO cr -553.5 -525.1 70.4 47.8 61 Ba(OH)2 cr -944.7 - - - 62 BaS cr -460.0 -456.0 78.2 49.4 63 BaSO4 cr -1473.2 -1362.2 132.2 101.8 64 Be cr 0.0 - 9.5 16.4 g 324.0 286.6 136.3 20.8 65 BeBr2 cr -353.5 - - - 66 BeCl2 cr -490.4 -445.6 82.7 64.8 67 BeCO3 cr -1025.0 - - - 68 BeF2 cr -1026.8 -979.4 53.4 51.8 69 BeI2 cr -192.5 - - - 70 BeO cr -609.4 -580.1 13.8 - 71 Be(OH)2 cr -902.5 -815.0 51.9 - 72 BeS cr -234.3 - - - 73 BeSO4 cr -1205.2 -1093.8 77.9 85.7 74 Bi cr 0.0 - 56.7 25.5 g 207.1 168.2 187.0 20.8 75 BiCl3 cr -379.1 -315.0 177.0 105.0 g -265.7 -256.0 358.9 79.7 76 BiI3 cr - -175.3 - - 77 Bi(OH)3 cr -711.3 - - - 78 Bi2O3 cr -573.9 -493.7 151.5 113.5 79 Bi2S3 cr -143.1 -140.6 200.4 122.2 80 Bk cr 0.0 - - - 81 Br g 111.9 82.4 175.0 20.8 82 BrF3 l -300.8 -240.5 178.2 124.6 g -255.6 -229.4 292.5 66.6 83 BrF5 l -458.6 -351.8 225.1 - g -428.9 -350.6 320.2 99.6 84 BrO g 125.8 108.2 237.6 32.1 序号(No.) 分子式(Molecular formula) 状态(State) Hf /(kJ/mol) Gf /(kJ/mol) S /J/(molK) Cp /J/(molK) 85 CO g -110.5 -137.2 197.7 29.1 86 CO2 g -393.5 -394.4 213.8 37.1 87 Ca cr 0.0 - 41.6 25.9 g 177.8 144.0 154.9 20.8 88 CaBr2 cr -682.8 -663.6 130.0 - 89 CaCl2 cr -795.4 -748.8 108.4 72.9 90 CaCO3 (方解石, calcite) cr -1207.6 -1129.1 91.7 83.5 91 CaCO3 (霰石, aragonite) cr -1207.8 -1128.2 88.0 82.3 92 CaF2 cr -1228.0 -1175.6 68.5 67.0 93 CaH2 cr -181.5 -142.5 41.4 41.0 94 CaI2 cr -533.5 -528.9 142.0 - 95 Ca(NO3)2 cr -938.2 -742.8 193.2 149.4 96 CaO cr -634.9 -603.3 38.1 42.0 97 Ca(OH)2 cr -985.2 -897.5 83.4 87.5 98 CaS cr -482.4 -477.4 56.5 47.4 99 CaSO4 cr -1434.5 -1322.0 106.5 99.7 100 Cd cr 0.0 - 51.8 26.0 g 111.8 - 167.7 20.8 101 CdBr2 cr -316.2 -296.3 137.2 76.7 102 CdCl2 cr -391.5 -343.9 115.3 74.7 103 CdCO3 cr -750.6 -669.4 92.5 - 104 CdF2 cr -700.4 -647.7 77.4 - 105 CdI2 cr -203.3 -201.4 161.1 80.0 106 CdO cr -258.4 -228.7 54.8 43.4 107 Cd(OH)2 cr -560.7 -473.6 96.0 - 108 CdS cr -161.9 -156.5 64.9 - 109 CdSO4 cr -933.3 -822.7 123.0 99.6 110 Ce cr 0.0 - 72.0 26.9 g 423.0 385.0 191.8 23.1 111 CeCl3 cr -1053.5 -977.8 151.0 87.4 112 CeO2 cr -1088.7 -1024.6 62.3 61.6 113 CeS cr -459.4 -451.5 78.2 50.0 114 Cf cr 0.0 - - - 115 Cl g 121.3 105.3 165.2 21.8 116 Cl2 g 0.0 - 223.1 33.9 117 Cl2CO g -219.1 -204.9 283.5 57.7 118 ClF3 g -163.2 -123.0 281.6 63.9 l -189.5 - - - 119 ClO2 g 102.5 120.5 256.8 42.0 120 Cl2OS g -212.5 -198.3 309.8 66.5 l -245.6 - - 121.0 121 Cl2O2S g -364.0 -320.0 311.9 77.0 l -394.1 - - 134.0 122 Cm cr 0.0 - - - 123 Co cr 0.0 - 30.0 24.8 g 424.7 380.3 179.5 23.0 124 CoBr2 cr -220.9 - - 79.5 125 CoCl2 cr -312.5 -269.8 109.2 78.5 126 CoCO3 cr -713.0 - - - 127 CoF2 cr -692.0 -647.2 82.0 68.8 