一些污染物沉降参数参考值.docx

一些污染物沉降参数参考值

来源:
ANL/ER/TR-01/003，DOE/xx-nnnn。《Deposition Parameterizations for the Industrial Source Complex (ISC3) Model》，by M. L. Wesely, P. V. Doskey, and J. D. Shannon
Environmental Research Division,
Argonne National Laboratory
9700 South Cass Avenue
Argonne, Illinois 60439
June 2002

附录B:粒径分布资料
这里列出为粒径分布不是很清楚且粒径在10um及以上的粒子质量占比较小（小于10%）的情况。这时在AERMOD中只需输入细粒子（2.5um以下）的质量百分比和全部粒子的质量中位径。
为便于使用，这里只列出推荐值，不再列出各次试验具体值及来源（详细参见原版资料）。

粒子成份
2.5μm以下质量百分比 (%)
中位径(μm)
备注
锑，复合物
60
1.0

砷，复合物
75
0.5

石棉
85
0.3

铍，复合物
(a) 80 (b) 0
(a) 0.4 (b) 7.0
(a)对应于燃烧 (b)对应于采矿
镉，复合物
70
0.6

CCaN2
0
7.0

氯复合物
60
1.0

铬复合物
55
1.2

钴复合物
75
0.5

焦炭炉排放物
80
0.4

氰化物（CN-）, 盐(不考虑HCN)
0
7.0

铅复合物
75
0.5

锰复合物
45
1.8

汞复合物 (不含气态汞)
80
0.4

精细矿物纤维
100
0.1

镍复合物
60
1.0

磷(假定为磷酯盐)
40
2.2

多环有机物 (POM)
80
0.4

多环有机复合物，如: PCCD/Fs
90
0.1

多环有机复合物，如: PAHs
93
0.1

放射性物质（含氡）
80
0.4

硒复合物
80
0.4

附录C:单个气态污染物和混合物的基本物化参数
在下表中查找污染物在空气中扩散率Da和水中扩散率Dw。如果找不到污染物，可参考分子结构相仿和分子量相近的物质。
在下面的表中（NA）表示该项无数据。
表 C.1. 单个气态污染物的基本物化参数， 298.2 K时.
序
化学名称
CAS No.
分子式
分子量 (g mol-1)
熔点 (ºC)
沸点 (ºC)
摩尔体积
Le Bas 摩尔体积 (cm3 mol-1)
空气扩散率 Da (cm2 s-1)
水中扩散率 Dw x 105 (cm2 s-1)
1
Acetaldehyde
75-07-0
C2H4O
44.05
-123.0
20.1
47.2
51.8
0.1281
1.450
2
Acetamide
60-35-5
C2H5NO
59.07
81.0
222.0
54.0
55.5
0.1153
1.402
3
Acetonitrile
75-05-8
C2H3N
41.05
-43.8
81.6
43.3
56.3
0.1342
1.393
4
Acetophenone
98-86-2
C8H8O
120.15
20.0
202.0
133.5
140.4
0.07241
0.8054
5
2-Acetylamino- fluorene
53-96-3
C15H13NO
223.28
193.0
NAa
224.3
248.0
0.05473
0.4807
6
Acrolein
107-02-8
C3H4O
56.06
-87.7
52.6
63.1
66.6
0.1094
1.279
7
Acrylamide
79-06-1
C3H5NO
71.08
84.5
192.6
69.9
80.8
0.1012
1.151
8
Acrylic acid
79-10-7
C3H4O2
72.06
12.3
141.0
69.2
83.2
0.1014
1.132
9
Acrylonitrile
107-13-1
C3H3N
53.06
-83.5
77.3
59.2
71.1
0.1133
1.235
10
Allyl chloride
107-05-1
C3H5Cl
76.53
-134.5
45.1
80.3
87.5
0.09463
1.099
11
4-Aminobiphenyl
92-67-1
C12H11N
169.23
53.5
302.0
184.2
198.8
0.06097
0.6032
12
Aniline
62-53-3
C6H7N
93.13
-6.0
184.1
97.8
110.2
0.08504
0.9533
13
o-Anisidine
90-04-0
C7H9NO
123.16
6.2
224.0
124.4
143.4
0.07449
0.7928
14
Benzene
71-43-2
C6H6
78.11
5.5
80.0
91.0
96.0
0.08962
1.040
15
Benzidine
92-87-5
C12H12N2
184.24
120
401.0
191.0
213.0
0.05962
0.5644
16
Benzotrichloride
98-07-7
C7H5Cl3
195.48
-5.0
221.0
167.6
180.9
0.06299
0.6568
17
Benzyl chloride
100-44-7
C7H7Cl
126.59
-45.0
