x射线光电子能谱手册（英文版）.pdf

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c t s E t t 6)(3 9 .,.,.,.,.,.,.,.:!5:!y x t t:b f f y i l:1 9 k r t T;i t i !/i t)/1 7 k t (:t(3!7 k (J f :8 2-r :t)/S;l l)f (:f:k k t t k t 1.J ,.,.,.,.,.,:!$:6(5,l-i T k z l t l r i t i t l f k s t)7 J E l e k c r:t f():7 t l l l L t j 1(-:a y s .,.,.,.,.,.,.,.,.,.,.,.(!5 2/I!.l-i f t f:1)(l s l t i t b r r t h y l l t c r r i r T l t f f 3:l k l i j l l L t t )(-!a 7 s.,.,.,.,;!5 6(.i f t t l 1)()i l i t i ():t s i f l l h I t l f r l ()f i (;E t l (T)r (#k!r .,.,.;(k i lL l.X-ra!Phot oe l e ct ron spec t r os corA.l nt roduc t i onHa n d b o;k Q f X-r a y Ph o t e k l t c t r o n s F k t t r g s t o p Ha n t l l l t mk Q f X-r a y P hp t n e kt t r a n S pe c t r e s c o z y*#*-4 I.1 c r 2 s.x Ph o t c m Pk o t oe l e c ro n7K x j s&u g e r e l e c t t o n z-.-A ,L 7 3 c I 2 2P e r k i n.El m r c e r g c r a t i o nDR.;,A !C.Pr e z a r i n g a n d Mo u n t i n g Sa t ug l e sC.Pr e par i nk ant l M ol l nt i ng Sampl e sC.Pr e p a r i n g a n d 5(:u n t i n g Sa m p l e bHa nd b o o k n f X-r a y P L a t o e l e c t r o n S pe c t r g s c n p yD.Ex p e r i mt n 11 Pr e t f d n r ePr oce dureD.Expe r i me nt al1 0D.E$t m i c Nu ml l c r 53 9Ca r b o n Ckt n mi c Numl l c r 6Ha nt l l l o o k ()f X.r a y Ph e t e l e c t r o n S p e c t r t l s c n p)4Car bon CA t om c Nt l m be r t;Xi t r o ke nt o mi c Na ml l e r 7I i n BNKL Ls I o n o c l l r o n l a t e t i Xl K()(K7.l oBC)$0 0 1 2 0 0 1 9 0 0 8 0 0 6 0 4 0 p 2 0 0Bi n l i n g En t r g y (e V)Ni t r t l k e n r ilt qt uk Nt l mbt r J!F i n BNKL LMg KC tB KLLk c1 2 0 0 1 0 0 0 8 q 0 6 g 0 4 0 g 2 0 g gBi a d i n g E n e f g y (e$)Ox y g en 0At o mi c Nu mt e r E IHa n d b o o k e f X.r a y P h :t e l e c t r p n s z e c t r o s r o p,0 i n .*1 2 0 3 (S a g/i r e)Mo n f l c h mma t e z t k Kc tKLLKLL A1A1k rr j r(2 2 S1 4 9 0 !2 0 0 1 0 9 0 8 0 6 0 0 4 0 0 2 0 0 0Bi q z l g Ec u r g y (t V)Ox yg t n ()At f h mi c Numbe r si(1.LFl t l or i ne Fomi c Na mb e r 9Fl t t or i n e FAt n mi c Num l l t rF l n L!F K LL51 g Kf/KLI-$?Fu1 2 f,0 )i)()t)8 t)()6 0 9 4 0(J 7(i 0 ()Bt r k d i f t g E n t qy (t V)47Ne t)n Nexit o mi c Numb e r 1 4849Set l i um Nat a mi c Numl l e r 1 1 l z n d b f o k q f l k-r a:P h i t t l t c t r c n S p t c t r:s c t p yFq1 s r.l n I ACLl S =i (1 72.1 e%I l al l dl l t mk e f X-r a,P n t c e l e c t r t)n S p e dr t s t ppyMa g ne s i u m 5 1 gxi t e mi c su mb e r 1 22 2 =4 9 .8 z b Ma g ne s i um 51 kA t omi t z 5 umbgr 1 2Il 2 551 g K ak LLKLL2 2IXrAf0t1 20 0 1 09 9 8 00 6 00 109 2 0q 0Bi n d i n g En c r g y (e V)5 3Al umi num AIAl p n?i c Nnmbi l r 1 3Ha n d bo t)k o f X.r a l Pk o t o e l e c t r p n Spe c t r e s c o g 2 3Mon o c h r o r n a zl i Al Ka2/.