AMMONIUM MOLYBDATE(钼酸铵).doc

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<!DOCTYPE HTML PUBLIC "-//W3C//DTD HTML 4.0 Transitional//EN"> The MSDS format adheres to U.S. standards and regulatory requirements and may not meet regulatory requirements in other countries. MSDS规格遵照美国标准及规范要求，但并不一定符合其他国家的规范要求。 This information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience are gained. 此资料依据被认为是可靠的技术资料汇编而成，但可随新的知识及经验的增长而随时修订。 AMMONIUM MOLYBDATE 钼酸铵 CF0236 Revised 16-OCT-1999 Printed 17-MAY-2000 CF0236 1999年10月16日修订 2000年5月17日印制 CHEMICAL PRODUCT/COMPANY IDENTIFICATION 化学品/公司识别 Material Identification 产品识别 Corporate MSDS Number : DU006246 DSPC MSDS No. : A13 CAS Number : 13106-76-8 Formula : N2H8MO04 Molecular Weight : 196.04 协会MSDS编号 :DU006246 CAS号 :13106-76-8 分子式 :N2H8MO04 分子量 :196.04 Tradenames and Synonyms 商品名及别名 AMMONIUM PARAMOLYBDATE DIAMMONIUM MOLYBDATE 仲钼酸铵钼酸二铵 Company Identification 公司识别 MANUFACTURER/DISTRIBUTOR BAKER; FISHER; KODAK; EM SCIENCE; ACROS ORGANICS 生产商/分销商 BAKER公司；FISHER公司；KODAK；EM SCIENCE公司； ACROS公司；ORGANICS公司； PHONE NUMBERS Transport Emergency : CHEMTREC: 1-800-424-9300 Medical Emergency : 1-800-441-3637 电话号码运输应急：CHEMTREC: 1-800-424-9300 医疗应急：1-800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS 组成/组份资料 Components 成份 Material CAS Number % AMMONIUM MOLYBDATE 13106-76-8 99-100 OR AMMONIUM MOLYBDATE, TETRAHYDRATE 12027-67-7 99-100 OR AMMONIUM PARA-MOLYBDATE TETRAHYDRATE 12054-85-2 99-100 材料 CAS号 % 钼酸铵 13106-76-8 99-100 或钼酸铵·四水合物 12027-67-7 99-100 或：仲钼酸铵四水合物 12054-85-2 99-100 HAZARDS IDENTIFICATION 危险识别 Potential Health Effects 对健康可能产生的影响 Poisoning may affect the blood, liver, and kidneys. At increased risk from exposure: Persons with pre-existing respiratory, kidney, or blood disorders or gout. 中毒可能会影响血液、肝脏及肾脏、接触后危险性增大的有：原先患有呼吸、肾脏、或血液不正常或痛风的病人。 May be excreted in breast milk. The body levels of copper, sulfur, and zinc may have an effect on the toxicity. (Based on information on soluble molybdenum compounds). 可在乳液中排泄出应分开体内铜、硫及锌的含量高低会对其毒性产生影响。（根据可溶性钼化合物的资料） INHALATION 吸入 May cause irritation of the respiratory tract. 可引起上呼吸道刺激 SKIN CONTACT 皮肤接触 May cause irritation. Chronic: Among chemists handling solutions of molubdenum and tungsten, there was a high incidence of gout. 可引起刺激、漫性：在接触到钼及钨的溶液的化工人员中，有较高的痛风发生率。 EYE CONTACT 眼接触 May cause irritation. 可引起刺激 INGESTION 摄入 May be harmful if swallowed. 若吞咽下则会是有害的。 Carcinogenicity Information 致癌性资料 None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. 被IARC, NTP, OSHA或ACGIH列为致癌的，在此物质的成份中没有一个基浓度是等于或大于0.1%的。 FIRST AID MEASURES 急救措施 First Aid 急救 INHALATION 吸入 If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. 若已吸入则移至新鲜空气处，若已停止呼吸则施以人工呼吸，若呼吸困难则输以氧气，请来医生。 SKIN CONTACT 皮肤接触 Flush skin with water after contact. Wash contaminated clothing before reuse. 接触后用水冲洗，在衣服再次穿用前要清洗干净。 EYE CONTACT 眼接触 In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. 万一接触到后，立即用大量的水至少冲洗15分钟，请来医生。 INGESTION 摄入 If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. 若已吞咽下去，不要设法呕吐，立即喝二大杯水，千万别给已失去知觉的人从嘴中喂食任何东西，请来医生。 Notes to Physicians 提示医生 Activated charcoal mixture may be administered. To prepare activated charcoal mixture, suspend 50 grams activated charcoal in 400 mL water and mix thoroughly. Administer 5 mL/kg, or 350 mL for an average adult. 可服用活性碳混合物，制备活性碳混合物方法为：将50克活性碳悬浮于400 mL水中并混合均匀，服用量为5 mL/kg或对一般成年人350 mL。 