179.0
130.2
124.3
0.07284
0.8791
18
Biphenyl
92-52-4
C12H10
154.21
69.0
256.1
177.3
199.6
0.06247
0.6009
19
Bis(chloromethyl) ether
542-88-1
C2H4Cl2O
114.96
-41.5
106.0
89.2
102.7
0.08636
0.9974
20
Bis(2-ethylhexyl) phthalate
117-81-7
C24H38O4
390.57
-55.0
384.0
475.5
524.8
0.03724
0.1002
21
Bromoform
75-25-2
CHBr3
252.75
8.0
149.1
83.9
99.5
0.08357
1.017
22
1,3-Butadiene
106-99-0
C4H6
54.09
-108.9
-4.4
77.5
81.4
0.1013
1.146
23
Caprolactan
105-60-2
C6H11NO
113.16
NA
NA
113.2
133.9
0.07823
0.8336
24
Captan
133-06-2
C9H8Cl3NO2S
300.59
172.5
NA
227.6
262.5
0.05355
0.4501
25
Carbaryl
63-25-2
C12H11NO2
201.22
145.0
NA
196.4
220.8
0.05853
0.5445
26
Carbon disulfide
75-15-0
CS2
76.14
-111.5
46.0
61.7
66.0
0.1053
1.285
27
Carbon tetrachloride
56-23-5
CCl4
153.82
-23.0
76.8
99.9
113.2
0.08024
0.9366
28
Carbonyl sulfide
463-58-1
COS
60.07
-138.8
-50.0
44.9
48.7
0.1234
1.493
29
Catechol
120-80-9
C6H6O2
110.11
105.0
245.0
103.2
110.8
0.08159
0.9499
30
Chloramben
133-90-4
C7H5Cl2NO2
206.03
200.0
NA
163.3
180.3
0.06351
0.6587
31
cis-Chlordane
5103-71-9
C10H6Cl8
409.78
108
NA
286.0
332.5
0.04756
0.3256
32
trans-Chlordane
5103-74-2
C10H6Cl8
409.78
104
NA
286.0
332.5
0.04756
0.3256
33
Chloroacetic acid
79-11-8
C2H3O2Cl
94.50
63.0
189.3
72.0
89.3
0.09631
1.086
34
2-Chloroacetophenone
532-27-4
C8H7OCl
154.60
56.5
247.0
152.2
161.3
0.06686
0.7233
35
Chlorobenzene
108-90-7
C6H5Cl
112.56
-45.2
131.7
109.7
116.9
0.07933
0.9167
36
Chlorobenzilate
510-15-6
C16H14Cl2O3
325.19
37.0
157.0 (0.07 mm Hg)
310.5
337.2
0.04613
0.3184
37
Chloroform
67-66-3
CHCl3
119.38
-63.6
61.1
81.2
92.3
0.08944
1.065
38
Chloromethyl methyl ether
107-30-2
C2H5OCl
80.51
-103.5
59.5
70.5
81.8
0.09910
1.143
39
Chloroprene
126-99-8
C4H5Cl
88.54
-130.0
59.4
96.2
102.3
0.08615
0.9996
40
o-Cresol
95-48-7
C7H8O
108.14
29.8
191.0
117.6
125.6
0.07732
0.8727
41
m-Cresol
108-39-4
C7H8O
108.14
11.8
202.2
117.6
125.6
0.07732
0.8727
42
p-Cresol
106-44-5
C7H8O
108.14
35.5
201.9
117.6
125.6
0.07732
0.8727
43
o-Cresyl acetate
533-18-6
C9H10O2
150.18
NA
208.0
160.1
177.2
0.06552
0.6685
44
Cumene
98-82-8
C9H12
120.20
-96.0
152.4
152.5
162.6
0.06830
0.7186
45
Diazomethane
334-88-3
CH2N2
42.04
-145.0
-23.0
29.6
53.4
0.1535
1.429
46
Dibenzofuran
132-64-9
C12H8O
168.2
86.5
287.0
160.5
176.7
0.06489
0.6702
47
1,2-Dibromo-3-chloropropane
96-12-8
C3H5ClBr2
236.34
NA
196.0
124.1
