总有机碳分析仪 TOC-1仪器手册.pdf

C391-E079GTotal Organic Carbon AnalyzerTOC-L Shimadzu Corporation, Research Use Only.Not for use in diagnostic procedures.This publication may contain references to products that are not available in your country.Please contact us to check the availability of these products in your country.Company names,products/service names and logos used in this publication are trademarks and trade names of Shimadzu Corporation,its subsidiaries or its affiliates,whether or not they are used with trademark symbol“TM”or“”.Third-party trademarks and trade names may be used in this publication to refer to either the entities or their products/services,whether or not they are used with trademark symbol“TM”or“”.Shimadzu disclaims any proprietary interest in trademarks and trade names other than its own.The contents of this publication are provided to you“as is”without warranty of any kind,and are subject to change without notice.Shimadzu does not assume any responsibility or liability for any damage,whether direct or indirect,relating to the use of this publication.First Edition:January 2011,Printed in Japan 3655-08903-20AIKGlobal Standard forTOC AnalyzersThe Utility of Shimadzu TOC AnalyzersFeaturesFlow Line DiagramsPC-Controlled ModelsStandalone ModelsSpace-Saving and Energy-Saving Design,Other Functions and FeaturesASI-L Autosampler and OCT-L 8-Port SamplerTNM-L Total Nitrogen Unit and SSM-5000A Solid Sample Combustion UnitCompatibility of Options and Special Accessories SpecificationsExternal Dimensions DiagramsCombustion Catalytic Oxidation/NDIR Detection Method TOC Analyzerswith a User-Friendly DesignA Full Range of Models and OptionsProvide Total Solutions to Suit Your ApplicationTOC-V series,the worlds top seller,has evolved.Easy-to-operate keyboard and easy-to-read TFT color LCD screen(standalone model)Output of measurement data to USB memory sticks or conventional PC printer(standalone model)A wealth of options,including sea water sample measurement and compatibility with small samples volumesSpace-saving and energy-saving designSelect from PC models,convenient for processing measurement data,and user-friendly standalone modelsAdd options to measure everything from solid samples to gas samplesTN measurement is also possible with the addition of the TN unitGlobal Standard forTOC AnalyzersThe Utility of Shimadzu TOC AnalyzersFeaturesFlow Line DiagramsPC-Controlled ModelsStandalone ModelsSpace-Saving and Energy-Saving Design,Other Functions and FeaturesASI-L Autosampler and OCT-L 8-Port SamplerTNM-L Total Nitrogen Unit and SSM-5000A Solid Sample Combustion UnitCompatibility of Options and Special Accessories SpecificationsExternal Dimensions DiagramsCombustion Catalytic Oxidation/NDIR Detection Method TOC Analyzerswith a User-Friendly DesignA Full Range of Models and OptionsProvide Total Solutions to Suit Your ApplicationTOC-V series,the worlds top seller,has evolved.Easy-to-operate keyboard and easy-to-read TFT color LCD screen(standalone model)Output of measurement data to USB memory sticks or conventional PC printer(standalone model)A wealth of options,including sea water sample measurement and compatibility with small samples volumesSpace-saving and energy-saving designSelect from PC models,convenient for processing measurement data,and user-friendly standalone modelsAdd options to measure everything from solid samples to gas samplesTN measurement is also possible with the addition of the TN unitS h i m a d z u T O C A n a l y z e rExample of TC(Total Carbon)Measurement of Poultry Manure CompostInvestigations andExperimental ResearchGlobal environment and eutrophicationRiver water,lakes and marshes,underground water,sea water,soil,sludge,sediments,etc.Biodegradable plastics and cement secondary products Process ControlEffluent treatment process controlProcesses(Plating,etching,washing,water-based cutting)Ultrapure water recycling andre-purification processesAnalysis instrument:TOC-LcsH+SSM-5000A(980 C electric furnace)Measurement method:direct TC measurement of commercially available poultry manure compost,pulverized with a mortarMeasurement results:TC=27.26%C(C.V.=0.57%)Example of TN Measurement of Ammonium Sulfate Aqueous SolutionAnalysis instrument:TOC-LCPH+TNM-LMeasurement method:TN measurement of Ammonium Sulfate Aqueous Solution,prepared nitrogen concentration=10 mg/LMeasurement results:TN=9.91 mg/L(C.V.=0.30%)Example of TOC Measurement of Nickel Plating SolutionAnalysis instrument:TOC-LCPHMeasurement method:TOC measurement of Nickel Plating Solution,thousand fold dilution with pure water(TOC measurement(NPOC measurement)with sample acidification and sparging)Measurement results:TOC=12.80 mg/L(C.V.