&rAr1 4 0 9 1 2 0 0 1 0 0 0 8 0 6 0 0 4 0 0 2 0 0 F n d i n g En e f g y (t 7)22 =72 .9 e v5 4;I L MS Il 5 1 g KC II2 5 2grAr1 2 0 0 1 0 9 9 8 9 6 0 1 0 2 9 0 0Bi n d l n g En e r g y (e V)i l i c o n Sit emi c h uml l er 1 42 2Mono ck r oma t e ,&l i:aL MM y1 4 0 0 1 2 0 0 l 0 p p 8 0 0 6 0 4 0 2 0 9 2Bi n i n g En e f g y (e V)2.9 =9 9.3 e V62/=1(6.3 e v5 7Pho s phg r us PAt c mi c Numl l e r 1 5l l a pd b a p k p f X-r a)Ph e t p e l e c t r n n s p e t t r a s c o p),2?h l o n o c h r o l n a t c l K:L Ms f2 8LMM0Z.I 0 1 2 0 0 1 0 9 9 o o 5 0 0 4 9 0 2 9 Bl n i n g En c r g y (e V)Phg s gkor u sAt t l mi c Nu mb e r5 1 g Kc tL).1 5 1LMM01 2 0 0 1 0 0 8 0 0 6 0 4 2 0 1 q (Bl n d i n g En r r g y (e 7)i ul f ur sN t a mi c N u mL t r 1 6I l a n t l bo g k n f X.r a)Ph o t o e l e c t r t)n s g e c t r a s c o y)rN l c n o c r e ma l e d A1 KJ 2 pLMN I2 0L V M,4:rO1 4 0 0 1 2 0 0 !0 0 0 8 0 0 6 0 0 4 0 0 2 0 0Bi n d i a g En e r g y (e V)P t c 4 c e l e c t r p n Li n e lsu l f ur SA t()l n i c Nunl l l e r l 6I I a n d b o o k e f X-r a y Ph e t o e l e c t n)n S pe dr i s c e p yz hl o r i ne C1kt pmi c Numbe r 1 7KCl i n KClMo n o c l vo ma t e t l .A.l Ka2?BL n s m;E c e r g.(e V)K2$LMMKK 3 ggr Z1 4 0 0 1 2 0 0 1 0 8 0 0 6 0 4 0 2 9 CBi n d i n g En t r z y (e 5/)62Ar g on Arz tt a mi c Nu mb e t 1 3s 1z t f i mp l a n t e t l i n S i T rMo n o c l u o ma t r l l A1 Ka2 pS!2!5LMM3 51 4 0 0 1 2 9 9 1 0 0 0 8 0 0 6 0 0 4 0 2 0 0Bi n d i n g E n e r g y (:V)1t a s s i u m Kmi c Nu ml l e r 1 9Hant l l l ook o f X.ra l Ph t oe l e c t r on spe c t r es c a pyPnt a s s i ur n I kA t omi c Nt l mbe r 1 9l l a n t l t l t mk e f X.r a)r P ht l t o e l e c t r o n s p e dr n s t a g yt l c i um Ca I n i c 5.u mbe r 2 92/3,:=3 1 6 7 e vA =3.5 4 c vCa l c i u m Cat t l mi c Numbe r 29t)C7 t i n C a CO3Mon c ch r o mat e d X1 Kq?p 3 r 22:1,22 6 cL MM 03?l 3 sl$p g 1 2 0 0 !0 0 q 8 0 6 0 4 o 2 4:Bi n d i n y E n e f g y (e V)C 1 t i n C a t z t h2 p3.,2 =3 6 6 z MJ =3.5 5 t b 69Ha n dbo k p f X-r a y P hp t t l e l c t r o n Sp e c l r f l s c p p yl d l nm Sct f c h t i m e r 2 1Sc a ndi u m Scr tl t l r n i t l Num be r 2 lI i t a ni um Tit t mi c Nu ml l t r 2 2l l a n d L c c k c f X-r a l Ph a t p e l e c t r p n S p e c t r o s c o p l Ti t ani nm Tiz tt pmi:s i umh er 2273Yanadi um Ykt o mi c Numbe r 2 32 1,3?2 =5 1 2.2 e v.5 .