141.5
0.07110
0.8005
48
2,4-Dichloro-phenoxyacetic acid
94-75-7
C8H6O3Cl2
221.04
140.5
160.0 (0.4 mm Hg)
183.1
209.8
0.06008
0.5727
49
1,1-Dichloro-2,2-bis(p-chlorophenyl)ethylene
72-55-9
C14H8Cl4
318.03
89.0
NA
288.5
305.2
0.04782
0.3701
50
Dibutyl phthalate
84-74-2
C16H22O4
278.35
-35.0
340.0
311.4
347.2
0.04639
0.3034
51
1,4-Dichlorobenzene
106-46-7
C6H4Cl2
147.00
52.7
174.0
128.3
137.8
0.07236
0.8164
52
3,3'-Dichlorobenzidine
84-68-4
C12H10N2Cl2
253.13
165.0
NA
228.4
265.0
0.05390
0.4448
53
Dichloroethyl ether
111-44-4
C4H8Cl2O
143.01
-51.9
178.5
130.2
147.9
0.07206
0.7742
54
trans-1,3-Dichloropropene
10061-02-6
C3H4Cl2
110.97
NA
112.0
98.9
108.4
0.08301
0.9633
55
Dichlorvos
62-73-7
C4H7Cl2O4P
220.98
NA
140.0 (20 mm Hg)
169.1
193.1
0.06227
0.6194
56
Diethanolamine
111-42-2
C4H11NO2
105.14
28.0
268.8
105.8
126.7
0.08114
0.8672
57
Diethyl sulfate
64-67-5
C4H10SO4
154.19
-24.0
208.0
134.0
155.0
0.07073
0.7465
58
Diethylene glycol monobutyl ether
112-34-5
C8H18O3
162.23
-68.0
231.0
187.1
213.3
0.06073
0.5635
59
3,3'-Dimethoxybenzidine
119-90-4
C14H16N2O2
244.30
137.0
NA
244.3
279.4
0.05234
0.4166
60
4-Dimethylamino- azobenzene
60-11-7
C14H15N3
225.30
117.0
NA
234.3
275.9
0.05325
0.4233
61
N,N-Dimethylaniline
121-69-7
C8H11N
121.18
2.4
194.1
138.9
156.1
0.07111
0.7423
62
3,3'-Dimethylbenzidine
119-93-7
C14H16N2
212.30
131.5
NA
232.0
257.4
0.05404
0.4605
63
Dimethylcarbamyl chloride
79-44-7
C3H6NOCl
107.54
-33.0
167.0
93.2
110.6
0.08538
0.9508
64
N,N-Dimethylformamide
68-12-2
C3H7NO
73.10
-60.4
153.0
74.5
89.7
0.09820
1.083
65
1,1-Dimethylhydrazine
57-14-7
C2H8N2
60.10
-58.0
63.9
59.4
90.4
0.1108
1.078
66
Dimethyl phthalate
131-11-3
C10H10O4
194.19
5.5
283.7
188.2
206.4
0.05981
0.5819
67
Dimethyl sulfate
77-78-1
C2H6SO4
126.13
-27.0
76.0 (15 mm Hg)
93.0
110.6
0.08411
0.9508
68
4,6-Dinitro-o-cresol
534-52-1
C7H6N2O5
198.14
86.5
NA
146.5
172.4
0.06681
0.6844
69
2,4-Dinitrophenol
51-28-5
C6H4N2O5
184.11
115.5
sublimes
126.0
150.2
0.07171
0.7650
70
2,4-Dinitrotoluene
121-14-2
C7H6N2O4
182.14
71.0
300.0 decomposes
140.4
165.0
0.06845
0.7098
71
1,4-Dioxane
123-91-1
C4H8O2
88.11
11.8
101.5
76.0
93.6
0.09502
1.056
72
1,2-Diphenylhydrazine
122-66-7
C12H12N2
184.24
131.0
NA
191.0
216.0
0.05962
0.5565
73
Epichlorohydrin
13403-37-7
C3H5ClO
92.53
-26.0
117.0
68.1
88.9
0.09874
1.089
74
1,2-Epoxybutane
106-88-7
C4H8O
