SASOL金属加工液乳化剂配方说明.pdf

saso Lreaching new frontiersEmulsifiers for Metal Working Fluids 金属加工液乳化剂Sasol(China)Chemical Co.,Ltd.General Compounds of Water Based Metal SSSOLWorking Fluids 水基金属加工液的一般组成 皿General Formulation:典型配方 Water 水 Oil(mineral oil,ester oil,natural fats and oils)油(矿物油、合成酯油、天然油脂)Emulsifier(anionic or nonionic surfactant)乳化剂(阴离子或非离子型表面活性剂)Corrosion Preventing Agent(ammonium compounds(i.a.based on fatty acids),sulfonate,benzotriazole,phosphates)缓蚀齐U(镀基化合物(基于脂肪酸)、磺酸盐、苯并三唾、磷酸盐)Coupling agent(fatty alcohol)偶合剂(脂肪醇)Defoamer(silicone defoamer,soap,fatty alcohol)消泡剂(有机硅消泡剂、肥皂、脂肪醇)Biocide生物杀灭剂 EP-Additive其它助剂saso Lreaching new frontiersContent主要产品MARLOX RTEmulsifier with high lubricity and high stability 具自高润滑性及高稳定性的乳化剂MARLOWET acidsAnionic Co-Emulsifiers with anti corrosion properties for hardwater stable MWF阴离子型助乳化剂,具有耐腐蚀性和抗硬水性能MARLOSOL TA/SAFOL ENEmulsifiers with high cleaning performance,NPE alternatives具白高清洗性能的乳化剂,可以替代NPEMARLOWET EsterEnvironmentally friendly water soluble lubricants and emulsifiers环境及好型水溶性润滑剂及乳化剂saso Lreaching new frontiersMARLOX RT-High Efficiency and Low Foaming Emulsifiers高效低泡乳化剂saso Lreaching new frontiersMARLOX RT-High Efficiency and LowFoaming Emulsifiers高效低泡乳化剂Nonionic非离子型 MARLOX RT 42 MARLOX RT 64W/O Emulsifier油包水型O/W Emulsifier水包油型HLB5HLB8.5MARLOX RT 42 一 W/0 Emulsifier with sasoLDefoaming Property具有消泡性能的W/0乳化剂的newfrontiers Hydrophobic Emulsifier 疏水性乳化剂 High Emulsifying Power 乳化力强 Low Foaming 低泡 Defoaming Properties 具有消泡性 Good at Low Temperature 低温性能好 Good Storage Stability 贮存安定性好 Readily Biodegradable 可生物降解PropertyMARLOX RT 42Active co ntent 活性物%99Appearance 夕卜观Cl ear o r hazy l iq uid 透明或浑浊液体Cl o ud Po int 浊点 10%in25%BDG C51-53Visco sity 20 粘度mPa.sabo ut 70Visco sity 50 C 粘度mPa.sabo ut 30Co l o r色泽Hazen99Appearance 夕卜观Cl ear o r hazy l iq uid 透明或浑浊液体Cl o ud Po int 浊点 10%in 25%BDG C60-62Visco sity 20 C 粘度mPa.sabo ut 100Visco sity 50 C 粘度mPa.sabo ut 30Co l o r色泽Hazen uo 弓 qssQ-0,11Size pm10100saso Lreaching new frontiersEmulsification Process 乳化过程cl ear1000-750-500-Temperature:23C250-Shear rate=120 s-1806040200MARLOX RT64Ol eyl al co ho l+5EO0-100finel y dispersed emul sio nInstrument:Bo hl in Viscomixina ratio Oil+Emul ifier(4:1)in water%1油+乳化剂(4:1)占水体系比重%saso Lreaching new frontiersOxidation and temperature stability氧化性及高温稳定性 advantage for slow oxidation at ambient temperatures 在环境温度下氧化非常缓慢8 0(48 h)MARLOX RT 64Ol eyl+5 EOsaso Lreaching new frontiersFoaming Properties 泡沫性能Foaming properties according EN 13996 泡沫测试方法400 Fo am Generatio n with centrifugal pedal0 2000 U/min;5 minutes Co ncentratio n:1g/l Temperature:2050-300-350-250-200-150-100-0-50 ,0 2 4 6 8 10 12 14time min=E】uEno EBOJ。