=7.5 4 e vs anadi um$.rt l o mi q Numt e r 2 3$I g Kt x2f0T hr g mi l l m Crt o mi c Nv mb t r 2 1Ha nd b t mk ()C X-r a,Pho t o e l e c t r t)n s p e c t r o s c o py2(b n =5 7 4,4 z b.!t =9.2 9 5.7 7l l a n d b p/k n X-r a l P l l p l a e l c c t r o n S pe c t r/s c o p ya nk a nt s e Mnl mi c sumbe r 2 65 1 a n ga n e s e 5 l nAt f l mi c Numl l e r 2579I r o n Fett e mi c h gml l e r 26Mj r KaLMM4 2 0p ba l t C0o mi c Nu ml l e r 2 7I l a l l l l b t nk o f X-t a y Pl l o t t l de c t r t m S p e dr s c c p Coba l t C()ztt o mi c Numl l t c 2783l i c ke l (Nit o mi:Nu mb e r 2 3Ha n l l l l o nk n f X.r a y Pho t o e l e c t r t m S p e c t r v s c t l pyNi c ke l NiA t omi c Numbe r 78l o pge r Cu.t o mi c Nu mbe r 1 92 p:5.c =9 3 2.7 e v&=1 9.8 0 C V86Cop pe r Cu.At ol ni:N u ml l e r 2 95 1 g Kl z87 i nc Znkt a mi c Xt l ml l e r 3(1Ha n d a e k o f X-r a y P he t o c l e c t r o n s g e c t r o s c e g y4 8Zi nc Zr lAt t l mi c Nt k ml l e r%*8 9l l a n t l bxk pf X-r a y Ph e t o e l e c t r a n S p e c t r o s c o p,Ga l l i am Gaxit t l mi c s u md e r 3 1Ge r ma ni um GeAt p mi c Numbe r 3 2Ha n l l b o a k o f X.r a)Ph o t o e l e c t r o n S pe c t r o s c o p l 3 2 =2 9.4 t vGe r ma ni um 6e,t t t l m i t l k i k umh e r 323 C 1 =2 9,4 e vHa n d b f l p k ()f X-r a y P ho t o de c t r o n S z e c t r s c pyA r s e ni c Xskt e mi c N u n l b e r 3 394Xr s e n i c ,isA t 0 m i c 5 l l m b t r 3 395Se l e ni u m sekt o mi c Nn mbe r 3 4l I a n d L o ok of X.r a)P ha l a e l e c t r p n S p a c t r a s c p p y96bel i l nl t l m ye.t f l mi c Numl p e r 3 497Br omi n e BrAt n mi s i i n mbf r 3 3l l u ud k q c k A f J z.r a,P k q t q e l e c t r n u S y t c t r s c q p:1Bf i n K BrNl o n o c h r e n p a t e d .&l K a3 d3 p3 5MMNzl dK z1 4 9 1 2 0 0 l p 8 0 6 0 4 0 2 0 Bi n d i n g En r r g y (t 9498Br omi ne BrA t t l r ni c Nk l mht r 3.5Ih B r n K B rMg f ta:!51)k8:tl Cy.4 d1 2 0 0 1 0()0 8(1 0 6 t)0 .t k C)0 2($)()Bi n d i n g rn e r g y (e l J)Kr l pt o n KrAt n r z j c J t l ml l t.r 3 6l l aa l L0 n k of X-r a:P ko t oc l e c t r on Spe c t r o s c g p:c 7K:i n pl a n t e d i n g f a g h i t eMo n o c r o ma t e d A1 Ka3 dcl k1.