72.11
-150.0
63.3
69.9
90.2
0.1010
1.080
75
Ethyl acrylate
140-88-5
C5H8O2
100.12
-71.2
99.4
110.2
123.4
0.08017
0.8833
76
Ethylbenzene
100-41-4
C8H10
106.17
-94.9
136.1
132.0
140.4
0.07369
0.8052
77
Ethyl carbamate
51-79-6
C3H7NO2
89.09
49.0
185.0
80.6
100.6
0.09264
1.010
78
Ethyl chloride
75-00-3
C2H5Cl
64.52
-138.7
12.3
64.4
72.7
0.1061
1.220
79
Ethylene dibromide
106-93-4
C2H4Br2
187.87
9.9
131.6
84.8
98.4
0.08467
1.024
80
Ethylene dichloride
107-06-2
C2H4Cl2
98.96
-35.5
83.5
83.0
93.6
0.09040
1.056
81
Ethylene glycol
107-21-1
C2H6O2
62.07
-13.0
197.3
57.9
66.6
0.1113
1.279
82
Ethylene glycol monobutyl ether
111-76-2
C6H14O2
118.18
-74.8
168.4
140.0
159.0
0.07104
0.7315
83
Ethyleneimine
151-56-4
C2H5N
43.07
-77.9
56.0
47.9
63.7
0.1279
1.309
84
Ethylene oxide
75-21-8
C2H4O
44.05
-111.7
10.6
28.9
45.8
0.1534
1.535
85
Ethylene thiourea
96-45-7
C3H6N2S
102.16
131.0
NA
93.5
118.3
0.08574
0.9092
86
Ethylidene dichloride
75-34-3
C2H4Cl2
98.96
-96.9
57.4
83.0
93.6
0.09040
1.056
87
Formaldehyde
50-00-0
CH2O
30.03
-92.0
-19.1
26.6
29.6
0.1720
1.845
88
Heptachlor
76-44-8
C8H5Cl7
373.30
95.5
NA
230.9
274.6
0.05274
0.4258
89
Hexachlorobenzene
118-74-1
C6Cl6
284.78
231.8
325.0
203.1
221.4
0.05657
0.5428
90
Hexachlorobutadiene
87-68-3
C4Cl6
260.76
-21.0
215.0
189.6
206.8
0.05861
0.5808
91
(á)1,2,3,4,5,6-Hexachlorocyclohexane
60291-32-9
C6H6Cl6
290.83
159.5
288.0
217.0
243.6
0.05482
0.4903
92
(ã)1,2,3,4,5,6-Hexachlorocyclohexane
58-89-9
C6H6Cl6
290.83
112.5
323.4
217.0
243.6
0.05482
0.4903
93
Hexachloro- cyclopentadiene
77-47-4
C5Cl6
272.77
-9
239.0
187.2
210.1
0.05882
0.5719
94
Hexachloroethane
67-72-1
C2Cl6
236.74
187.0 (tripl. pt.)
NA
157.8
177.2
0.06397
0.6685
95
Hexamethylene diisocyanate
822-06-0
C8H12N2O2
168.20
NA
255.0
176.2
208.8
0.06223
0.5754
96
Hexamethyl- phosphoramide
680-31-9
C6H18N3OP
179.20
7.0
232.5
179.6
225.3
0.06142
0.5332
97
Hexane
110-54-3
C6H14
86.18
-95.3
68.7
127.7
140.6
0.07660
0.8043
98
Hydrazine
302-01-2
N2H4
32.05
1.0
113.6
18.3
35.8
0.1922
1.709
99
Hydroquinone
123-31-9
C6H6O2
110.11
172.3
287.0
103.2
110.8
0.08159
0.9497
100
Isophorone
78-59-1
C9H14O
138.21
-8.1
215.2
163.3
177.4
0.06541
0.6679
101
Maleic anhydride
108-31-6
C4H2O3
98.06
52.8
202
68.3
79.8
0.09796
1.159
102
Methanol
67-56-1
CH4O
32.04
-97.6
64.6
31.3
37.0
0.1598
1.686
103
Methoxychlor
72-43-5
C16H15O2Cl3
345.66
87.0