Determinatio n o f Fo am Height in gl as cyl inder o ver timesaso Lreaching new frontiersMARLOX RT Dispersing Properties 钙皂分散能力20,1.0g/L LAS+0.1 g/L additive100-t%与 gf AouaJEdsuEH80-60-40-20-us SS+MARLOX RT42SS+MARLOX RT64 LAS+MARLOX B24/50“S+MARLOX B24/80 US+MARLOX MO124 US+MARLOX M0154+MARLOX FK64-LAS+MARLOX FK69 US+MARLOX FK86 LAS+MARLOX S58+MARLOX K158UXS+MARLOX LM55/18-LAS+Ol eyl+2EO+Ol eyl+5EORT 64 RT 42Ol eyl+5EOOl eyl+.00100200300Water hardness 水硬度ppm CaCO3saso Lreaching new frontiersLubricity润滑性能Product1%in water5%in water10%in watermgmgmgMARLOX RT 42353325MARLOX RT 64131212No nyl pheno l+4 EO333229No nyl pheno l+9 EO161111Ol eyl-FA+2 EO332725Ol eyl-FA+5 EO211514Determination of weightloss摩擦损失 stainless steel 不锈钢,rotations旋转：100 m weight负荷:1,5 kgsaso Lreaching new frontiersMARLOX RT-Environmental profile 对环境影响 Products have an excellent environmental profile.产品对环境的影响非常大Biodegradation生物降解性Daphnia toxicity水蚤致毒性MARLOX RT 42Readily biodegradable;60%after 28 days(OECDTG 301 B)EC 50 Daphnia magna;10-100 mg/l;48 hours;OECD TGMARLOX RT 64Readily biodegradable;60%after 28 days(OECD TG 301 B)EC 50 Daphnia magna;10-100 mg/l;48 hours;OECD TGsaso Lreaching new frontiersMARLOX RT 42 Alternatives to Oleth-2油醇醒2E0替代 EUMULGIN 3370 EUMULGIN ET2 EUMULGIN EP 2L EUMULGIN 020 SYNATIVE AC 3370 V SYNATIVE AC 3412 VRec.:MARLOX RT 42 plus 15 20%alcohol(ISALCHEM 145/ISOFOL 16)添加 15 20%支链脂肪醇(I SALCHEM 145/I SOFOL 16)MARLOX RT 64 Alternatives to Oleth-5 saso L油醇醒5EO替代reaching new frontiers EMULSOGEN M EUMULGIN ET5 EUMULGIN 05 SYNATIVE AC ET 5 V SYNATIVE AC EP 5LVRec.:MARLOX RT 64 plus 5 6%alcohol(ISALCHEM 145/ISOFOL 16)添加5 6%支链脂肪醇(I SALCHEM 145/I SOFOL 16)Summary 总结saso Lreaching new frontiersMARLOX RT provide excellent emulsification and also additional performance benefits in comparison with oleyl alcohol ethoxylates.和普通的油醇聚氧乙烯醴相比,MARLOX RT除了具有出色的乳化能力以外,增加了许多附加性能:Low foaming Emulsifier低泡乳化剂,适合于要求低泡的配方 High lubricity优异的润滑性能,提升配方的润滑能力 Good hardwater tolerance/lime soap dispersing properties 良好的抗硬水/钙皂分散性,增加配方适用性 Excellent oxidation stability出色的氧化稳定性能,便于产品的贮存saso Lreaching new frontiersMARLOWET Ethercarboxylic Acids 醇醒搂酸Hard water stable anionic surfactants抗硬水型阴离子表面活性剂MARLOWETEthercarboxylic Acids 醒竣酸 S3SOL-Hard water stable anionic surfactants硬水稳定的阴离子表面活性剂,Ethercarboxylic acids 做竣酸R2IR1-O-(CH2-CH-O)x-CH2-COOHR1=linear alkyl,branched alkyl or alkylaryl 直连烷基、支链烷基或芳烷基R2=CH3 or HGeneral application characteristicts 典型应用/性能 Anionic co-emulsifier阳离子型助乳化剂 Very good hardwater tolerance具有出色抗硬水能力 Capture hardness ions and deliver electrolyte stability to surfactant systems捕捉硬离子,使表面活性剂体 系对电解质稳定 Stable in acidic and alkaline form 在酸性和碱性环境 中稳定Distinctive functions增值性能 Corrosion inhibition 抗腐蚀性 Low foaming 低泡 Enhanced lubricity 润滑性增强saso Lreaching new frontiersEther Carboxylic Acids 酸较酸产品ProductOrigin R1HLBAcid Valuemg KOH/gMarlowet 4539C9 alcohol10.5107-114Marlowet 4539 LFC9 alcohol10.5107-114Marlowet 4541C12/14 alcohol7.197-102Marlowet 1072C12/14 alcohol10.075-8 2Marlowet 4538C13 alcohol12.173-78Marlowet 4570C13 alcohol10.055-60Marlowet 4570 LFC13 alcohol10.055-60Marlowet 4563C16/17 alcohol12.560-65Marlowet 4560C16/18 alcohol8.560-70Marlowet 4561C16/18 alcohol10.039-46Ethercarboxylic Acids-Hardness tolerance sssql酸竣酸-抗硬水能力 mg-ers25,concentration 1.0g/L,pH 9(adjusted with ME A)55【e/nlu-uo-su。