128 CoI2 cr -88.7 - - - 129 Co(NO3)2 cr -420.5 - - - 130 CoO cr -237.9 -214.2 53.0 55.2 131 Co(OH)2 cr -539.7 -454.3 79.0 - 132 CoS cr -82.8 - - - 133 CoSO4 cr -888.3 -782.3 118.0 - 134 Cr cr 0.0 - 23.8 23.4 g 396.6 351.8 174.5 20.8 135 CrBr2 cr -302.1 - - - 136 CrCl3 cr -556.5 -486.1 123.0 91.8 137 CrF3 cr -1159.0 -1088.0 93.9 78.7 138 CrI3 cr -205.0 - - - 139 Cr2O3 cr -1139.7 -1058.1 81.2 118.7 140 Cs cr 0.0 - 85.2 32.2 g 76.5 49.6 175.6 20.8 141 CsBr cr -405.8 -391.4 113.1 52.9 142 CsCl cr -443.0 -414.5 101.2 52.5 143 CsClO4 cr -443.1 -314.3 175.1 108.3 144 CsHCO3 cr -966.1 - - - 145 Cs2CO3 cr -1139.7 -1054.3 204.5 123.9 146 CsF cr -553.5 -525.5 92.8 51.1 147 CsHSO4 cr -1158.1 - - - 148 CsI cr -346.6 -340.6 123.1 52.8 149 CsNH2 cr -118.4 - - - 150 CsNO3 cr -506.0 -406.5 155.2 - 151 Cs2O2 cr -286.2 - - - 152 CsOH cr -417.2 - - - 153 Cs2O cr -345.8 -308.1 146.9 76.0 154 Cs2S cr -359.8 - - - 155 Cs2SO3 cr -1134.7 - - - 156 Cs2SO4 cr -1143.0 -1323.6 211.9 134.9 157 Cu cr 0.0 - 33.2 24.4 g 337.4 297.7 166.4 20.8 158 CuBr cr -104.6 -100.8 96.1 54.7 159 CuBr2 cr -141.8 - - - 160 CuCl cr -137.2 -119.9 86.2 48.5 161 CuCl2 cr -220.1 -175.7 108.1 71.9 162 CuCN cr 96.2 111.3 84.5 - 163 CuF2 cr -542.7 - - - 164 CuI cr -67.8 -69.5 96.7 54.1 165 Cu(NO3)2 cr -302.9 - - - 166 CuO cr -157.3 -129.7 42.6 42.3 167 Cu(OH)2 cr -449.8 - - - 168 CuS cr -53.1 -53.6 66.5 47.8 169 CuSO4 cr -771.4 -662.2 109.2 - 170 CuWO4 cr -1105.0 - - - 171 Cu2O cr -168.6 -146.0 93.1 63.6 172 Cu2S cr -79.5 -86.2 120.9 76.3 173 Dy cr 0.0 - 74.8 28.2 g 290.4 254.4 196.6 20.8 174 Dy2O3 cr -1863.1 -1771.5 149.8 116.3 175 Er cr 0.0 - 73.2 28.1 g 317.1 280.7 195.6 20.8 176 Er2O3 cr -1897.9 -1808.7 155.6 108.5 177 Eu cr 0.0 - 77.8 27.7 g 175.3 142.2 188.8 20.8 178 Eu2O3 cr -1651.4 -1556.8 146.0 122.2 179 F g 79.4 62.3 158.8 22.7 180 F2 g 0.0 - 202.8 31.3 181 F2CO g -639.8 - - - 182 Fe cr 0.0 - 27.3 25.1 g 416.3 370.7 180.5 25.7 183 FeBr2 cr -249.8 -238.1 140.6 - 184 FeBr3 cr -268.2 - - - 185 FeCl2 cr -341.8 -302.3 118.0 76.7 186 FeCl3 cr -399.5 -334.0 142.3 96.7 187 FeCO3 cr -740.6 -666.7 92.9 82.1 188 FeCr2O4 cr -1444.7 -1343.8 146.0 133.6 189 FeF2 cr -711.3 -668.6 87.0 68.1 190 FeI2 cr -113.0 - - - 191 FeI3 g 71.0 - - - 192 FeMoO4 cr -1075.0 -975.0 129.3 118.5 193 FeO cr -272.0 - - - 194 Fe2O3 cr -824.2 -742.2 87.4 103.9 195 Fe3O4 cr -1118.4 -1015.4 146.4 143.4 196 FeS cr -100.0 -100.4 60.3 50.5 197 FeSO4 cr -928.4 -820.8 107.5 100.6 198 FeWO4 cr -1155.0 -1054.0 131.8 114.6 199 Fm cr 0.0 - - - 200 Fr cr 0.0 - 95.4 - 201 Ga cr 0.0 - 40.9 25.9 g 277.0 238.9 169.1 25.4 l 5.6 - - - 202 GaBr3 cr -386.6 -359.8 180.0 - 203 