327.7
358.1
0.04485
0.2877
104
Methyl bromide
74-83-9
CH3Br
94.94
-93.7
3.5
44.7
52.9
0.1153
1.435
105
Methyl chloride
74-87-3
CH3Cl
50.49
-97.7
-24.0
43.8
50.5
0.1284
1.467
106
Methyl chloroform
71-55-6
C2H3Cl3
133.41
-30.4
74.0
101.7
114.5
0.08059
0.9293
107
Methyl ethyl ketone
78-93-3
C4H8O
72.11
-86.7
79.6
88.2
96.2
0.09180
1.039
108
Methylhydrazine
60-34-4
CH6N2
46.07
-52.4
87.5
38.8
59.5
0.1367
1.355
109
Methyl iodide
74-88-4
CH3I
141.94
-66.4
42.5
52.6
62.9
0.1047
1.317
110
Methyl isobutyl ketone
108-10-1
C6H12O
100.16
-84.0
116.5
129.2
140.6
0.07486
0.8043
111
Methyl isocyanate
624-83-9
C2H3NO
57.05
-45.0
39.5
49.4
63.7
0.1200
1.309
112
Methyl methacrylate
80-62-6
C5H8O2
100.12
-48.0
100.5
110.2
121.8
0.08017
0.8913
113
Methyl tert-butyl ether
1634-04-4
C5H12O
88.15
-108.6
55.2
113.3
129.4
0.08043
0.8544
114
4,4'-Methylenebis (2-chloroaniline)
101-14-4
C13H12N2Cl2
267.16
NA
NA
248.9
277.0
0.05166
0.4212
115
Methylene chloride
75-09-2
CH2Cl2
84.93
-95.1
40.0
62.5
71.4
0.1033
1.232
116
4,4'-Methylenediphenyl diisocyanate
101-68-8
C15H10N2O2
250.26
NA
NA
246.3
275.0
0.05208
0.4250
117
4,4'-Methylenedianiline
101-77-9
C13H14N2
198.27
92.5
398
211.5
235.2
0.05664
0.5095
118
Naphthalene
91-20-3
C10H8
128.18
80.2
217.9
140.9
147.6
0.07029
0.7754
119
Nitrobenzene
98-95-3
C6H5NO2
123.11
5.7
210.8
105.4
124.5
0.07997
0.8778
120
4-Nitrobiphenyl
92-93-3
C12H9NO2
199.21
114
340.0
191.8
208.0
0.05920
0.5776
121
4-Nitrophenol
100-02-7
C6H5NO3
139.11
113.8
279.0
111.5
126.8
0.07722
0.8697
122
2-Nitropropane
79-46-9
C3H7NO2
89.09
-91.3
120.2
80.6
97.4
0.09264
1.031
123
N-Nitroso-N-methylurea
684-93-5
C2H5N3O2
103.08
123.5 decomposes
NA
69.2
101.9
0.09691
1.002
124
N-Nitrosodimethylamine
62-75-9
C2H6N2O
74.08
NA
154.0
60.9
87.7
0.1063
1.098
125
N-Nitrosomorpholine
59-89-2
C4H8N2O2
116.12
29.0
225.0
85.1
135.7
0.08797
0.8256
126
Parathion
56-38-2
C10H14NO5PS
291.26
6.1
375.0
253.9
288.0
0.05097