色nsoI n-8o nu o duo o2oI o4oI o6water hardness ppm Ca2+Ethercarboxylic Acids-Hardness tolerance sssql醍搂酸(Mw ECA)-抗硬水能力(SOOOppm)reaching new frontiers25,5%Mw ECA-TEA salt,pH 8.52500ppm hard water,24hrsSerio us turbid and fl o ccul atio n严重浑浊、分层5000ppm hard water,24hrssaso Lreaching new frontiersMARLOWET Series-Dispersion of lime soaps钙皂分散性U,2SU9 onss605040302010T=25,concentration I.Og/L,pH 9(adjusted with ME A)0o l eic acido l eic acid/Marl o wet4538(3:1)o l eic add/Marl o wet4539(3:1)o l eic acid/Mar1o wet4560(3:1)o l eic acid/Marl o wet4561(3:1)Application:increase stability in hard watery曰sol应诩:提高配方的硬水稳定性 3Mineral o il 基础油3535Tal l o il fatty acid妥尔油脂肪酸77Marl o x RT 6455Marl o wet 456102Isal chem 14522Bo ric acid勺期酸5.55.5MEA单乙醇胺88Bio cide杀菌剂22Water 水To 100To 100AppearanceCl earCl earpH(5%in tap water)9.609.61Appearance(5%in tap water)Fo ggy,no o il/so apFo ggy,no o il/so apAppearance(5%in 2500 ppm water)4%o il/so ap separatio n(24hr)Mil ky,no o il/so ap(24hr)Appearance(5%in 5000 ppm water)5%o il/so ap separatio n(24hr)Mil ky,no o il/so ap(24hr)Application:increase stability in hard waterydsol 应诩:提高配方的硬水稳定性 neW frontiers5%diluents in hard water,after 4 days5%不同硬度水的稀释液,4天后“一 without ECA,oil/soap separation 不含醇醒较酸,有浮油/浮皂”一 contain ECA,no oil/soap separation 含醇醒较酸,无浮油/浮 皂Ethercarboxylic Acids-Corrosion inhibitionas l 醛较酸-抗腐蚀能力 reding neW frontiers Method 方法：Corrosion inhibition test according DI N 51360,iron flakes are soaked with water/inhibitor dispersion on filter paper.抗腐蚀性能实验依据DM 51360。在滤纸上用被测溶液浸 湿铁片。Processing 配制:Ol eic acid3 parts2%so l utio n in 20dH,use 10%MEA waterMw ECA1 partso l utio n to adjust pH Result of 2 hrs later 2小时后结果:pH-9.0pH-10.0Mw 453920Mw 4539LF20Mw 456030Mw 456132saso Lreaching new frontiersFoaming泡沫性能60o o o o o 5 4 3 2 1IE nEeoL2%in tap waterOperation condition:2%in tap water,shaking up and down about 10 times操作条件:2%溶液上下振摇10次saso Lreaching new frontiersSummary 总结 Best hardwater tolerance/lime soap dispersing 抗硬水/钙 皂分散能力最强:Marlowet 4539/4539LF/4561 Low foaming 低泡型:Marlowet 4539LF/4560/4561 Outstanding corrosion inhibition 抗腐蚀能力突出:Marlowet 4539/4539LF/4560 With lubricity 提升润滑性能:Marlowet 4560/4561saso Lreaching new frontiersMARLOSOL TA and SAFOL EN EthoxylatesAlternatives ofAPEOAPEO替代物saso Lreaching new frontiersElimination ofAPEOs APEO的禁用Mid-1990sEnd-1990sProven that biodegradation ofAPEOs results in 