FIRE FIGHTING MEASURES 消防措施 Flammable Properties 易燃性质 Not a fire or explosion hazard. 无着火或爆炸危险 Hazardous gases/vapors produced in fire are ammonia. 着火时产生的有害气体/蒸气为氨 Extinguishing Media 灭火介质 Use media appropriate for surrounding material. 采用适合于周边物质的灭火介质。 Fire Fighting Instructions 消防须知 Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus. Wear full protective equipment. 将人员撤至着火的上风处，戴上自背式呼吸器，穿戴齐全防护设备。 Move containers from fire area if it can be done without risk. Closed containers exposed to heat may explode. 若可以做到无危险的话，将容器搬离着火区域，密封的容器受热后，可能会发生爆炸。 ACCIDENTAL RELEASE MEASURES 事故消除措施 Safeguards (Personnel) 防护（人员） NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. 注：在清理干净之前，参阅“消防措施”及“处理（人员）”有关章节，在清理时，使用适当的“人员防护设施”。 Accidental Release Measures 事故消除措施 With clean shovel, carefully place material into clean, dry container and cover. Remove from area. Flush spill area with water. 用干净的铲子，小心将物质铲入洗净、干燥的容器中并盖上盖子并搬走，用水冲洗洒出区域。 HANDLING AND STORAGE 运输及贮藏 Handling (Personnel) 运输（人员） Avoid breathing dust. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Wash clothing after use. 避免吸入其尘粒，避免其与眼、皮肤及衣服接触，运输后要彻底洗净，穿过的衣服要洗净。 Handling (Physical Aspects) 运输（周边环境） Avoid dust generation. Keep away from heat, sparks and flames. 避免产生尘粒，避免靠近热、火花及火焰。 Storage 贮藏 Do not mix with strong acids. Store in a well ventilated place. Keep container tightly closed. 不要与强酸混合堆放，贮藏于通风良好之处，保持容器密闭。 Store in a dry place. 贮藏于干燥之处。 EXPOSURE CONTROLS/PERSONAL PROTECTION 接触控制/人员防护 Engineering Controls 工程控制 Keep container tightly closed. Use sufficient ventilation to keep employee exposure below recommended limits. 保持容器密闭，通风良好，使人员接触到的是低于推荐的极限。 Personal Protective Equipment 人员防护设施 EYE/FACE PROTECTION 眼/脸防护 Wear coverall chemical splash goggles when the possibility exists for eye or face contact from airborne material. 当眼及脸当有可能接触到空气中的该物质时，要戴上封闭式化学防溅护目镜。 RESPIRATOR 呼吸器 A NIOSH approved air purifying respirator with particulate cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a NIOSH approved positive pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. 在空气中浓度可能超过接触极限的某些场合，允许使用为NIOSH批准的带活性碳过滤器或滤毒筒的空气净化呼吸器，但空气净化呼吸器所提供的防护是有限的，若有下列可能则要用NIOSH批准的正压供气呼吸器：无法控制的泄漏，接触浓度未知，或其它的空气净化呼吸器不能提供足够保护任何场合。 PROTECTIVE CLOTHING 防护服装 Wear impervious clothing, such as gloves, apron, boots, or whole bodysuit as appropriate. 穿上不透水的服装，例如手套、围裙、靴子、或连衣裤。 Recommended glove material: No vendor recommendation on material of construction for protective clothing. 推荐手套材料：对防护服装的材质，卖主并未推荐。 # Exposure Guidelines # 接触准则 Exposure Limits AMMONIUM MOLYBDATE PEL (OSHA) : Particulates (Not Otherwise Regulated) 15 mg/m3, 8 Hr. TWA, total dust 5 mg/m3, 8 Hr. TWA, respirable dust 接触最大浓度钼酸铵 PEL (OSHA) : 颗粒（没有另外规定） 15 mg/m3, 8 小时暂时工作区，总尘量 5 mg/m3, 8小时工作区，可吸入尘量 Other Applicable Exposure Limits 其它适用接触最大浓度 AMMONIUM MOLYBDATE, TETRAHYDRATE PEL (OSHA) : 5 mg/m3, and soluble compounds, as Mo Insoluble compounds: 15 mg/m3, Total Dust as 8 Hr TWAs TLV (ACGIH) : 10 mg/m3, insoluble compounds, as Mo 5 mg/m3, soluble compounds as Mo 8 Hr TWAs Notice of Intended Changes (1999) Elemental/Metal and insoluble compounds 10 mg/m3 (Inhalable fraction) 3 mg/m3 (Respirable fraction) 0.5 mg/m3 (Soluble compounds), A3 AEL * (DuPont) : None Established 钼酸铵，如水合物 PEL (OSHA) : 5 mg/m3,及可溶性化合物，钼的不溶性化合物： 15 mg/m3, 总尘量8小时暂时工作区 TLV (ACGIH) : 10 mg/m3, 不溶性化合物，钼5 mg/m3, 可溶性化合物钼8小时暂时工作区变更通知（1999）元素/金属及不溶化合物 10 mg/m3 (可吸入部分) 3 mg/m3 (可呼吸部分) 0.5 mg/m3 (可溶化合物), A3 AEL * (杜邦 ) : 尚未建立 * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. *AEL为杜邦公司可接受的接触最大浓度，若政府规定的职业接触最大浓度低于AEL，则采用最大浓度。 