0.4005
127
Pentachloro- nitrobenzene
82-68-8
C6Cl5NO2
295.34
144.0
328.0 decomposes
198.9
223.9
0.05702
0.5366
128
Pentachlorophenol
87-86-5
C6Cl5OH
266.34
174.0
310.0 decomposes
190.5
204.2
0.05843
0.5879
129
Phenol
108-95-2
C6H5OH
94.11
40.9
181.8
97.1
99.7
0.07844
1.016
130
p-Phenylenediamine
106-50-3
C6H8N2
108.14
146.0
267.0
104.7
124.4
0.07598
0.8783
131
Phosgene
75-44-5
COCl2
98.92
-127.9
8.0
64.0
71.4
0.1004
1.232
132
Phosphine
7803-51-2
H3P
34.00
-133.0
-87.8
29.8
36.7
0.1604
1.716
133
Phthalic anhydride
85-44-9
C8H4O3
148.12
130.8
295.0
118.2
132.5
0.07492
0.8400
134
1,3-Propane sultone
1120-71-4
C3H6SO3
122.14
32.0
180.0 (30 mm Hg)
84.5
105.6
0.08779
0.9797
135
â -Propiolactone
57-57-8
C3H4O2
72.06
-33.4
162.0
50.9
69.1
0.1144
1.254
136
Propionaldehyde
123-38-6
C3H6O
58.08
-80.0
48.0
67.7
74.0
0.1057
1.209
137
Propoxur
114-26-1
C11H15NO3
209.25
87.0
decomposes
214.1
248.3
0.05613
0.4800
138
1,2-Dichloropropane
26198-63-0
C3H6Cl2
112.99
-100.4
96.4
103.6
115.8
0.08124
0.9223
139
Propylene oxide
75-56-9
C3H6O
58.08
-111.9
35.0
49.4
70.5
0.1197
1.241
140
1,2-Propylenimine
75-55-8
C3H7N
57.10
NA
67.0
50.1
76.3
0.1194
1.188
141
Quinoline
91-22-5
C9H7N
129.16
-14.8
237.1
127.2
144.7
0.07345
0.7872
142
Quinone
106-51-4
C6H4O2
108.10
115.7
sublimes
98.6
103.4
0.08334
0.9929
143
Styrene
100-42-5
C8H8
104.15
-31.0
145.0
127.4
133.0
0.07500
0.8377
144
Styrene oxide
96-09-3
C8H8O
120.15
-35.6
194.1
115.2
138.0
0.07718
0.8155
145
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
C12H4O2Cl4
321.98
305.0
446.5
241.4
267.8
0.05196
0.4392
146
1,1,2,2-Tetrachloroethane
79-34-5
C2H2Cl4
167.85
-43.8
146.5
120.4
135.4
0.07361
0.8270
147
Tetrachloroethylene
127-18-4
C2Cl4
165.83
-22.3
121.3
115.8
128.0
0.07492
0.8610
148
Toluene
108-88-3
C7H8
92.14
-94.9
110.6
111.5
118.0
0.08054
0.9097
149
Toluene-2,4-diamine
95-80-7
C7H10N2
122.17
99.0
292.0
125.2
146.6
0.07663
0.7780
150
2,4-Toluene diisoc