证实了APEO的生物降解会导致Bioaccumulation 生物积累Eco-toxicity生态毒性Recommendation to phase outAP and APEO particularly in强烈建议在以下领域禁用APEO/&/,洗涤Textile&Paper 纺织&造纸Cleaning application 清洗Catego ryNPE Usage(to nnes)I&I23000Emul sio n po l ymerisatio n9000Textil e auxil iaries8000Captive use7000Leather auxil iaries6000Agricul ture5000Paints4000Metal industry2000Pul p&paperwo oOther niche markets7000(unacco unted fo r)5600To tal77600January 2005Western Europe consumption of NPEs in 1997Amendment of European Directive 76/796 restricted use of APEO in a number of applicationsnDirective 76/796修改法案规定了在众多应用中名令禁止APEO的使用31saso Lreaching new frontiersElimination ofAPEOs APEO的禁用January 2013Chinese Environmental Protection Ministry issued the plan on the chemical environmental risk prevention and control中国环保部出台:化学品环境风险防控“十二五”规划strict restrictions on the production and use ofAPEOAPEO作为重点防控化学品,严格限制生产及使用The APEO substitution and elimination become a necessityAPEO替代和淘汰成为必然32MARLOSOL TA 一 Branched C13 Alcohol 535OLEthoxylates 异构C13醇乙氧基化物 reaching newfrontiers(1)10%in BDG 25%water solution;(2)1%in waterTrade Name 品名EO NumberEO数Cloud Point 浊点FCHLBSetting Point 凝固点。5Content含量%MARLOSOL TA 30348-51(1)7.999,5MARLOSOL TA 50564-66 10.599,5MARLOSOL TA 60669-71 11.499,5MARLOSOL TA 70773-75 12.199.5MARLOSOL TA 80876-78 12.8299.5MARLOSOL TA 90957-59 13.3699.5SA FOL EN 一 Semi-branched C12-13 Alcohol 5 3 solEthoxylates半支链C1213醇乙氧基化物 reaching new frontiers 10%in BDG 25%water solution;（2）1%in waterTrade Name 品名EO NumberEO数Cloud Point浊点。5HLBSetting Point 凝固点。3Content含量SAFOU&EN20246-50 6.299.5SAFOLEN 30357-61 8.299.5SAFOLEN 50569-73 10.699.5SAFOLEN 70751-55（2）12.2299.5SAFOLEN 90977-81（2）13.4899.5saso Lreaching new frontiersReplacement for NPE壬基酚乙氧基化物替代产品(b):10%am in 25%BDG so l utio n,(w):1%water so l utio n,(cl):1%am in 10%NaCI so l utio nSurfactant 产品EO NumberEO数Appearance 外观25。,Cloud Point浊点PCMelting point屣固点。5HNPE-44Clear liquid54-57(b)-208.7SAFOL EN 303Clear or hazy liquid57-61(b)-128.1MARLOSOL TA 404Clear or hazy liquid58-61(b)-49.4NPE-66Clear liquid67-70(b)-2010.7SAFOL EN 505Slight hazy liquid69-73(b)-210.6MARLOSOL TA 606Clear or hazy liquid69-71(b)-411.4NPE-99Clear liquid52-56(w)-512.9SAFOL EN 707Slight hazy liquid51-55(w)212.2MARLOSOL TA 808Clear or hazy liquid76-78(b)212.8NPE-1010Clear or hazy liquid61-66(w)-213.3SAFOL EN 909Slight hazy liquid49-53(cl)813.4MARLOSOL TA 909Clear or hazy liquid57-59(w)613.3Guide Formulation for Mineral Oils 推荐配方 reaching new frontiersComponent 组分Ratio,wt%含量Mineral o il 基础油70 75Tal l o il fatty acid 妥尔油脂肪酸46Petro l eum sul fo nate 石油磺酸钠812Marl o x RT 4235Marl o wet 4539。3Isal chem 145/Iso fo l 1612MEA单乙醇胺35TEA三乙醇胺35Bio cide杀菌剂2Defo amer消泡齐Uq.s.适量Component 组分Ratio,wt%含量Mineral o il 基础油30 35Tal l o il fatty acid 妥尔油脂肪酸58Marl o x RT 6446Marl o wet 456102Isal chem 145/Iso fo l 1612Bo ric acid 硼酸46MEA单乙醇胺68Bio cide杀菌剂2Water 水To 100Defo amer消泡齐Iq.s.