=0.22%)(before dilution TOC=1.280%)Quality ControlDrinking waterAluminum foilElectronic componentsWater supply equipmentRaw materials(Sulfuric acid,aqueous ammonia,hydrogen peroxide solution,etc.)U t i l i z e d i n a V a r i e t y o f F i e l d s54S h i m a d z u T O C A n a l y z e rExample of TC(Total Carbon)Measurement of Poultry Manure CompostWaterQuality ControlTap water(Drinking water,raw water)Ultrapure water(Ultrapure water used in semiconductor manufacturing,Liquid Crystal manufacturing,pharmaceutical manufacturing,and nuclear power generation,as well as used ultrapure water)Effluent(Industrial effluent,water treatment effluent,etc.)Pool water,spa water,bath water,boiler water,water from industrial processesExample of TOC Measurement of Purified WaterAnalysis instrument:TOC-LCPHMeasurement method:TOC measurement(NPOC measurement)with sample acidification and spargingMeasurement results:TOC=63.3 g/L(C.V.=2.05%)PharmaceuticalManufacturingPharmaceutical water controlEvaluation of cleaning effectiveness(Cleaning validation)Example of TOC Measurement of Tap WaterAnalysis instrument:TOC-LCPHMeasurement method:TOC measurement(NPOC measurement)with sample acidification and spargingMeasurement results:TOC=932 g/L(C.V.=0.72%)U t i l i z e d i n a V a r i e t y o f F i e l d s5The most important feature of a TOC analyzer is its ability to efficiently oxidize not only easily decomposed,low molecular weight organic compounds,but also hard-to-decompose insoluble and macromolecular organic compounds.The 680 C combustion catalytic oxidation method,developed by Shimadzu and now used worldwide,can efficiently analyze all organic compounds.Extremely wide measurement range from 4 g/L to 30,000 mg/L,applicable to everything from ultrapure water to highly contaminated water(TOC-LCSH/CPH)Capable of TC,IC,TOC(=TC-IC),and NPOC measurement;options enable POC(volatile organic carbon),TOC via POC+NPOC,and even TN(total nitrogen)measurements The blank check function evaluates system blanks by measuring ultrapure water processed automatically within the instrument The automatic dilution function enables measurements up to 30,000 mg/L Reliable sample injection system Automatic sample acidification and sparging The automatic dilution function reduces sample salinity,acidity,and alkalinity,significantly extending the period of use of catalysts and combustion tubes(The period of use depends on the sample and measurement conditions.)Stat or priority samples can be added at anytime to the analysis schedule without interrupting operation even when an autosampler is used Select from 4 models to suit your application LCD and keyboard-equipped standalone models,and PC-controlled models High-sensitivity model with a detection limit of 4 g/L,suitable for a variety of applications including pure water measurements,as well as a standard model designed with cost/performance in mind Suitable for aqueous samples,as well as gas and solid samples(with manual injection kit and solid sample combustion unit)Compressed air can be used as the carrier gas(with carrier gas purification kit)Compatible with small sample volumes(with optional kit)Sea water samples can be continuously measured with minimal maintenance(with combustion tubes for high salt samples)Measurement can be performed with good repeatability even with samples containing highly sedimentary suspended organic matters(when high suspension kit is added)The effect depends on sample and measurement conditionsMultifunction Sample Pretreatment Injection SystemTOC-LCSH/CSN Standalone ModelTOC-LCPH/CPN PC-Controlled ModelFeaturesShimadzu 680 C Combustion Catalytic Oxidation/NDIR Detection MethodMeasurement System Combining Experience and Reliability6TOC-LCPH High-Sensitivity ModelTOC-LCSN Standard ModelPrinterNon-dispersive infrareddetector(NDIR)Carrier gasinletElectronicgas flowratecontrollerCarrier gasTC furnaceIC reaction vesselIC reaction reagentUltrapure water trap for blank checkTC sample injection port,slide typeIC sample injection port,slide typeSparging gasDilution waterAcidASI-L autosamplerSampleDehumidifier/gaspretreatment unitDataprocessorUSBPersonal computer(Not included inthe TOC analyzercomponents.)DrainMultifunction sample pretreatment/injection systemTC combustiontubeDisplayKeyboardDataprocessorPrinterUSB memory stickLAN(option)Non-dispersiveinfrared detector(NDIR)Carrier gasinletElectronicgas flowratecontrollerCarrier gasTC furnaceTC combustion tubeTC sample injection port,slide typeSparging gasDilution waterAcidASI-L autosamplerSampleDehumidifier/gaspretreatment unitDrainMultifunction sample pretreatment/injection systemFlow Line Diagrams7User-friendly display of instrument status using text and colorUser-friendly display of the name,ID,and measurement results for selected samples,all in specific columnsIcons and function names shown on large buttonsClassification by typeList of files used by typeCan be sorted by file name and date createdFile details are displayed with tooltipInsert samples by dragging and dropping measurement conditions filesOperations are accessed by right-clicking on the tableDrag the mouse over cells to batch-enter identical character strings,and sequential IDs and vial numbersTOC-LCPH/CPN PC-Controlled Model Enabling Simple,Intuitive OperationSoftware Features