PHYSICAL AND CHEMICAL PROPERTIES 物理及化学性能 Physical Data 物理数据 Boiling Point : 190 C (374 F) Decomposes Vapor Density : 2.5 (Air = 1) Melting Point : 90 C (194 F) Hydrates (loses water) 190 C (374 F) @ 760 mm/Hg Solubility in Water : >10 WT% (Appreciable) ~43% (cold) pH : 5.0-5.5 @ 5% solution Odor : Odorless Form : Solid (crystals) Color : White to yellow-green Specific Gravity : 2.2-2.5 (Water=1) 沸点 : 190℃(374℉) 分解蒸气密度：2.5 (空气 = 1) 溶点：90℃ (194℉) 颗粒 (没有另外规定) 190 ℃(374℉) @ 760 mm/Hg 水中溶解度：>10 重量% (明显) ~43% (冷) PH ：5.0-5.5 @ 5%溶液气味：无气味形态：固态（结晶）颜色：白至黄绿色比重：2.2-2.5 (水=1) Solvent solubility: Soluble in acids, alkalis, ammonium chloride solution. Insoluble in alcohol. 溶剂溶解性：溶于酸、碱及铵盐及氯化物溶液中，不溶于酒精。 STABILITY AND REACTIVITY 稳定性及反应性 Chemical Stability 化学稳定性 Stable at normal temperatures and storage conditions. 在常温贮藏条件下稳定 Incompatibility with Other Materials 与其它物质不相容性 Incompatible with strong oxidizing agents, strong acids. 与强氧化剂，强酸不相容。 Decomposition 分解性 Decomposes with heat. 遇热分解 Hazardous gases/vapors produced are ammonia and oxides of nitrogen. 产生的危害气体/蒸气为氨及氮氧化物。 Polymerization 聚合性 Polymerization will not occur. 不会发生聚合 TOXICOLOGICAL INFORMATION 毒物学资料 Animal Data 动物数据 Ammonium Molybdate 动物数据 Oral LD50 (Rats) 3883 mg/kg IHL LC50 (Rats) >1930 mg/m3/4h 口服LD50（白鼠）3883 mg/kg IHL LC50 (白鼠) >1930 mg/m3/4h Ammonium Molybdate Tetrahydrate 钼酸铵四水合物 Oral LD50 (Rats) 333 mg/kg 口服LD50(白鼠) 333 mg/kg Ingestion: In animals, large doses have caused dyspnea, anorexia, colic, trembling, and incoordination. Listlessness, anemia, and deformities of the forelegs were reported. There is a correlation between molybdenum concentration in food and incidences of elevated xanthine oxidase activity, bout and uricemia. In animals, molybdenum may interfere with copper metabolism. 摄入：在动物身上，大剂量要引起呼吸困难、疼痛、发抖及共济失调，还有报导有：疲倦、贫血及前腿畸形，食物中钼的高的黄嘌呤氧化酶活性之间有相互关系，在动物身上，钼可能会干扰铜的新陈代谢。 DISPOSAL CONSIDERATIONS 废弃要点 Waste Disposal 废物处理 Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Do not flush to surface water or sanitary sewer system. 处理、贮藏、运输及废弃须符合现行联邦、州/省及地方法规，不要冲洗入地面水及污水系统中。 TRANSPORTATION INFORMATION 运输资料 Shipping Information 运输资料 DOT Proper Shipping Name : NON-REGULATED DOT 正确运输名称：没有规定 REGULATORY INFORMATION 法规资料 U.S. Federal Regulations 美国联邦法规 TSCA Inventory Status : Reported/Included. TSCA库存状况：已报导/已包括 TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 第III条危险分类第311，312节 Acute : Yes Chronic : Yes Fire : No Reactivity : No Pressure : No 急性：是慢性：是着火：否反应性：否压力：无 OTHER INFORMATION 其它资料 NFPA, NPCA-HMIS NFPA, NPCA-HMIS NPCA-HMIS Rating Health : 1 (Chronic Health Effects) Flammability : 0 Reactivity : 0 NPCA-HMIS等级健康：1（慢性健康影响）易燃性：0 反应性：0 Personal Protection rating to be supplied by user depending on use conditions. 个人防护等级视使用条件由用户提供。 Additional Information 附加资料 Technical data, based on J. T. Baker MSDS dated 1/4/94, Fisher Scientific MSDS dated 10/12/92, Eastman Kodak Co. MSDS dated 11/18/86, E. M. Science MSDS dated 2/24/94; Acros Organics MSDS dated 1/12/96. 技术数据根据1994年4月1日的J. T. Baker公司MSDS，1992年12月10日的Fisher科学公司MSDS，1986年11月18日的Eastman Kodak公司MSDS，1994年2月24日的E. M.公司MSDS，1996年12月1

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