$()(1 1 2 0 0 1()()8 9()6 0 0 z 0t l 2%()I y i n i n g En e r g y (e 7)Krypt on Kr.t 0m i c Nt l m be r 3 63 ds a =8 7.0 e$/A =!2 3 e vl f a n d b 0()k e f X.r a l P o t o e l e c t r o n S p v c t r o s c e gyRubi li um RbAt t l ml c Nu mh e r 3 7Ru bi t l i t l m RLA t n mi c Numl l e r 37Pc r k n-El n l e r Co r go r at i o nPhys i c al El e c t t o ni c s Di vi si o nl l a n t l b t mk()f X-r a)Ph o t o e l e c t r o n S pe c t r l sc o p ySt r nl i u m SrAt o mi c skmb e t 3!St r e nt i u m 8rAt t l m c st l r n b e r 3 3Ha n l b n Q k e f X-r a l Pko t s e l e c t r o n S p e c t r o s c o p yYt t r i um YAl n mi c l h l umhe r 3 9Yt t r i um YA t o mi c su mk t r j 9l l a nt l b f mk o f X.r a y Pl l o t o e l e c t r o f l Sp e c t l vs c o p yZi r c o t l i t l m Zrt o l ni c Nu n)L e r 4 0Zi r c o ni t l m ZrAt f l r a i c Nu mb e r 4()i o ki u nl Nbk t mi t l Nt l mbe r 1 1N i obi um NbAt o mi c Nu mh e r 4 1sl o l y bde n um M0kt o mi c Nu mb e r /1 2sl ol l f b de num 5 1 0lt nl l l i f Numl l e r 12Ru t he ni um RuAt t l mj c Nu ml l e r 4 43 d 5,.:=2 3.y e 7h =4.J 7 t j lRut he n i u m RuAt omi c Nt l ml l e r 4 4Rhedi u m l t l lkt f l mi c su me r 4 53 1 5/2 =3 0 7.2 e k A=4.7.$e vRhodi um Rl 1rtt f l mi c Numbe r .1 5Ha n db ek t)f X-r a l P h t p e l e c t r o n S pt c t r a s c t l pya l l a di um Pdt:mi c Nu n l h e r 4 6l a l l a t l i l l:;l l t lAt t l mi c Numbe r u l iPc r ki n-El me r Co l yo r at i o nPkpi r al El e c t r f mi c s Di vi h i t)nHa n 1 e 9 k o f X.r a l P ho t o c l t c t r a n s p e t t r o s c a p/Si l v e r XgAt o mi c NumL e r 1 1 73 ic =3 6 3.3 t 9J =6.L Q T VSi l v e r gAt o mi c Nu mb e?4 7a ad mi t l m Cd.t o mi c Nu mb e r 1 3s l o a o c h r o ma t e t l KaMN 53/,23 0 7 cM NN3?1 2 2 d s?f1 4 0 0 1 2 0 0 1 0 0 0 8 0 0 6 0#0 2 0 0 Bi n d i n?En e f g y (e V)Cad mi t l m CdAt omi c Nt l ml l cr .1 8l ndi u m l nAt o mi Nt l mt l k r 1 91 25Ti n SnAt n mi c Nn mb t r 5(1Ti n SnAt o mi t Nt l ml l e r 5 9l l a n d b a p k o X.r a)P l l n l a e l e c l r p n S pe c t r p s c o p,knt i mo ny Sbt o mi c Nu mt l e r 5 1nt i mon q 8I)At f l mh c Ng mb e r F 1Te l l ur i um Tkz&t o n l i c X u n l L e r 5 2Ba n l L o:k n f X-r a y Pko t o de c t r o n S p e c t r o s c n pyne 1l i c Ne m e r 5 2 3Xe no n Xt&t 0 mi t N u n a b e r 5 4H lbie k o f X-r ay P hct t l tc t r c n Spt c t r o s i p jan3 11 2 =6 6 9.7 e v =1 2 6 7 e vXe no n Xeztt o mi c Numl l ct 5.1Ce s i u m CsAt o mi c Nt l ml l e r 5 5Ha n d o k o f X.r a y Ph o t o e l e c t r o n s p e c t r o s c o p l Ce s i um CsXt v mi t Numh t f 5 5Bar i um BaAt t h mi c su ml l e r 5 6Bar i um Balt o mi c Nur n l l e r .56I z a nt ha num Lar t o mi c Numl l e r 5 7Fh c t e e l e c?t.p Lp n e sLant ka num LaAt f ml i Nu mb e r 5 7um Cei c Nl T mbe 5 83 t%:=3 1 3.3 t 9,j =I S.l e vCe r i um CeAt o mi c Nu mb e r 5 8Pr a s e o dy mi um Prt omi c NumLt r 59Pr a s k o dl mi t l m Prt n n i i c Xt l r nl l e r 5 9Ha n t i i l t mk o f X-r a l Pb o t a e l e c t r o n S z e c t r o s c o p yNt t dy mi um sdkt g mi c Nl l mb e r 6 0h l z o dy mi um NdAt i l l ni c Nu mL i t r 6(1Sa ma r i nm Smt o mi t Numl l e r 6 2Sa mar i p m SmA t omi r Nur nl l e r 62Ha n d b n Q k o f X.r a y P a t o e l e c t r c n S p e c t r p s c o pl Eur o pi um Eukt o mi c Nu n l be r 6 3Eur o pi um Eu?t t t l mi t:st l l u b e r 6 3N 1 g K a10 6I l a n d Loe k f X.r a l Pht p e l e c t r/n Spc ct r/x c p pl&a dt l l i ni um(q;(1t t o n z i c Nu a l b e r 6 14(1 =1 4 0.4 e vGa dn l i ni u m 6(1r t l o mi c Xt l r n b e r i.lN1 g K aMNX1 2 0042 =1 4:.4 c NrTer bi u n l TbAt o mi c Nu ml l k r 6 5Ha nt l l l e f)k t)f X.r a l P ho t e e l t t t r o n S pe c t r o s c a p l T r e r bi t l m l l b,$t t 3 uk Nu mk k r 6 64:1 =1 4 6.9 z%I l a n d l l c c k c f X.r a y P p t c de c t r t m S pe c t r t w c a p yp y s pr o s i um I)yt a mi c Nu mbe r 6 64(1 =1 5 2.4 e VDy s gr o s i u m D).At o n l i c Nt t mb e r 6 6l l o l n l i u l n l l 0t n mi c Nu mb e r 6 7l l a nt l b t mk J X-r a Pl l t o t l t c t e n S pt c t r t s c a p q41Er l l i um ErAt o l u i c Numl l e r 6 84:1 =16 7.3 e V4dEr bi um Ert o mi c Nt l ml l er 684 =1 67.3 :VThul i t l m TmAt c nl k h l nn l l l e r 5.9Thui i um TmXt t t mi c Nt l mbe r 6 944 =1 75.4 e$t t t e r bi u m Ybk t e mi c Nt l mb k r 7 0h r t t e r bi un l ba&t o cl i c N ul nl l e r 70(t l =l 8 2,4 t V4 4Ha n t l l l o o k o f X-r a y P ho t g de c t r t)n S p e c t r n s c o ri u m I,uNt l m e r 7 fLut e t i um LuAt t l mi c Nu m b f r s 7 ll l a f ni un l i l fkt n mi c Nu mb e r 7 2i l a f ni u nl i l fAt t l nl i c Nt l r nl l e r 7 2Ta nt a l um TaAt o mi c N u mh e r 7 3Han dl l nok ()f X-r aj Phqt t l e l ec t r t)n Spe c t r t k s c t l pyl l a r l d l mt)k t)f 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