GaCl3 cr -524.7 -454.8 142.0 - 204 GaF3 cr -1163.0 -1085.3 84.0 - 205 Ga2O3 cr -1089.1 -998.3 85.0 92.1 206 Ga(OH)3 cr -964.4 -831.3 100.0 - 207 Gd cr 0.0 - 68.1 37.0 g 397.5 359.8 194.3 27.5 208 Gd2O3 cr -1819.6 - - 106.7 209 Ge cr 0.0 - 31.1 23.3 g 372.0 331.2 167.9 30.7 210 GeBr4 g -300.0 -318.0 396.2 101.8 l -347.7 -331.4 280.7 - 211 GeCl4 g -495.8 -457.3 347.7 96.1 l -531.8 -462.7 245.6 - 212 GeF4 g -1190.2 -1150.0 301.9 - 213 GeI4 cr -141.8 -144.3 271.1 - g -56.9 -106.3 428.9 104.1 214 H g 218.0 203.3 114.7 20.8 215 H2 g 0.0 - 130.7 28.8 216 H3AsO4 cr -906.3 - - - 217 H3BO3 cr -1094.3 -968.9 88.8 81.4 g -994.1 - - - 218 HBr g -36.3 -53.4 198.7 29.1 219 HCl g -92.3 -95.3 186.9 29.1 220 HClO g -78.7 -66.1 236.7 37.2 221 HClO4 l -40.6 - - - 222 HF l -299.8 - - - g -273.3 -275.4 173.8 - 223 HI g 26.5 1.7 206.6 29.2 224 HIO3 cr -230.1 - - - 225 HNO2 g -79.5 -46.0 254.1 45.6 226 HNO3 l -174.1 -80.7 155.6 109.9 g -135.1 -74.7 266.4 53.4 227 H2O l -285.8 -237.1 70.0 75.3 g -241.8 -228.6 188.8 33.6 228 H2O2 l -187.8 -120.4 109.6 89.1 g -136.3 -105.6 232.7 43.1 229 H3P g 5.4 13.4 210.2 37.1 230 HPO3 cr -948.5 - - - 231 H3PO2 cr -604.6 - - - l -595.4 - - - 232 H3PO3 cr -964.4 - - - 233 H3PO4 cr -1284.4 -1124.3 110.5 106.1 l -1271.7 -1123.6 150.8 145.0 234 H4P2P7 cr -2241.0 - - - l -2231.7 - - - 235 H2S g -20.6 -33.4 205.8 34.2 236 H2SO4 l -814.0 -690.0 156.9 138.9 237 H3Sb g 145.1 147.8 232.8 41.1 238 H2Se g 29.7 15.9 219.0 34.7 239 H2SeO4 cr -530.1 - - - 240 H2SiO3 cr -1188.7 -1092.4 134.0 - 241 H4SiO4 cr -1481.1 -1332.9 192.0 - 242 H2Te g 99.6 - - - 243 He g 0.0 - 126.2 20.8 244 Hf cr 0.0 - 43.6 25.7 g 619.2 576.5 186.9 20.8 245 HfCl4 cr -990.4 -901.3 190.8 120.5 g -884.5 - - - 246 HfF4 cr -1930.5 -1830.4 113.0 - g -1669.8 - - - 247 HfO2 cr -1144.7 -1088.2 59.3 60.3 248 Hg l 0.0 - 75.9 28.0 g 61.4 31.8 175.0 20.8 249 HgBr2 cr -170.7 -153.1 172.0 - 250 Hg2Br2 cr -206.9 -181.1 218.0 - 251 HgCl2 cr -224.3 -178.6 146.0 - 252 Hg2Cl2 cr -265.4 -210.7 191.6 - 253 Hg2CO3 cr -553.5 -468.1 180.0 - 254 HgI2 cr -105.4 -101.7 180.0 - 255 Hg2I2 cr -121.3 -111.0 233.5 - 256 HgO cr -90.8 -58.5 70.3 44.1 257 HgS cr -58.2 -50.6 82.4 48.4 258 HgSO4 cr -707.5 - - - 259 Hg2SO4 cr -743.1 -625.8 200.7 132.0 260 Ho cr 0.0 - 75.3 27.2 g 300.8 264.8 195.6 20.8 261 I g 106.8 70.2 180.8 20.8 262 I2 cr 0.0 - 116.1 54.4 g 62.4 19.3 260.7 36.9 263 In cr 0.0 - 57.8 26.7 g 243.3 208.7 173.8 20.8 264 Ir cr 0.0 - 35.5 25.1 g 665.3 617.9 193.6 20.8 265 K cr 0.0 - 64.7 29.6 g 89.0 60.5 160.3 20.8 266 KAlH4 cr -183.7 - - - 267 KBH4 cr -227.4 -160.3 106.3 96.1 268 KBr cr -393.8 -380.7 95.9 52.3 269 KBrO3 cr -360.