分子开关型8-羟基喹啉锰类配合物催化烯烃环氧化研究的开题报告.docx

分子开关型8-羟基喹啉锰类配合物催化烯烃环氧化研究的开题报告
【摘要】
8-羟基喹啉锰配合物具有分子开关特性，在不同的配体作用下，可以调控其催化活性。本项目旨在通过合成不同的配体，设计一系列8-羟基喹啉锰配合物，并系统研究它们在烯烃环氧化反应中的催化活性和选择性。采用紫外可见光谱、核磁共振、红外光谱等技术对合成的配合物进行表征，并通过气相色谱分析反应产物，探索其对不同烯烃的环氧化反应催化效果。结果表明，不同配体对催化活性产生不同的影响，且8-羟基喹啉锰配合物能够高效、选择性地催化烯烃的环氧化反应。
【关键词】 分子开关；8-羟基喹啉锰配合物；烯烃环氧化；催化活性；选择性
【Abstract】
8-hydroxyquinoline manganese complex has molecular switch properties, and its catalytic activity can be regulated by different ligands. This project aims to design a series of 8-hydroxyquinoline manganese complexes by synthesizing different ligands, and systematically study their catalytic activity and selectivity in the epoxidation reaction of olefins. The synthesized complexes were characterized by UV-visible spectroscopy, nuclear magnetic resonance, infrared spectroscopy and other techniques, and the reaction products were analyzed by gas chromatography to explore the catalytic effect of different olefins in the epoxidation reaction. The results show that different ligands have different effects on catalytic activity, and 8-hydroxyquinoline manganese complexes can efficiently and selectively catalyze the epoxidation reaction of olefins.
【Keywords】 Molecular switch; 8-hydroxyquinoline manganese complex; Epoxidation of olefins; Catalytic activity; Selectivity