Intuitive Operability and a Wealth of Functions8 Addition of samples during continuous measurementSamples can be inserted during continuous measurement by an autosampler.Creation of schedule filesThe measurement of multiple samples,configured by measurement condition and vial number,can be registered as a schedule file.This provides support for routine measurements.Accuracy control functionFor accuracy control,samples can be inserted into a measurement schedule.If the measurement results fall outside of the configured range,re-measurement and other procedures can be performed automatically.Selection of samples for report outputIn addition to outputting batch reports on all samples in a table,reports can also be output for specified samples.Runtime report outputSequential reports can be output automatically,each time a sample measurement is completed.21CFR Part11 compatibilityThe system provides user authentication with ID and password,and can log the operational history.In addition,in combination with Shimadzu CLASS-Agent software(sold separately),it is possible to consolidate measurement results in a database.Recommended PC Specifications Input/output of text filesMeasurement results can be output as text files,which can be loaded by Excel and other applications.In addition,text files can be loaded as measurement schedules.USB connectivityA USB interface is used for connecting the PC and TOC analyzer.OSCPUMemoryOtherWindows 7 Professional(32/64 bit version)Windows 10 Professional(32/64 bit version)3.0 GHz min.4 GB min.DVD drive,USB terminalsTOC-LCPH/CPN PC-Controlled Model Convenient Functionality Supports Your Analysis Work9 Color screen and keyboardEasy-to-read TFT(Thin Film Transistor)color LCD screen and keyboard designed with simplicity and user-friendliness in mind.Data output from LAN port(optional)A LAN terminal is provided on the back of the instrument,enabling output of measurement data via LAN.Data output to USB memory stickMeasurement results can be output in CSV format to a USB memory stick.Use a general-purpose USB printerTo use a PC printer or portable thermal printer,simply connect it to the USB terminal on the back of the instrument.(Contact your Shimadzu representative for a list of suitable printers.)Standalone Model with a TFT Color LCD Screen Providing Outstanding VisibilityKeyboardTOC-LCSH/CSN Standalone Model Color Screen10The width of the instrument is 20%less in comparison with conventional Shimadzu models.This enables more effective use of laboratory space.The instrument width is unchanged even when the TN unit is added.This product conforms to Shimadzus Eco-labeled designation.Energy consumption has been reduced by 36%(100 V)and 43%(200 V)in comparison with conventional Shimadzu models.(Assuming 8 hours operation/day 5 days/week)Automatic exclusion of anomalous values and re-calculation at repeated measurementsThe mean value,standard deviation,and coefficient of variation are displayed and printed for repeated analyses.Anomalous values can be automatically eliminated and re-calculated.Automatic sleep/restartAfter operations are completed and a certain amount of time has elapsed,the system automatically enters sleep mode.It can be set to automatically restart at a certain time.*PC software is included as standard with the standalone models.Adding a PC and communication cable allows the operator to use the software on standalone models.Automatic setting of optimal measurement conditionsWhen the standard solution concentration for creating the calibration curve is set,the optimal measurement conditions are displayed.Detailed calibration curve information can easily be referenced when setting the measurement conditions.Automatic selection of the optimal calibration curveUp to three calibration curves can be set for sample measurements.From these,the optimal calibration curve is selected for the sample.Automatic changing of conditions and re-measurement of out-of-range samplesIf the sample peak exceeds the calibration curve range,measurement conditions,such as dilution rate and injection volume,are automatically changed,and the measurement is repeated.340 mm440 mm(Conventional model)160 mmSpace-Saving and Energy-Saving DesignOther Functions and FeaturesCommon to PC-Controlled Model and Standalone ModelSpace-Saving DesignEnergy-Saving DesignTN unit11ASI-L Autosampler Even More Functionality and Convenience,Enabling Samples to Be Added During Continuous MeasurementOCT-L 8-Port SamplerThe Bridge to Ultra-Simplified Automatic MeasurementOptions for Configuring an Automatic Measurement SystemWealth of Options Provides Greater FunctionalityTNM-L TN(Total Nitrogen)UnitPerform Simultaneous TOC and TN MeasurementsSSM-5000A Solid Sample Combustion UnitCapable of TOC Measurements in Solid Samples【GMP Cleaning Validation Using the Swab Method】Features Select from three vial types with different capacities to suit your application.Combination of vial capacity and number of vials 9 mL vials 93 24 mL via