适量saso Lreaching new frontiersMARLOWET EsterEnvironmentally friendly water soluble lubricants and emulsifiers 环境友好型水溶性润滑剂及乳化剂MARLOWET LVS Emulsifier for Vegetable oils SdSOL植物油乳化剂 3 Ester of castor oil ethoxylate 聚氧乙烯蔓麻油酯Q Used for building stable macro emulsions 用于建立稳定的乳液体系 Free of labelling 环境友好 Low pour point for easy handling 倾点低,使用方便 Use as emulsifier with installed lubricating properties具有润滑性能的乳化剂与大豆油/水形成微乳液体系0,20,80,0 mico emul sio n-cl ear micro emul sio n-o paq ue l iq uid crystal l ine phases macro emul sio n0,40,00,00,20,4water0,8micro emul sio n o paq ue 不透明的微乳液0,60,40.2MARLOWET R11 Co-Emulsifier,Lubricant助乳化剂,润滑剂saso Lreaching new frontiers Castor oil ethoxylate乙氧基化篦麻油Q Used as Co-Emulsifier in LVS applications 作为MARLOWET LYS应用时的助乳化剂 Free of labelling 环境友好 Very low pour point 倾点非常低 Excellent lubricating properties 出色的润滑性能 Self dispersing agent in water based working fluids在水基工作液中具有自分散性saso Lreaching new frontiersMARLOWET/MARLOSOLName产品名 MARLOSOL OL7 MARLOWET4702S MARLOSOL FSS MARLOWET 4750 M MARLOWET R40Compos币on组成PEG-7 MonooleatPEG-8 DioleatePEG-12 DioleateSoybean oil esterPEG-40 Castor OilMain Function主要功能 Emulsifier for mineal oils,lubricanthydrophobe co-emulsifier,lubricantEmulsifier for mineral oils,lubricantEmulsifier for paraffinic oils,lubricantEmulsifier for hydrophilic oils,dispersant Excellent enviromential properties,no labellingsaso Lreaching new frontiersMARLOWET EstersNameHLBCP*setting point clear melting point Marlosol OL7ca.10,5ca.62ca.5ca.5Marlowet 4702ca.8,3ca.42ca.-2ca.5Marlosol FSca.10,3ca.52ca.12ca.18Marlowet 4750 Mca.9,6ca.65ca.-6ca.3Marlowet R11ca.6,9ca.53ca.-40ca.20Marlowet R40ca.13,1ca.71ca.17ca.24Marlowet LVSca.6,9 10-20ca.-20*10%ig in 25%BDG-LdsungMARLOWET Esters-aqueous solubility 53501 水溶性能 reaching new frontiersNameAppearance 10%in water水溶液外观viscosity 10%粘度 D=10 s1 mPasrheology 10%流变性Marlosol 0L7Dispersion 可分散ca.56shear thinning 剪切稀化Marlowet 47022-phases 两相-newtonic牛顿流体Marlosol FSfine Dispersion 精细分散ca.250shear thinning 剪切稀化Marlowet 4750 Mfine Dispersion 精细分散ca.37shear thinning 剪切稀化Marlowet R11fine Dispersion 精细分散ca.45shear thinning 剪切稀化Marlowet R40Clear清澈ca.2newtonic牛顿流体Marlowet LVSDispersion 可分散ca.32shear thinning 剪切稀化saso Lreaching new frontiersMARLOWET/MARLOSOL Ester Lubricity 润滑性能5%aqueous solution/dispersionNameFriction loss mgMarlosol OL711Marlowet 470214Marlosol FS13Marlowet 4750 M7Marlowet R115Marlowet R406Marlowet LVS3MARLOWET EstersName MARLOSOL 0L7 MARLOWET4702 MARLOSOL FS MARLOWET 4750 M MARLOWET 4753 MARLOWET COE 145 MARLOWET R11 MARLOWET R40 MARLOWET LVSsaso Lreaching new frontiersEnvironmental LabellingnonenonenonenoneR38nonenonenone nonesaso Lreaching new frontierssaso Lreaching new frontiers